File name: Pandora104s1_Downsview_20200927_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T064031.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200927_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200927T133124.4Z 7575.563476 143 1 48.71 2 66.59 117.79 154.90 337.48 0.00 1 0.00 1 0 17 3.397e-02 8.356e-03 2.165e-02 3.899e-03 2.909046e-01 1.998493e-03 3.553194e-03 -6.000000e+00 1.982906e-02 227.48 -2.00 3.57 -2.00 318.65 0.00e+00 1.715634e-03 4.161511e-04 7.793579e-04 -6.000000e+00 8.832967e-04 283.24 -2.00 20.00 -2.00 317.88 0.00e+00 2.498 0.000 302.00 328.00 3 5.4353e+00 5.4462e-03 2.8773e-02 -6.0000e+00 4.9233e-02 4.8293e-02 6.2284e-03 1.5369e-02 -6.0000e+00 5.3466e-02 -2.0466e-03 4.0784e-03 7.7148e-03 -6.0000e+00 3.1856e-02 -9.3909e-03 2.0881e-03 2.3655e-03 -6.0000e+00 1.3421e-02 1.4083e-04 4.1706e-05 1.1914e-04 2.5390e-05 -6.0000e+00 9.4298e-04 -9.6719e-03 0.0000e+00 11 8 0 10 0 0 99.97 26.00 0.51 -0.00967 -0.00936 20 4 1 5 0 2435.190 26.00 15.00 22.87 6259 -10395 -15402 -3180 -9155 -13174 -7642 7702 2679 829 -7705 -2780 -6869 985 2962 -12237 4137 -497 5054 4841 9768 -2244 3149 2059 3539 2546 -5707 599 -7281 -1027 -125 -2554 821 266 -10850 -1454 -1254 -192 -2206 -1419 -78 -1678 -515 130 -403 1309 -697 -273 -770 582 1658 1203 3187 365 1756 681 1035 -883 414 325 1826 2150 1825 2018 1458 -109 976 -317 1708 742 228 655 -463 433 -600 155 -1796 -1807 -1135 -592 -1838 -1030 -3011 -862 -1193 534 888 151 122 634 -19 290 -924 -833 390 -128 -393 35 97 -1479 -269 -1792 763 -579 -612 -1518 -167 -632 1004 600 933 326 577 492 399 297 368 653 0 500 -123 183 -277 826 319 745 -620 472 -254 -389 -875 -776 -293 -207 712 148 164 255 106 -568 452 -512 -224 332 -687 -1086 -184 -514 -758 -451 445 177 58 -575 -213 -632 98 329 -1720 518 -69 688 688 1353 -344 472 331 593 441 -1057 99 -1253 -167 -22 -501 170 56 -2378 -295 -282 -51 -702 -510 -30 -679 -212 54 -168 543 -290 -112 -314 240 720 564 1542 191 927 372 575 -495 227 179 1030 1303 1196 1400 1011 -71 598 -195 1121 552 182 536 -380 339 -446 104 -1132 -1109 -738 -433 -1499 -914 -2877 -844 -1249 585 1018 178 143 716 -20 286 -854 -765 379 -137 -458 44 130 -1965 -335 -2094 843 -672 -765 -1992 -227 -892 1468 933 1515 535 919 741 564 402 500 920 0 785 -197 288 -427 1227 457 1031 -827 632 -364 -596 -1407 -1273 -489 -359 1288 281 317 500 209 -1110 851 -942 -405 SS 20200927T135447.7Z 7575.579719 157 1 1.45 2 62.95 122.85 155.98 349.85 0.00 1 0.00 1 0 25 1.366e-02 7.772e-03 6.293e-03 2.708e-03 2.560214e-01 1.399974e-03 3.123879e-03 -6.000000e+00 7.968157e-03 227.48 -2.00 3.57 -2.00 316.62 0.00e+00 5.002981e-04 1.719429e-04 1.713952e-04 -6.000000e+00 3.550312e-04 283.24 -2.00 20.00 -2.00 315.89 0.00e+00 2.187 0.000 302.00 328.00 3 2.5156e+00 3.6527e-03 2.5141e-02 -6.0000e+00 1.9783e-02 6.0128e-03 4.0931e-03 1.3296e-02 -6.0000e+00 2.1486e-02 -3.5965e-03 2.3801e-03 6.5093e-03 -6.0000e+00 1.2802e-02 -4.7442e-03 1.1164e-03 1.8231e-03 -6.0000e+00 5.3925e-03 3.7997e-03 -1.9617e-04 7.9399e-05 2.0820e-05 -6.0000e+00 3.7899e-04 -8.3648e-03 0.0000e+00 12 9 1 12 1 1 52.93 26.00 0.20 -0.00836 -0.00984 6 57 1 5 0 180.380 26.00 15.00 22.87 -1573 -2299 408 -4339 -3918 -6551 -1772 -444 531 -3441 -2370 -2464 814 -1381 2867 38 1149 887 2805 