File name: Pandora104s1_Downsview_20210423_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T094955.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20210423_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210423 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210423T105438.9Z 7783.454617 176 1 49.83 2 85.08 77.13 109.27 307.72 0.00 1 0.00 1 0 17 5.697e-01 8.091e-02 5.642e-01 7.237e-02 1.253554e+00 4.726622e-02 1.722477e-02 -6.000000e+00 3.587035e-01 228.87 -2.00 3.57 -2.00 322.30 0.00e+00 3.007980e-02 1.872577e-02 9.744061e-03 -6.000000e+00 1.732372e-02 278.29 -2.00 20.00 -2.00 321.81 0.00e+00 9.941 0.019 302.00 328.00 3 1.6535e-02 1.6086e-01 1.2085e-01 -6.0000e+00 8.9830e-01 3.1620e+00 1.8649e-01 6.5697e-02 -6.0000e+00 9.8588e-01 -2.8227e+00 1.0771e-01 3.6139e-02 -6.0000e+00 5.8552e-01 9.2886e-01 6.0601e-02 2.0137e-02 -6.0000e+00 2.4257e-01 3.8597e-06 -1.5944e-03 1.7849e-03 3.5191e-04 -6.0000e+00 1.7501e-02 1.7115e-02 0.0000e+00 12 8 8 10 0 0 99.65 25.39 2.38 0.01712 0.00513 20 4 1 5 0 2491.240 25.39 15.00 22.13 267279 900000 119532 38774 -39104 29977 -70493 -28379 900000 3046 900000 44285 45842 15285 900000 -24965 900000 900000 900000 160601 900000 900000 -34470 40188 81148 -76157 198445 900000 900000 900000 6802 -4809 86794 900000 11081 900000 55263 900000 -20761 900000 900000 36775 18959 -48471 900000 -67918 900000 -73644 87430 11856 900000 97661 148279 -38426 -25383 123993 900000 3028 900000 900000 19417 127201 123672 900000 45613 51630 -35291 74730 -16483 120617 -5814 78328 -7781 53378 -55774 900000 -40601 13867 -26457 900000 2703 66057 53812 60235 3344 30330 8782 18520 43933 -16923 26961 -17723 17878 -21516 -1627 -27396 19982 -2132 28013 -12662 18967 13910 3319 -11038 -11440 -13655 -145 9755 745 22089 7355 15749 -4146 12537 3736 1961 -5598 -4775 -2537 10382 -4942 -1961 9650 -2026 -6896 -6992 -8036 -5674 11761 -697 -1290 -5458 244 -3468 2956 -1063 2559 -1233 3132 -5311 2305 2169 4848 18754 900000 8387 3174 -5259 2103 -8244 -1991 900000 214 900000 3107 3217 1162 900000 -4087 900000 900000 900000 11269 900000 900000 -3426 2820 5694 -7570 13924 900000 900000 900000 521 -491 6090 900000 848 900000 3878 900000 -2251 900000 900000 2580 1451 -7111 900000 -12131 900000 -15502 6135 1210 900000 6853 10404 -8089 -4534 8700 900000 328 900000 900000 1610 8925 8678 900000 4655 4940 -8329 6817 -3785 8463 -1335 8244 -1588 5618 -14872 900000 -8262 1849 -6498 900000 721 10661 10572 11412 1150 8087 2958 5588 9865 -6531 6243 -6218 4516 -9209 -696 -18646 10095 -1571 16708 -11195 11046 7222 1677 -6351 -6984 -8815 -88 5886 580 16585 7432 16024 -5352 13723 4377 2312 -7346 -6499 -3508 12458 -6415 -2256 9412 -2175 -7596 -7555 -8740 -6888 14772 -1188 -2534 -12332 569 -9126 7819 -3030 7020 -3503 8329 -14309 5192 4414 9253 SS 20210423T110638.9Z 7783.462950 179 1 49.74 2 82.95 79.16 110.93 310.15 0.00 1 0.00 1 0 25 4.663e-01 2.012e-02 4.327e-01 1.216e-02 1.145157e+00 7.588316e-03 1.170757e-02 -6.000000e+00 2.763317e-01 228.87 -2.00 3.57 -2.00 322.70 0.00e+00 1.728869e-03 4.829179e-03 5.957432e-03 -6.000000e+00 1.254519e-02 278.29 -2.00 20.00 -2.00 322.31 0.00e+00 7.492 0.008 302.00 328.00 3 8.2704e-01 3.1976e-02 1.0727e-01 -6.0000e+00 6.9002e-01 1.4536e+00 4.6067e-02 9.1405e-02 -6.0000e+00 7.5294e-01 -1.8969e+00 4.3364e-02 4.2409e-02 -6.0000e+00 4.4519e-01 7.4143e-01 1.9515e-02 1.2485e-02 -6.0000e+00 1.8405e-01 4.3062e-05 -6.5835e-04 3.1199e-04 1.5451e-04 -6.0000e+00 1.3143e-02 1.6221e-02 0.0000e+00 12 8 8 10 0 0 87.20 25.39 0.62 0.01622 0.01127 96 20 1 5 0 517.970 25.39 15.00 22.16 -84365 44523 20163 900000 900000 -99703 -159189 -184256 2817 -190429 -86923 -19155 18746 -52637 900000 47559 900000 47409 55793 -32540 68515 16230 900000 900000 -30618 65925 -23648 17168 -55359 -13642 4498 900000 -40538 35725 -52251 93410 32591 146782 65062 54645 -17631 49727 85927 70657 39458 48439 111896 118915 31741 16247 2763 17604 61371 18143 94377 31392 103499 26700 13145 13731 55076 9481 42954 33507 32450 44837 29207 14903 21009 29275 23233 21740 7297 25938 -6330 3355 -11634 -4959 -97 2518 4249 3605 9606 5282 8305 4526 8489 1841 7084 -758 2630 1772 184 -9826 -1245 -6310 -931 -4778 -1587 -2950 -1748 -2841 -238 -1937 -1929 -6525 -2068 1762 -1438 -967 -1302 66 -1532 -232 -751 -668 -984 13 -734 345 1649 1937 993 1990 2187 2734 744 1122 1637 -840 728 -93 -277 -531 974 -116 1051 525 401 -1347 70 -749 -1779 -1635 527 239 900000 900000 -1396 -4114 -6349 33 -7176 -1217 -227 222 -1020 900000 563 900000 562 661 -736 811 192 900000 900000 -626 781 -407 203 -1252 -259 91 900000 -1528 677 -1969 1106 618 1738 1233 1294 -835 1355 1628 1506 1122 1262 1590 1690 1165 770 170 1043 2544 1246 3130 2008 3187 1676 872 862 2348 719 2696 2659 2767 3399 2733 1747 2662 3849 3412 3244 1068 3103 -915 397 -1612 -717 -16 504 901 893 2462 1490 2396 1408 2632 610 2166 -238 753 504 55 -3713 -521 -3370 -556 -3452 -1213 -2268 -1216 -1734 -128 -1076 -1151 -4258 -1389 1257 -1243 -986 -1539 83 -2060 -309 -983 -863 -1315 18 -1071 496 2207 2397 1194 2325 2499 3041 839 1426 2510 -1558 1509 -214 -690 -1443 2802 -351 3144 1577 1182 -3769 175 -1723 -4021 SS 20210423T111603.6Z 7783.469486 182 1 49.16 2 81.28 80.74 112.19 312.11 0.00 1 0.00 1 0 17 7.363e-01 1.439e-02 2.315e-01 4.676e-03 9.953337e-01 2.742426e-03 1.134592e-02 -6.000000e+00 4.300457e-01 228.87 -2.00 3.57 -2.00 322.37 0.00e+00 1.262879e-02 1.691182e-03 3.353175e-03 -6.000000e+00 1.875411e-02 278.29 -2.00 20.00 -2.00 321.93 0.00e+00 6.232 0.005 302.00 328.00 3 8.3163e-01 1.0944e-02 8.3697e-02 -6.0000e+00 1.0727e+00 6.8646e-01 1.7081e-02 6.1448e-02 -6.0000e+00 1.1662e+00 -9.5049e-01 1.8265e-02 3.2477e-02 -6.0000e+00 6.9213e-01 3.8316e-01 8.0605e-03 1.6419e-02 -6.0000e+00 2.8835e-01 1.7645e-04 -3.4345e-04 1.2018e-04 2.7270e-04 -6.0000e+00 2.0337e-02 1.5491e-02 0.0000e+00 12 8 8 10 0 0 21.21 25.39 0.41 0.01549 0.01291 215 44 1 5 0 228.590 25.39 14.99 22.20 -227838 -186410 -226183 -261375 -261038 -245088 -288733 -178103 -134060 -236940 -246951 -164353 -120094 -121454 -78405 -11550 -52112 -15792 -17711 -35654 -80188 -95609 -110756 -94814 -73549 -48747 -45691 -102759 -105429 -32014 -26218 8897 2697 6682 5950 1346 4031 547 21827 20562 18497 35397 1518 -3012 13781 30010 -5770 17367 18028 15445 30975 23264 44148 32127 27660 27118 23749 21663 24046 22065 17057 12384 19036 17358 18563 13763 16904 14302 8863 14575 10934 12395 6480 3682 616 7741 -1162 -2569 3229 2734 2735 3335 1206 -189 1158 2404 1035 1251 2038 1488 -430 -1351 -2862 -3185 -2451 -2009 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