File name: Pandora104s1_Downsview_20220427_L2Fit_fout2c22d20211217p1-8.txt
File generation date: 20241127T133601.4Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c22p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt
Level 1 file used: Pandora104s1_Downsview_20220427_L1_smca1c22d20211217p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20220427
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217"
First and last pixel inside fitting window: 208 350
Nominal wavelengths inside fitting window [nm]: 305.0351 305.1757 305.3162 305.4567 305.5973 305.7378 305.8783 306.0188 306.1593 306.2997 306.4402 306.5806 306.7211 306.8615 307.0019 307.1423 307.2827 307.4231 307.5634 307.7038 307.8441 307.9845 308.1248 308.2651 308.4054 308.5457 308.6860 308.8262 308.9665 309.1067 309.2470 309.3872 309.5274 309.6676 309.8078 309.9480 310.0881 310.2283 310.3684 310.5086 310.6487 310.7888 310.9289 311.0690 311.2091 311.3491 311.4892 311.6292 311.7693 311.9093 312.0493 312.1893 312.3293 312.4693 312.6092 312.7492 312.8891 313.0290 313.1690 313.3089 313.4488 313.5886 313.7285 313.8684 314.0082 314.1481 314.2879 314.4277 314.5675 314.7073 314.8471 314.9869 315.1266 315.2664 315.4061 315.5458 315.6855 315.8252 315.9649 316.1046 316.2443 316.3839 316.5236 316.6632 316.8028 316.9424 317.0820 317.2216 317.3612 317.5008 317.6403 317.7799 317.9194 318.0589 318.1984 318.3379 318.4774 318.6169 318.7563 318.8958 319.0352 319.1747 319.3141 319.4535 319.5929 319.7322 319.8716 320.0110 320.1503 320.2897 320.4290 320.5683 320.7076 320.8469 320.9862 321.1254 321.2647 321.4039 321.5431 321.6824 321.8216 321.9608 322.1000 322.2391 322.3783 322.5174 322.6566 322.7957 322.9348 323.0739 323.2130 323.3521 323.4912 323.6302 323.7693 323.9083 324.0473 324.1863 324.3253 324.4643 324.6033 324.7422 324.8812
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20220427T114511.3Z 8152.489714 91 1 49.71 2 75.12 84.83 65.45 125.95 0.00 1 0.00 1 0 17 2.174e-01 5.483e-03 3.909e-02 8.857e-04 6.138111e-01 4.864987e-04 7.190730e-03 -6.000000e+00 1.289735e-01 229.24 -2.00 3.57 -2.00 320.88 0.00e+00 6.244530e-03 2.058440e-04 1.958313e-03 -6.000000e+00 5.556022e-03 278.75 -2.00 20.00 -2.00 320.36 0.00e+00 3.818 0.001 302.00 328.00 3 9.1996e-01 1.5420e-03 5.0317e-02 -6.0000e+00 3.2212e-01 7.1134e-02 2.0444e-03 3.3871e-02 -6.0000e+00 3.4833e-01 -4.1528e-02 2.0610e-03 2.1562e-02 -6.0000e+00 2.0683e-01 2.4139e-03 1.0084e-03 1.0476e-02 -6.0000e+00 8.7519e-02 2.3330e-03 -1.9405e-04 2.6042e-05 1.1819e-04 -6.0000e+00 6.0145e-03 3.8642e-03 0.0000e+00 10 0 0 10 0 0 99.94 21.69 0.23 0.00386 0.00241 800 164 1 5 0 62.110 21.69 14.91 18.51 -67169 -42678 -71669 -54206 -83894 -69538 -90093 -67187 -79102 -64629 -66838 -61805 -52003 -35092 -19311 -12023 -9053 -11020 -6969 -7267 -8613 -8812 -4529 -13337 -12231 -15170 -15664 -15118 -15596 -13299 -5896 -4012 506 -2033 -6840 -3374 -3886 -929 -449 -955 -2190 -907 -1882 -158 471 1377 1155 1944 1450 1627 2279 3399 3289 2976 1878 652 439 -577 -997 67 1191 2656 3428 2959 2728 1111 1232 892 1073 2147 579 176 -531 -562 -619 -1355 -1135 -1840 -1429 -815 -1167 -1063 -1574 -2126 -1012 -232 341 352 167 436 485 484 -200 -351 178 272 231 272 290 -216 -561 -478 -26 572 -90 -1166 -1181 -309 -214 929 235 312 -424 253 -26 488 671 934 249 191 -504 133 115 519 -152 121 -262 153 423 -280 -565 -535 -742 -50 -106 209 -306 473 14 -23 -187 390 23 -366 -217 -539 -346 -667 -463 -770 -517 -772 -592 -658 -641 -620 -461 -277 -178 -149 -206 -138 -153 -194 -198 -100 -342 -335 -450 -480 -457 -476 -420 -201 -164 23 -105 -363 -169 -210 -57 -33 -85 -224 -99 -221 -19 58 173 149 258 202 239 363 602 587 577 391 142 99 -133 -226 16 290 692 916 891 894 367 394 290 371 850 258 83 -253 -256 -263 -571 -440 -707 -586 -389 -599 -621 -1028 -1482 -740 -180 277 298 141 361 379 353 -139 -241 133 231 225 300 356 -276 -688 -532 -26 554 -94 -1304 -1376 -381 -281 1342 348 496 -687 398 -41 746 1002 1442 405 329 -814 226 187 814 -230 177 -369 212 641 -483 -993 -1008 -1457 -103 -233 488 -735 1144 35 -56 -429 840 48
SS 20220427T115504.7Z 8152.496582 94 1 10.22 2 73.34 86.50 64.03 128.09 0.00 1 0.00 1 0 25 1.227e-01 6.128e-03 3.299e-02 1.354e-03 5.586974e-01 7.259667e-04 6.540964e-03 -6.000000e+00 7.277454e-02 229.24 -2.00 3.57 -2.00 319.97 0.00e+00 3.967997e-03 2.340889e-04 8.857055e-04 -6.000000e+00 3.134969e-03 278.75 -2.00 20.00 -2.00 319.40 0.00e+00 3.434 0.001 302.00 328.00 3 1.3258e+00 2.1026e-03 4.5097e-02 -6.0000e+00 1.8176e-01 6.4079e-02 2.5522e-03 2.9799e-02 -6.0000e+00 1.9655e-01 -3.3611e-02 2.2834e-03 1.6294e-02 -6.0000e+00 1.1670e-01 -1.9712e-04 1.1766e-03 6.7704e-03 -6.0000e+00 4.9387e-02 2.3801e-03 -1.8681e-04 3.8876e-05 6.8553e-05 -6.0000e+00 3.3934e-03 3.3982e-03 0.0000e+00 12 1 1 12 1 1 95.71 21.69 0.22 0.00340 0.00199 106 109 1 5 0 93.860 21.69 14.92 18.53 -48623 -43427 -39997 -34460 -29408 -37707 -37295 -43339 -22275 -43080 -34077 -46633 -22997 -25676 -14997 -12479 -7807 -9194 -2491 -6249 -2858 -1135 -2512 461 -3513 -2788 -6462 -4367 -7557 -5446 -3815 451 -1240 -904 -7604 -3990 -5980 -2782 -2267 -1305 -1865 -288 -1034 293 772 1788 1735 1096 1565 1264 2283 2210 1653 1422 1832 498 198 -1095 -1228 -228 731 2190 2490 1897 1791 580 1155 1444 1209 2232 381 183 -310 -161 -682 -887 -940 -1341 -1481 -892 -1117 -1378 -1645 -2301 -1165 -438 540 216 167 606 588 1042 679 91 476 311 138 -15 64 -581 -746 -372 -249 507 132 -1073 -1194 -280 -109 729 99 405 -380 240 140 844 834 1083 92 179 -499 85 -60 374 -304 270 -192 220 590 -192 -540 -620 -484 56 4 248 -333 405 -86 -33 -235 298 -12 -546 -545 -528 -432 -322 -433 -448 -629 -297 -698 -580 -890 -428 -623 -409 -398 -268 -351 -97 -267 -125 -48 -111 21 -182 -151 -372 -242 -428 -313 -245 33 -106 -85 -747 -368 -604 -318 -288 -196 -318 -52 -200 58 154 362 358 233 343 290 562 609 500 465 631 180 74 -419 -462 -83 270 861 1008 859 874 282 535 670 597 1258 242 122 -210 -105 -416 -490 -477 -666 -780 -542 -789 -1029 -1364 -2033 -1079 -402 519 216 167 593 581 955 587 78 436 302 153 -17 83 -781 -962 -465 -282 557 156 -1362 -1481 -366 -151 1042 156 679 -610 395 216 1230 1263 1592 143 295 -840 139 -95 569 -445 406 -277 310 902 -312 -912 -1115 -901 109 9 517 -718 881 -180 -71 -487 581 -24
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