File name: Pandora104s1_Downsview_20211106_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T115052.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20211106_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211106T124617.8Z 7980.532151 53 1 49.69 2 83.47 119.82 104.29 107.91 0.00 1 0.00 1 0 25 6.176e-01 2.676e-02 4.651e-01 1.917e-02 8.652976e-01 1.144727e-02 9.289611e-03 -6.000000e+00 3.622275e-01 223.39 -2.00 3.57 -2.00 322.24 0.00e+00 -8.540115e-03 6.866624e-03 1.584217e-03 -6.000000e+00 1.860811e-02 278.30 -2.00 20.00 -2.00 321.78 0.00e+00 7.981 0.010 302.00 328.00 3 1.5752e+00 4.5160e-02 9.1957e-02 -6.0000e+00 8.9197e-01 9.1193e-01 6.0904e-02 5.2030e-02 -6.0000e+00 9.7673e-01 -1.1624e+00 5.6052e-02 2.5992e-02 -6.0000e+00 5.7956e-01 4.4798e-01 2.5972e-02 9.6377e-03 -6.0000e+00 2.4494e-01 2.0363e-05 -6.8450e-04 5.5927e-04 1.2212e-04 -6.0000e+00 1.7477e-02 7.3185e-03 0.0000e+00 12 8 8 10 0 0 -22.82 25.28 1.20 0.00732 0.00217 44 9 1 5 0 1129.170 25.28 15.00 21.98 -37645 900000 900000 -34965 -126097 900000 124035 -93228 900000 -56177 -74993 -88235 185716 -172845 900000 -70462 900000 44686 101100 -6 900000 72490 900000 900000 900000 900000 75773 900000 173209 900000 -66590 49941 27524 153169 -33547 54646 -29988 94961 -46304 78451 17667 291859 84080 74674 124766 65114 77031 81141 294434 22398 43635 -19497 18148 16210 23194 34116 18512 20726 17968 19431 23288 16046 24725 955 27745 -269 72671 29001 10100 21921 2578 1489 1059 12677 -417 12286 -5822 9868 -2417 13354 1987 1079 -50 2757 11040 8046 71 4232 2933 -9883 -3218 -8890 -2506 -7024 -1306 -1318 -3128 -3878 1995 -2969 1304 -1336 -346 -4080 324 -3791 -4985 -3385 -1093 -473 927 -663 561 402 -2392 -513 -3569 1540 -1631 1572 1085 3773 832 2925 1221 1821 1658 1686 716 751 -147 122 725 -1260 837 563 -22 590 825 -2189 978 -1687 -915 -702 900000 900000 -652 -2351 900000 2313 -1738 900000 -1047 -1398 -1944 3463 -12598 900000 -2389 900000 833 1885 0 900000 1352 900000 900000 900000 900000 1413 900000 3230 900000 -3160 931 653 2856 -1365 1019 -1322 1771 -3532 2194 988 5442 2508 2367 2326 2185 2298 2421 5490 1378 2441 -2290 1590 1572 2206 3053 1967 2087 1742 1775 2084 1705 2720 150 3466 -44 5826 3839 1845 4046 615 366 251 2458 -82 1924 -1064 1638 -527 2988 582 366 -19 1069 4199 3315 33 1909 1313 -4791 -1374 -3879 -1028 -3300 -674 -801 -2234 -3188 1678 -2602 1014 -946 -224 -2822 232 -2962 -4211 -3049 -1093 -541 1178 -914 779 550 -3246 -667 -4891 2098 -2418 2300 1544 4946 1086 3665 1516 2193 1954 2166 1086 1312 -287 256 1618 -3097 2164 1529 -61 1631 2256 -5860 2355 -3875 -2036 SS 20211106T125734.9Z 7980.539988 56 1 49.66 2 81.72 121.91 102.46 109.66 0.00 1 0.00 1 0 17 5.123e-01 1.277e-02 3.216e-01 6.838e-03 7.552288e-01 3.874456e-03 9.605803e-03 -6.000000e+00 2.936560e-01 223.39 -2.00 3.57 -2.00 321.97 0.00e+00 1.116708e-02 2.208819e-03 7.006657e-03 -6.000000e+00 1.349788e-02 278.30 -2.00 20.00 -2.00 321.49 0.00e+00 6.525 0.005 302.00 328.00 3 1.5674e+00 1.4459e-02 7.9710e-02 -6.0000e+00 7.2313e-01 3.7691e-01 2.1124e-02 5.1617e-02 -6.0000e+00 7.8908e-01 -4.8554e-01 2.2150e-02 3.3965e-02 -6.0000e+00 4.7060e-01 1.8900e-01 1.0134e-02 1.4669e-02 -6.0000e+00 2.0014e-01 9.0322e-05 -5.0692e-04 1.9666e-04 2.5370e-04 -6.0000e+00 