File name: Pandora104s1_Downsview_20200924_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T064055.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200924_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200924T115211.1Z 7572.494573 49 1 50.26 2 82.89 97.93 160.58 12.43 0.00 1 0.00 1 0 25 5.343e-01 2.820e-02 3.560e-01 2.041e-02 7.913552e-01 1.183334e-02 8.905149e-03 -6.000000e+00 3.159611e-01 227.85 -2.00 3.57 -2.00 321.96 0.00e+00 -6.763731e-03 6.240587e-03 8.119862e-03 -6.000000e+00 1.495539e-02 283.62 -2.00 20.00 -2.00 321.43 0.00e+00 7.429 0.008 302.00 328.00 3 2.2439e+00 4.3981e-02 9.8721e-02 -6.0000e+00 7.8453e-01 9.0923e-01 5.6784e-02 8.3460e-02 -6.0000e+00 8.5351e-01 -1.1932e+00 4.5444e-02 2.8818e-02 -6.0000e+00 5.0963e-01 4.8231e-01 2.1524e-02 9.3309e-03 -6.0000e+00 2.1476e-01 1.8095e-05 -5.4002e-04 5.9139e-04 8.7053e-05 -6.0000e+00 1.5137e-02 -4.3932e-03 0.0000e+00 12 8 8 10 0 0 -25.43 25.68 0.91 -0.00439 -0.00845 26 5 1 5 0 1932.760 25.68 15.00 22.49 55139 900000 122007 -108673 -110545 -30434 28596 -58273 -57074 -103334 -52500 -108691 62053 900000 900000 -21841 900000 194078 40065 234273 -43514 900000 139015 900000 -48182 900000 -72450 900000 -59523 900000 -31420 -5573 -2229 -37643 4263 -34260 34552 -4523 305935 46104 120232 22183 106367 39339 16078 -3726 45750 -2052 -1960 -17855 -17155 27421 27771 17810 36112 40305 41853 15397 53237 55361 35208 65582 37608 24802 25143 27946 37332 5873 17094 24242 3741 -3590 -1777 883 1168 -2785 1458 8233 4843 7539 -3142 -2624 7483 -132 4071 3408 4129 -2244 -7182 1207 -5170 -9651 -2457 -4749 6039 -2745 -4130 -639 -1055 -2964 -4111 -2262 -4484 875 -4955 1592 -4757 -2073 -1264 153 -459 -987 -408 1001 -512 -2317 105 1823 -1016 1860 2889 2375 1195 3381 891 1433 4860 -532 1274 -939 1197 -1565 344 -530 376 928 827 -129 -680 -119 93 -1051 -1601 1095 900000 2424 -4678 -4209 -605 568 -1544 -1606 -4790 -1478 -5938 1233 900000 900000 -868 900000 3856 929 4654 -2233 900000 2762 900000 -3031 900000 -5518 900000 -3449 900000 -1665 -258 -111 -2680 200 -2155 1311 -302 6078 2581 3474 1763 3650 2558 1278 -357 2644 -196 -195 -2040 -2158 2674 2909 2220 3913 4368 4535 2113 4711 4599 3625 5449 4619 3852 4042 4240 5192 1177 3458 5210 1054 -1115 -523 234 278 -619 298 1636 1137 2056 -1107 -1052 2973 -60 1890 1680 2118 -1244 -4112 608 -2605 -4863 -1136 -2410 3163 -1834 -3215 -547 -987 -2816 -3683 -1777 -3337 632 -4108 1297 -4390 -2007 -1358 185 -624 -1439 -599 1421 -709 -3172 143 2551 -1545 2833 4253 3350 1644 4457 1169 1822 5784 -715 1940 -1672 2303 -3313 758 -1267 955 2462 2225 -354 -1863 -309 226 -2399 -3560 SS 20200924T120228.7Z 7572.501721 52 1 49.46 2 81.06 99.75 160.11 18.88 0.00 1 0.00 1 0 17 5.317e-01 1.153e-02 3.436e-01 7.256e-03 6.964541e-01 4.158978e-03 8.408265e-03 -6.000000e+00 3.121152e-01 227.85 -2.00 3.57 -2.00 321.79 0.00e+00 7.720002e-03 2.368969e-03 5.003947e-03 -6.000000e+00 1.548697e-02 283.62 -2.00 20.00 -2.00 321.25 0.00e+00 6.090 0.004 302.00 328.00 3 2.2608e+00 1.5816e-02 7.3356e-02 -6.0000e+00 7.7782e-01 2.1450e-01 2.3106e-02 4.6842e-02 -6.0000e+00 8.4636e-01 -2.7628e-01 2.3465e-02 2.8518e-02 -6.0000e+00 5.0330e-01 1.0308e-01 1.0661e-02 1.0629e-02 -6.0000e+00 2.1283e-01 7.2796e-05 -7.7277e-04 2.1682e-04 