File name: Pandora104s1_Downsview_20210817_L2Fit_fwvt1c20d20191115p1-8.txt File generation date: 20241127T110921.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20210817_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0388 492.1594 492.2799 492.4004 492.5209 492.6413 492.7618 492.8822 493.0026 493.1230 493.2434 493.3638 493.4841 493.6044 493.7248 493.8450 493.9653 494.0856 494.2058 494.3260 494.4463 494.5664 494.6866 494.8068 494.9269 495.0470 495.1671 495.2872 495.4073 495.5273 495.6474 495.7674 495.8874 496.0073 496.1273 496.2473 496.3672 496.4871 496.6070 496.7269 496.8467 496.9666 497.0864 497.2062 497.3260 497.4457 497.5655 497.6852 497.8050 497.9247 498.0443 498.1640 498.2837 498.4033 498.5229 498.6425 498.7621 498.8816 499.0012 499.1207 499.2402 499.3597 499.4792 499.5986 499.7181 499.8375 499.9569 500.0763 500.1956 500.3150 500.4343 500.5536 500.6729 500.7922 500.9115 501.0307 501.1499 501.2691 501.3883 501.5075 501.6266 501.7458 501.8649 501.9840 502.1031 502.2221 502.3412 502.4602 502.5792 502.6982 502.8172 502.9362 503.0551 503.1740 503.2929 503.4118 503.5307 503.6496 503.7684 503.8872 504.0060 504.1248 504.2435 504.3623 504.4810 504.5997 504.7184 504.8371 504.9558 505.0744 505.1930 505.3116 505.4302 505.5488 505.6673 505.7858 505.9044 506.0228 506.1413 506.2598 506.3782 506.4966 506.6151 506.7334 506.8518 506.9702 507.0885 507.2068 507.3251 507.4434 507.5616 507.6799 507.7981 507.9163 508.0345 508.1527 508.2708 508.3890 508.5071 508.6252 508.7433 508.8613 508.9794 509.0974 509.2154 509.3334 509.4514 509.5693 509.6873 509.8052 509.9231 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210817T134930.4Z 7899.576047 161 1 48.90 2 54.53 107.08 157.47 36.04 0.00 1 0.00 1 0 15 2.350e-03 2.353e-03 8.722e-04 8.701e-04 5.222164e+03 5.551708e+01 3.522913e+02 -6.000000e+00 1.300042e+02 287.31 -2.00 20.00 -2.00 505.27 0.00e+00 7.144758e-04 2.397188e-05 4.562254e-05 -6.000000e+00 6.606973e-05 287.31 -2.00 20.00 -2.00 500.40 0.00e+00 5.951085e-02 1.708727e-02 3.611624e-02 -6.000000e+00 4.612059e-02 231.74 -2.00 3.57 -2.00 502.00 0.00e+00 1.718 0.000 489.00 513.00 1 7.7990e+00 1.3086e-03 4.0276e-03 -6.0000e+00 3.5356e-03 2.6896e-03 3.3897e-04 8.5368e-04 -6.0000e+00 9.2346e-04 6.1807e-04 2.6366e-04 7.4047e-05 3.6707e-05 -6.0000e+00 2.0792e-04 -3.5480e-03 4.4689e-06 10 0 0 10 0 0 98.47 25.68 1.35 -0.00355 -0.00172 16 3 1 4 0 3054.930 25.68 15.00 22.55 -321 -316 -189 -278 -81 -125 395 349 222 285 279 121 -106 -164 -261 -127 123 15 221 -59 -237 462 127 126 323 458 -3 2 -213 -275 -338 -47 -163 171 -18 -304 5 -30 141 -20 199 33 238 118 229 109 292 215 136 -96 -317 -326 -398 -461 -335 -206 -388 -222 -173 158 163 476 167 278 222 232 262 1 -161 -67 -235 -53 -74 -52 -114 -380 -273 217 -155 24 -97 -448 -317 -269 -109 68 -195 -204 99 -73 261 156 376 61 71 -4 255 140 -471 -244 -195 -177 -87 -175 -485 -423 -250 -320 -117 131 37 -180 109 142 191 336 502 469 296 155 131 276 333 296 332 34 -94 170 187 89 180 -124 -47 -224 -227 -57 27 -341 -211 74 107 97 66 174 191 69 -192 -152 -282 -177 -97 -308 -306 -186 -281 -83 -130 415 369 236 299 289 125 -108 -166 -263 -127 124 16 232 -62 -251 487 135 133 343 486 -3 2 -223 -279 -337 -46 -164 175 -19 -323 5 -31 146 -20 204 34 247 124 241 114 307 224 141 -98 -317 -319 -386 -445 -329 -206 -396 -229 -178 162 167 488 172 286 228 236 264 1 -159 -66 -229 -52 -72 -51 -114 -379 -269 210 -149 23 -92 -431 -307 -261 -106 67 -192 -201 97 -72 257 154 375 61 71 -4 248 134 -443 -226 -178 -162 -81 -168 -479 -422 -249 -316 -114 127 36 -178 109 142 192 338 506 475 300 157 130 272 324 287 324 33 -92 167 182 86 175 -120 -45 -212 -214 -54 25 -330 -206 73 106 96 66 173 191 69 -191 -150 -272 -169 -93 SQ 20210817T135954.5Z 7899.583270 164 1 50.06 2 52.75 109.32 156.38 41.04 0.00 1 0.00 1 0 15 2.212e-03 2.212e-03 6.882e-04 6.858e-04 5.037982e+03 4.368103e+01 3.375965e+02 -6.000000e+00 1.223583e+02 287.31 -2.00 20.00 -2.00 505.25 0.00e+00 6.510970e-04 1.883815e-05 4.274272e-05 -6.000000e+00 6.218303e-05 287.31 -2.00 20.00 -2.00 500.36 0.00e+00 6.748930e-04 1.345159e-02 3.473689e-02 -6.000000e+00 4.340977e-02 231.74 -2.00 3.57 -2.00 501.95 0.00e+00 1.648 0.000 489.00 513.00 1 7.4510e+00 1.0294e-03 3.8595e-03 -6.0000e+00 3.3277e-03 4.1374e-03 2.6765e-04 8.1767e-04 -6.0000e+00 8.6923e-04 8.8905e-04 2.8315e-04 5.8264e-05 3.5763e-05 -6.0000e+00 1.9566e-04 -2.9179e-03 -3.5055e-06 10 0 0 10 0 0 99.61 25.68 1.38 -0.00292 -0.00095 24 5 1 4 0 2085.540 25.68 14.99 22.56 -282 -356 -221 -267 -4 60 455 243 374 94 276 199 -42 -114 -39 -167 39 -4 -23 -175 -79 251 140 229 306 293 -70 118 -255 -326 -81 182 -160 127 -101 -174 -82 73 29 36 79 15 220 107 361 34 253 198 194 -227 -243 -483 -309 -392 -276 -245 -498 -146 -339 150 143 229 310 178 116 198 197 60 56 -31 -251 99 -132 -71 -196 -191 -451 263 -130 -270 -268 -73 -79 -392 -169 -13 -66 -110 8 -11 121 27 392 78 27 10 222 -47 -318 -121 -243 -235 -64 -117 -288 -566 -460 -291 -126 158 123 -83 -76 126 185 376 411 448 273 271 205 422 170 270 215 21 281 112 106 138 191 -219 -107 -39 -32 13 -53 -183 -234 -149 40 -34 70 225 117 35 -189 -381 -44 55 -80 -271 -347 -222 -265 -4 62 478 258 398 99 285 204 -42 -113 -38 -165 39 -5 -24 -187 -85 268 150 244 329 316 -75 126 -268 -330 -80 178 -158 131 -109 -189 -88 77 31 37 82 16 230 113 387 35 271 210 202 -233 -242 -468 -294 -370 -267 -246 -515 -153 -356 156 148 239 325 187 121 204 200 60 55 -30 -243 95 -129 -70 -196 -192 -446 252 -123 -256 -254 -70 -76 -380 -165 -13 -66 -110 8 -11 121 27 399 76 28 10 218 -45 -298 -111 -219 -213 -60 -113 -277 -556 -449 -279 -125 156 123 -80 -75 124 184 373 409 451 276 271 202 407 162 269 205 20 268 107 101 131 182 -208 -104 -38 -31 12 -52 -174 -225 -145 39 -33 70 224 117 35 -188 -372 -42 51 -75 SQ 20210817T141024.1Z 7899.590557 168 1 48.21 2 50.98 111.65 155.17 45.68 0.00 1 0.00 1 0 15 2.411e-03 2.410e-03 9.923e-04 9.898e-04 5.769676e+03 6.381775e+01 3.879391e+02 -6.000000e+00 1.333513e+02 287.31 -2.00 20.00 -2.00 505.27 0.00e+00 7.175263e-04 2.726727e-05 4.687186e-05 -6.000000e+00 6.777389e-05 287.31 -2.00 20.00 -2.00 500.38 0.00e+00 4.236115e-02 1.946810e-02 3.928567e-02 -6.000000e+00 4.730518e-02 231.74 -2.00 3.57 -2.00 501.99 0.00e+00 1.585 0.000 489.00 513.00 1 8.0693e+00 1.4908e-03 4.1397e-03 -6.0000e+00 3.6265e-03 3.4681e-03 3.8598e-04 9.2984e-04 -6.0000e+00 9.4708e-04 4.8071e-04 -4.3902e-05 8.3627e-05 3.9725e-05 -6.0000e+00 2.1336e-04 -4.8217e-03 2.1666e-05 10 0 0 10 0 0 33.07 25.68 1.38 -0.00482 -0.00513 13 3 1 4 0 3707.720 25.68 15.00 22.54 -314 -393 -435 -144 -119 3 318 268 491 120 164 358 -226 -230 -292 -69 60 -118 5 -307 178 232 305 272 377 71 189 99 -157 -329 -262 332 -268 143 -88 90 -252 3 -42 -41 73 89 248 50 82 321 333 285 185 -125 -332 -336 -444 -348 -257 -73 -446 -283 -264 154 94 295 271 53 206 0 85 146 20 -67 -255 181 -116 -115 -73 -327 -350 624 66 -31 -152 -124 -282 -129 -239 80 -100 107 -250 -111 221 74 542 179 -43 -22 239 -20 -71 -271 -245 -172 -13 -268 -266 -552 -318 -205 -200 -17 -6 29 -160 250 224 486 245 501 137 196 -92 427 134 549 283 -20 -55 321 229 31 109 -385 -316 -32 -131 -332 -134 -197 -181 53 90 193 106 78 206 -56 -167 -227 -69 -5 -121 -301 -380 -430 -145 -122 3 335 284 520 127 170 369 -232 -233 -295 -69 61 -122 5 -327 188 246 322 287 400 76 200 105 -164 -335 -261 330 -269 146 -93 96 -266 4 -44 -43 75 92 257 52 86 339 350 297 191 -128 -332 -329 -430 -336 -252 -73 -456 -291 -272 158 96 302 280 55 212 0 86 145 20 -66 -249 176 -113 -113 -73 -326 -345 601 63 -29 -145 -119 -273 -124 -233 79 -99 105 -246 -109 217 73 539 180 -43 -22 232 -19 -66 -250 -223 -157 -12 -256 -262 -551 -316 -202 -195 -17 -6 29 -159 250 225 487 247 506 139 197 -92 419 130 530 276 -19 -54 314 222 30 106 -373 -302 -30 -122 -311 -127 -191 -176 52 89 191 105 78 206 -56 -166 -223 -66 -5 -115 SQ 20210817T141525.7Z 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