File name: Pandora104s1_Downsview_20200814_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T060901.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200814_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200814T110625.9Z 7531.462800 198 1 49.78 2 83.12 77.00 34.36 117.64 0.00 1 0.00 1 0 17 4.361e-01 2.757e-02 3.792e-01 2.042e-02 7.818340e-01 1.201590e-02 1.091083e-02 -6.000000e+00 2.652378e-01 231.90 -2.00 3.57 -2.00 322.08 0.00e+00 1.468347e-02 6.834268e-03 1.381183e-02 -6.000000e+00 1.279601e-02 287.44 -2.00 20.00 -2.00 321.54 0.00e+00 7.625 0.009 302.00 328.00 3 1.9014e+00 4.7727e-02 1.0924e-01 -6.0000e+00 6.6724e-01 1.0577e+00 6.0452e-02 9.0719e-02 -6.0000e+00 7.2432e-01 -1.2935e+00 4.4915e-02 3.6116e-02 -6.0000e+00 4.2749e-01 4.9681e-01 2.1267e-02 6.8679e-03 -6.0000e+00 1.7740e-01 1.9322e-05 -6.0422e-04 5.9846e-04 2.8412e-04 -6.0000e+00 1.2671e-02 -6.1257e-03 0.0000e+00 12 8 8 10 0 0 99.16 25.39 0.89 -0.00613 -0.01067 35 7 1 5 0 1421.770 25.39 15.00 22.23 131175 -37080 -133434 900000 -75253 900000 -31394 900000 -124865 900000 -111844 28779 -43851 900000 -5589 900000 900000 -4808 27798 15148 137617 12764 900000 -48173 900000 22707 136314 -58072 900000 89601 143784 112294 74920 67943 -11098 124801 117928 -21721 -15506 -19097 3458 40373 -1664 55425 28040 18756 17698 42179 85049 26834 -829 43315 3383 67915 26919 31518 72104 34872 30388 35672 3779 24221 14230 28442 24990 14779 23306 24635 18439 604 16249 -1443 -1266 6651 -1119 5426 8092 -9820 5741 23466 6006 8626 2644 -6836 -1472 -858 282 443 4819 16 -7707 -756 -12015 7600 -4075 -9652 -2387 -136 -3604 -3925 -2953 -5065 -2528 219 -7048 -2594 -3475 -2678 20 2806 210 221 -242 -202 467 109 1512 -1384 1949 1562 381 4350 1813 1451 1260 -59 -261 1136 428 1600 2053 -409 -268 -1358 -1662 919 651 378 137 410 564 -1790 -1649 2607 -1139 -9725 900000 -2448 900000 -624 900000 -5641 900000 -4244 572 -1268 900000 -172 900000 900000 -191 804 493 2735 369 900000 -2437 900000 533 2709 -2833 900000 1781 2858 2232 1936 1891 -562 2481 2344 -1452 -1121 -1587 268 2247 -132 2754 1839 1379 1337 2599 3550 2133 -96 3530 437 4860 2943 3320 5016 3396 2960 3262 496 2889 2121 4127 3924 2497 3613 3917 3482 155 3779 -407 -342 1534 -251 1025 1432 -2186 1267 5224 1850 2949 1046 -3125 -679 -414 141 226 2318 8 -3784 -329 -5731 3187 -2220 -6561 -1751 -112 -3360 -3667 -2548 -3977 -1784 153 -5730 -2119 -3053 -2523 20 3202 275 308 -343 -280 618 141 1977 -1961 2832 2356 570 5965 2458 1933 1631 -76 -325 1493 655 2777 3921 -859 -597 -3284 -4324 2449 1766 1042 377 1080 1388 -4213 -3754 SS 20200814T111638.9Z 7531.469895 201 1 39.85 2 81.31 78.72 32.77 120.66 0.00 1 0.00 1 0 17 4.540e-01 1.563e-02 2.767e-01 8.956e-03 6.882907e-01 5.072152e-03 9.210500e-03 -6.000000e+00 2.700219e-01 231.90 -2.00 3.57 -2.00 321.81 0.00e+00 1.129974e-02 2.862738e-03 8.695861e-03 -6.000000e+00 1.223358e-02 287.44 -2.00 20.00 -2.00 321.24 0.00e+00 6.246 0.005 302.00 328.00 3 2.3431e+00 1.9643e-02 8.1330e-02 -6.0000e+00 6.7596e-01 4.1372e-01 2.6479e-02 6.0145e-02 -6.0000e+00 7.3132e-01 -5.8436e-01 2.3336e-02 3.1511e-02 -6.0000e+00 4.3466e-01 2.3661e-01 1.0764e-02 9.6465e-03 -6.0000e+00 1.8197e-01 5.6400e-05 -3.2410e-04 2.6336e-04 2.3727e-04 -6.0000e+00 1.2651e-02 -6.6603e-03 