1.7431e-04 -6.0000e+00 1.5139e-02 -3.9440e-03 0.0000e+00 12 9 8 11 8 0 63.13 25.68 0.59 -0.00394 -0.00975 60 12 1 5 0 824.170 25.68 15.00 22.51 -24139 -179337 900000 900000 -158216 -89591 -151299 108689 -77313 900000 -251724 900000 -123505 64875 -119664 -88402 -77001 900000 3215 279496 50450 210108 27167 -52532 -43631 91761 51722 -43794 3996 -28237 -40 1876 47272 21032 -32244 -3185 18160 -17066 30244 -7420 -3261 4837 5957 1307 -3114 19685 -1513 29595 7897 28229 10517 14300 9908 19125 5940 8338 -717 -1335 258 11060 -2504 6114 2194 4872 6523 2236 5190 5058 5612 3511 2946 1472 4143 1302 -2183 -6087 -1090 -6024 968 -1366 -1455 -3779 -799 -1338 -2247 -324 -382 536 1670 1240 2133 -538 -2485 -261 -866 815 -1890 -157 -615 -524 -885 -1426 -2034 -1001 -1488 -779 -333 -107 799 305 1252 575 237 -155 31 -240 1070 810 466 -808 -8 31 654 452 758 335 -267 208 -402 258 -345 -249 -1162 45 8 618 44 511 -80 -180 -321 230 -396 -171 -1844 900000 900000 -1220 -633 -1167 768 -547 900000 -7280 900000 -1587 459 -2461 -1591 -1386 900000 31 1976 357 1485 250 -1047 -841 649 439 -873 56 -563 -1 41 835 506 -1140 -86 488 -713 952 -396 -184 270 348 82 -210 1101 -108 1636 574 1814 906 1333 1051 2003 741 1056 -101 -188 35 1343 -367 923 392 955 1321 461 1044 1066 1327 975 884 463 1235 375 -595 -1561 -256 -1549 266 -461 -570 -1729 -388 -690 -1252 -188 -233 331 1011 726 1161 -285 -1307 -142 -542 584 -1600 -148 -636 -539 -851 -1235 -1644 -820 -1324 -722 -326 -112 920 398 1790 873 362 -231 44 -329 1474 1171 716 -1302 -12 47 943 636 1029 444 -343 282 -626 453 -669 -511 -2540 105 20 1598 117 1365 -215 -465 -782 523 -883 SS 20200924T121500.0Z 7572.510416 57 1 49.96 2 78.84 102.00 159.29 26.30 0.00 1 0.00 1 0 17 3.262e-01 7.464e-03 1.462e-01 2.981e-03 5.861812e-01 1.634599e-03 7.575301e-03 -6.000000e+00 1.904588e-01 227.85 -2.00 3.57 -2.00 321.26 0.00e+00 8.182477e-03 7.858978e-04 5.012448e-03 -6.000000e+00 8.494426e-03 283.62 -2.00 20.00 -2.00 320.66 0.00e+00 4.985 0.002 302.00 328.00 3 2.0581e+00 5.5897e-03 6.0898e-02 -6.0000e+00 4.7321e-01 7.3480e-02 7.4576e-03 3.9623e-02 -6.0000e+00 5.1388e-01 -8.7424e-02 7.1649e-03 2.4166e-02 -6.0000e+00 3.0616e-01 2.4580e-02 3.4269e-03 9.3476e-03 -6.0000e+00 1.2883e-01 2.8048e-04 -1.5191e-04 8.9425e-05 1.5792e-04 -6.0000e+00 9.0525e-03 -3.8763e-03 0.0000e+00 11 8 0 10 0 0 94.30 25.68 0.35 -0.00388 -0.00502 144 29 1 5 0 346.880 25.68 15.00 22.50 -170859 -111601 -107996 -102968 -139685 -104631 -105376 -12519 -82123 -34806 -82742 107131 -48023 36276 -14947 -13134 -19960 15409 -18545 -16153 -33887 -28605 -21421 -17960 -16608 -31485 -23995 -30632 5169 -24424 16763 -11159 -461 -4336 3070 -12355 9397 -6294 3204 -5069 -3396 -4158 732 -866 -3154 5960 116 10833 3013 11032 3780 8721 4129 6295 3362 5123 1427 -534 -365 2464 -1385 3964 2008 5441 3350 1529 1709 992 3231 1772 412 -236 287 -422 463 -716 -200 -3333 -1070 -1056 -1652 -1529 -2447 -1844 -1030 -299 195 -60 583 942 -244 381 -1252 -577 -245 586 -81 601 -239 -843 -832 -1227 -808 -329 -821 -1625 -670 -647 696 680 911 272 493 7 381 191 1230 250 534 -83 237 640 450 54 -38 12 -811 389 -190 -170 -548 -576 -379 -10 40 -170 -81 343 33 -268 137 267 -1 -2754 -1121 -1113 -952 -1735 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