File name: Pandora104s1_Downsview_20220421_L2Fit_fout2c22d20211217p1-8.txt File generation date: 20241127T133558.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20220421_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 208 350 Nominal wavelengths inside fitting window [nm]: 305.0351 305.1757 305.3162 305.4567 305.5973 305.7378 305.8783 306.0188 306.1593 306.2997 306.4402 306.5806 306.7211 306.8615 307.0019 307.1423 307.2827 307.4231 307.5634 307.7038 307.8441 307.9845 308.1248 308.2651 308.4054 308.5457 308.6860 308.8262 308.9665 309.1067 309.2470 309.3872 309.5274 309.6676 309.8078 309.9480 310.0881 310.2283 310.3684 310.5086 310.6487 310.7888 310.9289 311.0690 311.2091 311.3491 311.4892 311.6292 311.7693 311.9093 312.0493 312.1893 312.3293 312.4693 312.6092 312.7492 312.8891 313.0290 313.1690 313.3089 313.4488 313.5886 313.7285 313.8684 314.0082 314.1481 314.2879 314.4277 314.5675 314.7073 314.8471 314.9869 315.1266 315.2664 315.4061 315.5458 315.6855 315.8252 315.9649 316.1046 316.2443 316.3839 316.5236 316.6632 316.8028 316.9424 317.0820 317.2216 317.3612 317.5008 317.6403 317.7799 317.9194 318.0589 318.1984 318.3379 318.4774 318.6169 318.7563 318.8958 319.0352 319.1747 319.3141 319.4535 319.5929 319.7322 319.8716 320.0110 320.1503 320.2897 320.4290 320.5683 320.7076 320.8469 320.9862 321.1254 321.2647 321.4039 321.5431 321.6824 321.8216 321.9608 322.1000 322.2391 322.3783 322.5174 322.6566 322.7957 322.9348 323.0739 323.2130 323.3521 323.4912 323.6302 323.7693 323.9083 324.0473 324.1863 324.3253 324.4643 324.6033 324.7422 324.8812 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220421T191018.8Z 8146.798829 478 1 27.58 2 40.07 226.36 142.69 282.13 0.00 1 0.00 1 0 33 1.035e-02 6.955e-03 2.955e-04 1.379e-04 2.112841e-01 7.247840e-05 2.597954e-03 -6.000000e+00 6.126828e-03 228.72 -2.00 3.57 -2.00 316.32 0.00e+00 5.804911e-04 7.992033e-06 8.924723e-05 -6.000000e+00 2.637224e-04 278.10 -2.00 20.00 -2.00 315.70 0.00e+00 1.305 0.000 302.00 328.00 3 2.5043e-01 1.8861e-04 1.7002e-02 -6.0000e+00 1.5286e-02 2.4662e-02 2.0968e-04 1.1018e-02 -6.0000e+00 1.6538e-02 -8.1126e-03 1.2183e-04 5.4232e-03 -6.0000e+00 9.8203e-03 -4.2177e-03 5.6540e-05 1.5530e-03 -6.0000e+00 4.1579e-03 8.9004e-02 -7.8109e-05 4.1348e-06 1.8417e-05 -6.0000e+00 2.8617e-04 3.1408e-03 0.0000e+00 11 8 0 10 0 0 46.00 21.79 0.32 0.00314 0.00255 2727 559 1 5 0 9.850 21.79 14.83 18.61 756 -1206 -910 -2321 -3190 -2022 -1506 -66 -550 -1789 -3306 -2785 -462 -420 281 322 -152 835 1291 1376 1733 835 1581 1237 980 244 -398 -942 -553 -239 755 828 110 -482 -3810 -2822 -1988 -923 -318 -721 -844 -909 -519 -343 -6 355 -313 7 -303 56 942 1339 859 1038 869 903 930 615 337 892 1151 1739 1383 1106 613 -727 -6 172 572 1633 1 153 -339 -115 79 -421 -324 -932 -851 -737 -1553 -1857 -2025 -2257 -954 -494 54 112 -50 273 146 502 196 405 867 545 149 -100 -46 -640 -852 -432 -272 333 -61 -1077 -1133 -340 -362 845 367 606 -130 549 350 816 832 999 294 342 -457 -116 -187 400 97 752 302 567 689 -31 -379 -487 -616 77 38 368 -248 376 -136 -129 -398 4 -560 135 -239 -183 -453 -556 -325 -246 -12 -111 -385 -714 -592 -105 -108 81 102 -50 278 445 485 632 302 568 463 389 101 -165 -373 -204 -84 268 315 45 -208 -1600 -1121 -828 -437 -162 -429 -553 -626 -367 -245 -4 250 -218 5 -199 36 618 935 635 801 691 728 703 509 276 717 939 1367 1175 999 569 -640 -6 142 479 1401 1 154 -346 -114 75 -363 -273 -732 -665 -634 -1380 -1820 -2146 -2499 -1104 -565 65 141 -63 338 170 580 206 396 866 590 178 -120 -59 -852 -1082 -504 -321 393 -72 -1370 -1496 -468 -514 1258 535 906 -191 812 476 1025 1097 1249 389 488 -685 -175 -274 566 131 969 400 721 909 -41 -528 -700 -893 114 60 563 -394 608 -223 -212 -636 7 -904 SS 20220421T191046.5Z 8146.799150 478 2 27.46 2 40.13 226.50 142.77 282.23 0.00 1 0.00 1 0 33 1.033e-02 6.967e-03 2.938e-04 1.371e-04 2.116658e-01 7.215234e-05 2.607138e-03 -6.000000e+00 6.115685e-03 228.72 -2.00 3.57 -2.00 316.32 0.00e+00 5.742223e-04 7.944453e-06 9.026568e-05 -6.000000e+00 2.632430e-04 278.10 -2.00 20.00 -2.00 315.69 0.00e+00 1.307 0.000 302.00 328.00 3 2.4114e-01 1.8770e-04 1.7031e-02 -6.0000e+00 1.5259e-02 2.5221e-02 2.0854e-04 1.1048e-02 -6.0000e+00 1.6508e-02 -8.3931e-03 1.2128e-04 5.4396e-03 -6.0000e+00 9.8025e-03 -4.0587e-03 5.6303e-05 1.5571e-03 -6.0000e+00 4.1503e-03 8.9654e-02 -8.4493e-05 4.1072e-06 1.8507e-05 -6.0000e+00 2.8565e-04 3.1527e-03 0.0000e+00 11 8 0 10 0 0 29.08 21.69 0.32 0.00315 0.00252 2727 559 1 5 0 9.850 21.69 14.90 18.61 688 -1313 -916 -2321 -3200 -1987 -1511 -92 -557 -1732 -3198 -2776 -395 -428 299 355 -124 857 1276 1325 1773 822 1550 1275 926 229 -410 -959 -599 -204 746 853 93 -434 -3862 -2797 -1963 -993 -321 -722 -827 -913 -490 -331 2 377 -301 -12 -311 65 942 1352 835 1051 862 898 897 619 319 855 1132 1732 1387 1121 591 -722 -28 203 597 1654 9 149 -345 -93 79 -430 -332 -942 -834 -748 -1568 -1871 -2032 -2232 -946 -484 76 118 -51 281 143 506 198 393 870 525 119 -85 -39 -625 -851 -442 -292 355 -75 -1068 -1148 -336 -379 865 358 610 -121 565 368 817 856 999 285 364 -455 -103 -201 378 135 762 293 582 698 -56 -384 -494 -617 86 42 376 -249 383 -125 -135 -388 -3 -573 123 -260 -184 -452 -558 -320 -247 -17 -113 -373 -689 -590 -90 -110 86 112 -41 285 440 467 646 297 557 