File name: Pandora104s1_Downsview_20210525_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T100110.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20210525_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210525T110001.1Z 7815.458346 204 1 35.42 2 78.19 72.10 109.53 265.37 0.00 1 0.00 1 0 25 3.425e-01 1.681e-02 2.782e-01 1.001e-02 5.628740e-01 5.499342e-03 7.145244e-03 -6.000000e+00 2.024996e-01 231.53 -2.00 3.57 -2.00 321.09 0.00e+00 7.054007e-03 2.458349e-03 4.503233e-03 -6.000000e+00 9.362418e-03 281.86 -2.00 20.00 -2.00 320.49 0.00e+00 4.733 0.002 302.00 328.00 3 4.0299e+00 1.8106e-02 5.7739e-02 -6.0000e+00 5.0769e-01 1.7656e-01 2.3179e-02 3.6285e-02 -6.0000e+00 5.5064e-01 -2.1701e-01 2.1118e-02 2.1509e-02 -6.0000e+00 3.2706e-01 8.1141e-02 1.0246e-02 8.4311e-03 -6.0000e+00 1.3640e-01 4.9003e-05 8.0915e-05 3.0168e-04 1.4265e-04 -6.0000e+00 9.5584e-03 1.0633e-02 0.0000e+00 12 9 9 12 1 1 99.99 26.00 0.48 0.01063 0.01124 20 6 1 5 0 1678.380 26.00 15.00 22.90 -48122 19213 87336 -110088 -142123 -197173 -102476 -86194 -17617 -18079 900000 -53680 900000 -37450 900000 75326 150344 7540 25894 -2445 -7753 -6811 46109 -29498 -911 14496 -76220 -7868 -6716 71299 -34505 -8943 -38882 15 -15526 24532 -15858 34594 14171 21958 12783 11073 8031 -2266 -1694 6210 6540 1336 9250 13684 16725 2738 20715 4765 13997 -5940 5458 6908 9777 8018 5447 -1398 9927 13416 5728 1384 -411 -495 -3540 5011 -3351 1283 -197 -2349 -4704 4940 -1960 1613 3022 3064 -4174 -337 -4363 -1774 589 1110 3538 -3789 -1795 -1245 465 -5136 -1302 -1341 1658 -2810 -391 -809 -498 111 691 -485 633 1078 -522 -1341 3 -477 313 4 -38 443 -146 5 -1545 1424 -703 2410 247 1218 -442 1100 -643 2821 1096 119 -377 -223 -481 -962 -117 -472 364 -381 894 -877 684 -54 158 -554 -178 -79 -101 -483 187 852 -2090 -3385 -7831 -1816 -1454 -172 -178 900000 -914 900000 -858 900000 823 1466 186 565 -73 -244 -211 902 -1237 -31 432 -5271 -283 -245 1374 -2118 -494 -3191 1 -986 1105 -1171 1894 1111 1819 1249 1164 908 -289 -219 768 821 182 1212 1834 2406 494 3377 965 2680 -1419 1189 1463 1985 1673 1233 -375 2668 3822 1786 431 -129 -161 -1336 1967 -1521 570 -86 -998 -1881 1642 -666 547 1146 1361 -2255 -196 -2827 -1185 411 819 2678 -3119 -1437 -953 329 -3616 -851 -921 1242 -2500 -382 -887 -579 126 728 -470 580 1024 -543 -1466 3 -578 413 6 -59 706 -232 8 -2260 1967 -1014 3530 392 1975 -722 1713 -991 4093 1565 166 -511 -319 -767 -1698 -219 -924 739 -823 2026 -2098 1643 -133 386 -1316 -403 -170 -216 SS 20210525T112029.6Z 7815.472565 213 1 15.29 2 74.64 75.39 113.10 268.65 0.00 1 0.00 1 0 17 1.041e-01 6.340e-03 3.418e-02 2.000e-03 4.570022e-01 1.052731e-03 5.357637e-03 -6.000000e+00 6.145480e-02 231.53 -2.00 3.57 -2.00 319.89 0.00e+00 3.524945e-03 