1.4390e-02 8.1529e-03 0.0000e+00 12 8 8 10 0 0 84.42 25.28 0.52 0.00815 0.00434 108 22 1 5 0 459.750 25.28 15.01 22.02 -194455 900000 -53694 900000 -217966 35960 -203233 118429 -197874 -66634 -136582 46606 -165974 -165096 -9008 8741 48745 -20382 1098 -20666 30707 -76522 67552 -94969 185521 -85807 -43271 -66446 -70807 -43680 -11664 33046 -18003 -9310 20212 -8980 27166 11050 17133 -9373 -3907 37507 11706 11818 11132 28860 5422 10833 7624 11859 -3939 23522 13484 7677 8246 9185 14363 10656 5507 2299 10940 9194 16060 8523 11736 5348 10987 3554 9376 4376 4973 970 6029 -352 1856 -1537 -211 -1407 -4053 4322 -2253 -1034 -3715 -363 -2444 2286 -1588 1729 -137 1398 -3569 -982 -3298 -788 -3952 -374 -1138 472 404 -1143 -1131 -2208 -303 -1572 271 -3638 -612 -1186 670 -1001 1354 -134 543 -675 394 416 1023 638 455 84 752 1025 969 310 54 564 -217 1095 -439 443 -120 -365 -431 75 -96 -85 248 66 -204 -363 249 -411 159 -2475 900000 -358 900000 -3434 240 -2833 789 -2998 -444 -1242 311 -3420 -4502 -72 70 325 -247 12 -276 266 -1716 450 -2762 1237 -2392 -865 -1530 -1802 -1077 -264 573 -545 -292 445 -269 634 361 628 -466 -201 1500 582 602 587 1462 329 663 513 834 -365 1853 1275 828 914 1041 1558 1175 621 269 1246 1209 2258 1462 2041 972 1917 704 1994 1114 1341 278 1582 -92 427 -333 -44 -316 -1095 1294 -838 -433 -1738 -174 -1272 1199 -908 971 -77 745 -1877 -480 -1627 -410 -2455 -263 -933 435 403 -1144 -1048 -1837 -229 -1241 227 -3311 -576 -1211 754 -1302 1912 -202 819 -1001 553 568 1422 934 705 134 1158 1497 1369 430 73 736 -278 1498 -705 802 -239 -781 -977 182 -248 -231 678 184 -564 -959 612 -952 358 SS 20211106T131449.4Z 7980.551960 61 1 49.76 2 79.13 125.18 99.72 112.37 0.00 1 0.00 1 0 17 3.461e-01 6.379e-03 7.818e-02 1.986e-03 6.195182e-01 1.065847e-03 7.519082e-03 -6.000000e+00 1.983196e-01 223.39 -2.00 3.57 -2.00 321.29 0.00e+00 8.385770e-03 5.204572e-04 3.398996e-03 -6.000000e+00 8.814759e-03 278.30 -2.00 20.00 -2.00 320.77 0.00e+00 5.110 0.003 302.00 328.00 3 1.1962e+00 3.5792e-03 6.0124e-02 -6.0000e+00 4.8855e-01 8.2327e-02 4.9288e-03 3.4829e-02 -6.0000e+00 5.3302e-01 -9.9396e-02 5.0998e-03 2.3943e-02 -6.0000e+00 3.1768e-01 3.0127e-02 2.4250e-03 1.1965e-02 -6.0000e+00 1.3403e-01 5.7691e-04 -6.1884e-05 5.7364e-05 1.5972e-04 -6.0000e+00 9.5683e-03 7.3787e-03 0.0000e+00 10 0 0 10 0 0 40.92 25.28 0.35 0.00738 0.00691 319 65 1 5 0 155.960 25.28 14.99 22.03 -98281 -110606 -126257 -124651 -127170 -110298 -120474 -82185 -128176 -119410 -86592 -74426 -69792 -56234 -26385 -22163 -17615 -15959 -16086 -27524 -14409 -27987 -11374 -20936 -18122 -32773 -18316 -28659 -18459 -15823 -2281 4379 5371 -3450 -13142 -3633 -7691 -1115 -410 -319 -3070 544 2193 1953 1859 1973 3182 4686 3120 5659 4777 5448 5000 3882 4817 1177 2101 -1454 1065 2239 4140 3203 4681 3482 2799 874 1619 700 2629 1548 684 326 -413 -482 -745 -1459 -1199 -2373 -1201 -334 -1384 -1234 -2574 -1391 -853 -295 319 208 557 248 44 -103 -1350 -682 -293 -218 -63 617 281 -719 -63 -767 15 -268 -795 -1786 -476 -631 839 553 883 -120 186 37 112 488 653 274 288 -71 -173 261 565 162 64 384 -471 568 22 -475 -505 -592 -335 -17 102 -106 146 133 104 -200 248 -150 81 -628 -900 -1272 -1159 -1133 -833 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