477 368 95 -171 -380 -221 -72 264 324 38 -188 -1623 -1111 -817 -470 -164 -431 -542 -629 -346 -237 1 266 -210 -8 -205 42 618 945 618 811 686 725 679 513 261 688 924 1362 1179 1012 550 -636 -25 167 500 1420 8 149 -351 -92 75 -371 -280 -741 -653 -644 -1394 -1835 -2156 -2474 -1096 -554 92 148 -65 348 167 585 208 385 869 570 142 -103 -50 -833 -1082 -517 -345 419 -89 -1359 -1519 -463 -540 1288 523 914 -177 837 502 1029 1042 1250 377 520 -682 -156 -294 536 183 983 388 740 923 -74 -536 -711 -896 127 66 577 -396 619 -207 -223 -621 -4 -925 SS 20220421T191951.7Z 8146.805460 481 1 3.87 2 41.34 229.35 144.27 284.21 0.00 1 0.00 1 0 17 1.498e-02 9.718e-03 1.021e-02 5.710e-03 2.193661e-01 3.016437e-03 2.734589e-03 -6.000000e+00 8.870128e-03 228.72 -2.00 3.57 -2.00 315.71 0.00e+00 6.854596e-04 2.942415e-04 7.575988e-05 -6.000000e+00 3.817964e-04 278.10 -2.00 20.00 -2.00 315.14 0.00e+00 1.330 0.000 302.00 328.00 3 5.2533e+00 7.7959e-03 1.7517e-02 -6.0000e+00 2.2131e-02 5.8647e-02 8.6550e-03 1.1508e-02 -6.0000e+00 2.3941e-02 -1.1505e-02 4.9753e-03 5.6621e-03 -6.0000e+00 1.4217e-02 -2.6526e-03 2.2502e-03 1.6326e-03 -6.0000e+00 6.0207e-03 5.6644e-04 2.0652e-04 1.6755e-04 1.9983e-05 -6.0000e+00 4.1403e-04 1.8565e-03 0.0000e+00 12 9 9 12 1 1 999.00 21.79 0.48 0.00186 0.00341 1 6 1 5 0 1844.140 21.79 14.77 18.71 -4016 691 -698 -1326 2 -4241 1627 -625 2270 -3332 219 -5603 2702 -1550 2452 692 974 1367 2612 967 1077 739 100 -857 517 1131 -133 1777 -2 2515 -1638 1948 -424 -632 -5783 -3038 -4188 -3312 -1371 -2142 -854 -523 -1597 -684 176 -83 82 1087 736 696 2414 932 1753 184 1706 1521 1982 1533 -214 1378 585 2402 1100 937 578 -453 -280 1227 630 1303 -510 89 -440 135 -625 -1027 -546 -2038 -760 -1600 -1214 -1727 -2535 -2684 -135 -84 860 239 149 269 69 428 359 -485 830 889 445 -910 55 -599 -1336 -793 -1209 174 -454 -887 -914 113 -684 1672 -452 944 365 1040 -235 1230 256 1011 272 105 1 -77 92 245 341 432 356 394 605 859 -1016 -340 202 148 132 367 -325 177 172 -120 -836 -342 -696 -956 169 -177 -325 0 -916 341 -147 572 -918 58 -1553 760 -498 843 260 376 537 1048 402 458 313 43 -379 236 528 -63 796 -1 1034 -708 867 -201 -313 -2845 -1421 -2061 -1790 -828 -1443 -609 -384 -1205 -518 133 -63 61 791 527 495 1732 706 1369 149 1401 1264 1666 1296 -181 1148 495 2086 1009 894 561 -425 -248 1047 547 1216 -509 91 -456 138 -621 -967 -480 -1724 -638 -1437 -1167 -1764 -2728 -2964 -153 -98 1043 297 186 333 83 486 386 -502 868 977 517 -1122 71 -781 -1698 -961 -1412 202 -554 -1127 -1187 150 -929 2323 -653 1376 525 1448 -315 1563 321 1287 358 145 2 -110 128 335 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