0.0000e+00 12 9 9 12 1 1 98.80 25.39 0.46 -0.00666 -0.00910 34 9 1 5 0 1133.620 25.39 15.00 22.25 -102814 -149043 -167707 -69535 900000 -158566 -138028 -140051 -78535 -109008 -94421 -125487 -50221 4734 95834 -80226 190834 -95973 37413 4596 -23002 -65124 25299 -15382 -70993 -19143 -20205 -14681 -75118 -10525 27724 56550 -1730 33529 15637 85491 18281 47881 -1576 17439 -11590 15043 12594 33129 4657 18106 -288 15404 18956 19000 28584 8791 27522 29004 33529 3942 10000 3701 9584 684 15760 11396 4901 6082 16821 648 6062 5095 5942 3942 5022 4108 968 5218 -436 -1624 -1119 931 -3191 -1282 -3249 2501 -2948 2408 2 -2723 -807 1821 1751 -624 -1795 -1000 -2663 -677 -2427 -1312 -1423 -1802 500 -1461 -929 -2245 -649 -738 -1936 -3836 -800 -831 -512 335 670 -165 -1360 -408 -949 1383 1097 1414 -56 787 530 1897 642 2583 -138 992 352 838 -154 420 -172 -623 -412 -60 752 -53 -137 270 390 -902 100 -506 -483 -1306 -3313 -4660 -662 900000 -3147 -2301 -2557 -810 -1558 -1199 -2590 -638 50 837 -2611 1666 -4419 523 84 -548 -2275 398 -376 -2818 -501 -529 -359 -3161 -285 629 1136 -65 995 519 1418 655 1505 -88 914 -883 931 840 2025 351 1236 -24 1162 1445 1554 2360 984 2753 3062 3487 566 1365 529 1255 98 2052 1737 903 1241 3218 142 1251 1104 1434 1111 1499 1272 301 1454 -117 -400 -263 223 -914 -432 -1292 1068 -1449 1183 1 -1600 -490 1100 1049 -369 -1008 -527 -1385 -365 -1520 -949 -1185 -1717 507 -1503 -887 -1948 -516 -602 -1731 -3669 -789 -881 -600 439 967 -253 -2114 -609 -1359 1876 1522 2055 -87 1266 843 2857 945 3637 -192 1334 460 1155 -245 751 -340 -1309 -910 -142 1883 -142 -369 737 1061 -2395 247 -1184 -1097 SS 20200814T113034.9Z 7531.479570 206 1 49.72 2 78.84 81.05 30.69 125.13 0.00 1 0.00 1 0 25 2.483e-01 6.073e-03 1.194e-01 2.169e-03 5.978944e-01 1.186116e-03 7.319785e-03 -6.000000e+00 1.472139e-01 231.90 -2.00 3.57 -2.00 321.21 0.00e+00 5.529527e-03 5.918886e-04 4.513499e-03 -6.000000e+00 6.569424e-03 287.44 -2.00 20.00 -2.00 320.58 0.00e+00 4.984 0.002 302.00 328.00 3 1.4526e+00 4.1355e-03 6.1450e-02 -6.0000e+00 3.6890e-01 3.8179e-02 5.6745e-03 4.0986e-02 -6.0000e+00 3.9906e-01 -5.4497e-02 5.4798e-03 2.2618e-02 -6.0000e+00 2.3749e-01 9.5262e-03 2.5881e-03 7.1751e-03 -6.0000e+00 9.9517e-02 5.1147e-04 -5.9368e-05 6.3241e-05 1.1745e-04 -6.0000e+00 6.8983e-03 -7.4778e-03 0.0000e+00 10 0 0 10 0 0 -4.15 25.39 0.34 -0.00748 -0.00792 271 56 1 5 0 183.420 25.39 15.00 22.23 -61378 -49269 -47311 -69184 -33153 -85520 -97376 -108206 -51766 -86795 -107296 -59282 -71200 -29967 -49898 -33238 -29916 12698 -633 8573 -17019 -360 -6466 -11226 -24808 -22963 -29462 -26345 -27977 -18495 1287 -14730 -6685 1054 -9010 -11990 -5391 -6707 4680 -1730 314 13 1882 1114 1956 873 2767 1773 1467 1866 1565 4103 3398 2028 419 1102 559 -634 -207 1093 988 4570 3276 3939 2756 2282 721 1608 2394 2500 1231 312 -293 -632 -1033 -1441 -1264 -2861 -1768 -559 -1580 -1397 -1980 -1912 -121 185 873 594 688 736 57 -183 -931 -691 -706 34 -191 448 -1 -992 -742 -708 -178 491 -760 -1823 -361 -140 941 650 823 48 202 -107 246 424 671 463 340 98 -84 97 444 92 26 159 -499 423 -237 -452 -732 -691 -522 33 122 44 68 407 69 -59 135 -36 -115 -273 -219 -220 -381 -119 -525 -742 -1053 -318 -808 -1294 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