3.315490e-04 1.340605e-03 -6.000000e+00 2.691307e-03 281.86 -2.00 20.00 -2.00 319.22 0.00e+00 3.705 0.001 302.00 328.00 3 2.3237e+00 3.0630e-03 4.3842e-02 -6.0000e+00 1.5411e-01 1.0508e-02 3.6656e-03 2.4696e-02 -6.0000e+00 1.6707e-01 -2.1707e-02 3.0137e-03 1.3352e-02 -6.0000e+00 9.9136e-02 -1.1215e-03 1.5442e-03 5.1173e-03 -6.0000e+00 4.1240e-02 8.2610e-04 5.9451e-05 5.9084e-05 5.5306e-05 -6.0000e+00 2.8826e-03 9.9822e-03 0.0000e+00 12 1 1 12 1 1 90.86 26.00 0.32 0.00998 0.01043 57 39 1 5 0 260.610 26.00 15.00 22.85 -17572 -33014 -3370 -58280 -14378 -65547 -26351 -39861 -8908 -35844 -13140 -23076 -3716 -5171 10262 2716 6797 7631 7693 5290 748 -152 -3009 -2112 -10103 -3497 -12456 -2258 -16309 -483 -5981 3856 -76 2635 -3327 2121 -2702 1480 -175 -897 -571 -2087 362 -1776 597 -1211 729 -1243 952 -948 2671 505 3105 1864 2357 671 1099 -962 860 977 2271 2013 2350 2493 319 443 -185 602 613 1144 -723 370 -776 720 -817 476 -950 -785 -663 -628 -1473 -1793 -1875 -1533 -321 -248 594 -19 589 -4 374 -324 -239 -286 499 -43 314 378 -21 -787 -240 -750 237 351 -673 -1299 -313 -497 697 314 403 -283 77 533 47 871 871 659 244 -9 68 172 328 -87 381 227 -285 195 89 -728 -448 -944 -292 -99 327 -227 396 -2 100 -331 383 -96 62 -265 -632 -50 -1374 -204 -1569 -472 -933 -167 -921 -277 -622 -101 -176 357 115 298 361 383 286 43 -9 -188 -141 -774 -258 -996 -158 -1316 -35 -539 355 -8 278 -353 221 -336 213 -31 -182 -115 -451 80 -405 135 -285 184 -300 250 -245 733 155 994 644 836 251 416 -369 318 365 882 867 1112 1277 168 219 -90 296 340 714 -491 255 -530 461 -488 254 -485 -404 -380 -418 -1120 -1406 -1575 -1353 -301 -248 619 -20 617 -4 351 -284 -198 -245 470 -46 349 468 -27 -1019 -287 -883 265 411 -800 -1622 -409 -686 1029 474 651 -468 124 805 72 1268 1292 957 380 -14 111 271 500 -129 577 332 -400 285 135 -1216 -796 -1745 -523 -188 656 -479 847 -4 205 -704 771 -185 117 SS 20210525T115048.4Z 7815.493616 229 1 37.85 2 69.29 80.25 118.39 273.65 0.00 1 0.00 1 0 17 2.102e-02 5.774e-03 5.860e-03 6.922e-04 3.564510e-01 3.616779e-04 4.210821e-03 -6.000000e+00 1.240962e-02 231.53 -2.00 3.57 -2.00 319.07 0.00e+00 1.857843e-03 8.479941e-05 5.585299e-04 -6.000000e+00 5.434741e-04 281.87 -2.00 20.00 -2.00 318.33 0.00e+00 2.800 0.000 302.00 328.00 3 2.0040e+00 1.0059e-03 3.3406e-02 -6.0000e+00 3.1120e-02 4.3157e-03 1.1567e-03 1.8997e-02 -6.0000e+00 3.3736e-02 -1.1313e-02 8.1821e-04 9.4668e-03 -6.0000e+00 2.0019e-02 -4.4611e-03 4.2215e-04 3.0434e-03 -6.0000e+00 8.3275e-03 3.0249e-03 3.7978e-05 2.0825e-05 3.0697e-05 -6.0000e+00 5.8206e-04 1.0189e-02 0.0000e+00 12 1 1 12 1 1 99.99 26.00 0.26 0.01019 0.01047 331 90 1 5 0 113.490 26.00 15.00 22.80 -4019 -2792 -3496 -5112 -8154 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