2340 456 -579 1544 1731 427 -374 -2249 -1446 -1348 1451 667 1007 975 -2077 -3946 -1485 -2395 -305 -474 -844 -1412 -252 15 -8 402 819 86 -743 -80 0 1186 785 754 852 1124 858 1139 368 367 967 1562 1959 1572 1116 16 -492 34 -127 1594 1326 104 392 -542 -7 -131 -657 -1304 -1410 -1032 -735 -1955 -1852 -2773 -1560 -590 -397 88 -9 101 38 471 293 260 692 717 121 180 -164 -13 -1533 -297 -975 129 477 -356 -1342 -291 -735 570 774 631 290 533 796 476 671 1035 251 51 -315 -416 -73 62 446 679 1220 -422 732 162 -632 -536 -483 -109 -87 316 193 276 -168 106 -371 77 -413 -488 -249 -385 67 -718 -585 -988 -276 -78 96 -663 -443 -489 178 -338 759 11 344 267 855 747 150 -190 511 608 160 -139 -868 -519 -461 501 238 386 387 -856 -1609 -598 -1034 -146 -261 -511 -891 -164 9 -5 258 544 56 -480 -50 0 794 547 533 632 848 667 867 280 284 746 1244 1622 1360 993 14 -415 27 -102 1371 1215 100 389 -537 -6 -119 -578 -1057 -1138 -853 -663 -1865 -1882 -2938 -1708 -669 -467 105 -11 124 46 540 318 266 716 770 136 216 -206 -16 -1971 -371 -1159 150 563 -448 -1739 -382 -1008 793 1120 936 434 783 1115 632 864 1368 340 71 -452 -611 -105 89 628 934 1604 -547 945 220 -904 -783 -704 -161 -131 492 310 452 -276 174 -618 123 -655 -761 SS 20200927T140030.8Z 7575.583690 160 1 9.67 2 62.09 124.14 156.12 353.00 0.00 1 0.00 1 0 17 1.773e-02 7.196e-03 1.047e-02 3.580e-03 2.495141e-01 1.839259e-03 3.026928e-03 -6.000000e+00 1.034507e-02 227.48 -2.00 3.57 -2.00 317.21 0.00e+00 6.432365e-04 2.616965e-04 1.827968e-04 -6.000000e+00 4.608689e-04 283.24 -2.00 20.00 -2.00 316.46 0.00e+00 2.126 0.000 302.00 328.00 3 4.8596e+00 4.8435e-03 2.4471e-02 -6.0000e+00 2.5685e-02 3.3050e-02 5.4510e-03 1.2992e-02 -6.0000e+00 2.7894e-02 8.9269e-04 3.2407e-03 6.3616e-03 -6.0000e+00 1.6620e-02 -7.0932e-03 1.5669e-03 1.8018e-03 -6.0000e+00 7.0016e-03 3.8449e-04 -1.0067e-04 1.0626e-04 1.9702e-05 -6.0000e+00 4.9198e-04 -9.1459e-03 0.0000e+00 12 9 1 12 9 1 99.96 26.00 0.27 -0.00915 -0.00990 7 9 1 5 0 1186.390 26.00 14.99 22.88 -36 2711 -3290 -4771 -2655 -7968 -6048 6147 -6231 -2716 -2688 1487 -3431 2253 4671 2180 -620 3907 1950 1250 1970 -1603 1915 238 873 228 -87 -882 -828 -1200 2390 882 1051 -2664 -3303 -4288 -419 -1021 -678 -1290 -1548 -333 521 -914 -209 113 -1267 -202 -1097 600 264 1305 446 1479 -424 1298 1293 410 -487 850 1686 1401 1334 1363 358 -585 118 -236 1400 1013 390 -303 2 354 130 -321 -317 -1628 -345 -701 -2020 -1785 -1902 -1714 -321 80 830 -322 803 770 353 300 -1106 39 100 330 -103 502 223 -643 -670 -526 -326 14 -611 -1351 -620 -315 271 686 891 274 511 14 312 160 469 526 472 -421 136 -236 -211 59 696 1160 -482 700 14 -338 -836 -449 -133 95 -19 321 73 110 93 166 -511 -29 -308 -4 335 -434 -588 -293 -911 -733 752 -928 -403 -392 221 -600 425 966 494 -149 938 491 328 524 -434 516 69 263 71 -27 -257 -231 -334 689 275 350 -923 -1082 -1433 -148 -421 -323 -689 -877 -193 307 -548 -124 68 -750 -117 -631 345 160 828 296 1014 -300 924 935 297 -351 608 1234 1089 1097 1168 306 -473 91 -179 1122 893 363 -291 2 327 114 -263 -243 -1223 -269 -601 -1886 -1784 -1984 -1847 -360 94 1005 -399 983 921 403 323 -1129 39 105 370 -123 638 296 -845 -845 -626 -378 17 -776 -1778 -838 -437 387 1018 1363 421 767 20 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