File name: Pandora104s1_Downsview_20220512_L2Fit_fout2c22d20211217p1-8.txt File generation date: 20241127T133848.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20220512_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 208 350 Nominal wavelengths inside fitting window [nm]: 305.0351 305.1757 305.3162 305.4567 305.5973 305.7378 305.8783 306.0188 306.1593 306.2997 306.4402 306.5806 306.7211 306.8615 307.0019 307.1423 307.2827 307.4231 307.5634 307.7038 307.8441 307.9845 308.1248 308.2651 308.4054 308.5457 308.6860 308.8262 308.9665 309.1067 309.2470 309.3872 309.5274 309.6676 309.8078 309.9480 310.0881 310.2283 310.3684 310.5086 310.6487 310.7888 310.9289 311.0690 311.2091 311.3491 311.4892 311.6292 311.7693 311.9093 312.0493 312.1893 312.3293 312.4693 312.6092 312.7492 312.8891 313.0290 313.1690 313.3089 313.4488 313.5886 313.7285 313.8684 314.0082 314.1481 314.2879 314.4277 314.5675 314.7073 314.8471 314.9869 315.1266 315.2664 315.4061 315.5458 315.6855 315.8252 315.9649 316.1046 316.2443 316.3839 316.5236 316.6632 316.8028 316.9424 317.0820 317.2216 317.3612 317.5008 317.6403 317.7799 317.9194 318.0589 318.1984 318.3379 318.4774 318.6169 318.7563 318.8958 319.0352 319.1747 319.3141 319.4535 319.5929 319.7322 319.8716 320.0110 320.1503 320.2897 320.4290 320.5683 320.7076 320.8469 320.9862 321.1254 321.2647 321.4039 321.5431 321.6824 321.8216 321.9608 322.1000 322.2391 322.3783 322.5174 322.6566 322.7957 322.9348 323.0739 323.2130 323.3521 323.4912 323.6302 323.7693 323.9083 324.0473 324.1863 324.3253 324.4643 324.6033 324.7422 324.8812 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220512T105049.0Z 8167.451956 169 1 50.18 2 81.61 72.80 116.11 301.73 0.00 1 0.00 1 0 25 5.367e-01 1.968e-02 3.496e-01 1.317e-02 7.985585e-01 8.330932e-03 9.911994e-03 -6.000000e+00 3.308473e-01 230.60 -2.00 3.57 -2.00 321.94 0.00e+00 1.226792e-02 4.652952e-03 6.610902e-03 -6.000000e+00 1.786867e-02 280.47 -2.00 20.00 -2.00 321.48 0.00e+00 6.444 0.005 302.00 328.00 3 2.6044e+00 3.1522e-02 8.1216e-02 -6.0000e+00 8.3275e-01 5.6079e-01 4.5104e-02 5.2876e-02 -6.0000e+00 9.0607e-01 -6.7208e-01 4.6173e-02 3.3549e-02 -6.0000e+00 5.3249e-01 2.6713e-01 2.1155e-02 1.4810e-02 -6.0000e+00 2.2591e-01 2.9087e-05 -8.5648e-04 4.1348e-04 2.9316e-04 -6.0000e+00 1.5441e-02 4.2470e-03 0.0000e+00 12 8 8 10 0 0 37.22 21.88 1.01 0.00425 -0.00219 28 6 1 5 0 1791.860 21.88 14.75 18.73 -260110 900000 900000 16626 900000 900000 900000 -109405 -254089 900000 -167341 900000 900000 900000 900000 900000 -45253 900000 900000 -106595 16073 -77586 900000 900000 125935 -2799 900000 -3799 900000 -2657 900000 900000 900000 -18260 242278 146084 -66858 -814 12975 74975 559 120193 8655 43153 35462 27871 -10902 44595 13085 57628 -24920 66235 15535 36576 8126 19993 -3400 4717 9116 31837 28 3576 27146 14236 18238 15727 22815 10951 15673 9542 14435 6841 8929 -468 4092 -6238 84 -4876 -4163 -1100 -5149 -5551 -6190 2051 -1518 3450 -482 2082 1472 4329 -2383 1600 -1481 1018 -6529 640 -1839 -1015 -646 -2051 577 -59 -2577 -3094 -2449 -1993 -2841 -3415 234 49 2822 -724 -55 -1475 -931 -78 -16 394 762 -216 368 2948 1596 2163 548 1656 -719 387 -860 377 -945 1372 -629 433 125 861 -346 484 -77 -705 -588 -301 -348 -6929 900000 900000 213 900000 900000 900000 -1399 -7310 900000 -2140 900000 900000 900000 900000 900000 -684 900000 900000 -3717 206 -1984 900000 900000 1610 -36 900000 -49 900000 -37 900000 900000 900000 -594 3098 1868 -3419 -25 407 1482 26 1816 423 1555 1402 1231 -735 1814 776 2345 -2549 3080 1318 2721 850 1906 -419 532 954 2590 3 428 2935 2002 2735 2450 3262 1820 2678 2008 3205 1717 2190 -119 913 -1385 16 -997 -934 -288 -1670 -2091 -2641 861 -699 1608 -246 1077 767 2143 -1194 725 -666 453 -3506 375 -1297 -819 -588 -1984 523 -49 -1950 -2255 -1876 -1624 -2440 -3172 228 55 3454 -1009 -78 -2133 -1290 -103 -21 534 1078 -325 551 4142 2150 2830 704 2056 -880 470 -1186 597 -1705 2635 -1305 949 293 2150 -898 1259 -203 -1831 -1434 -683 -740 SS 20220512T110602.1Z 8167.462524 174 1 49.94 2 78.97 75.30 118.37 304.96 0.00 1 0.00 1 0 17 5.800e-01 1.075e-02 2.677e-01 4.307e-03 6.672411e-01 2.473914e-03 8.377226e-03 -6.000000e+00 3.459086e-01 230.60 -2.00 3.57 -2.00 321.45 0.00e+00 6.710218e-03 1.221012e-03 5.686175e-03 -6.000000e+00 1.499314e-02 280.47 -2.00 20.00 -2.00 320.94 0.00e+00 5.039 0.002 302.00 328.00 3 2.4612e+00 8.6003e-03 6.5787e-02 -6.0000e+00 8.6622e-01 1.5840e-01 1.1954e-02 4.7450e-02 -6.0000e+00 9.3604e-01 -1.7936e-01 1.2248e-02 2.8850e-02 -6.0000e+00 5.5525e-01 6.4785e-02 5.7681e-03 1.0737e-02 -6.0000e+00 2.3594e-01 1.5427e-04 -2.7536e-04 1.3108e-04 1.8795e-04 -6.0000e+00 1.6216e-02 4.4079e-03 0.0000e+00 12 9 8 11 8 0 99.96 21.88 0.48 0.00441 0.00234 81 17 1 5 0 616.490 21.88 14.71 18.73 900000 -162879 -65046 -148923 -160898 -141694 -211188 -112062 -179678 -33461 -173661 112160 -134049 54256 -40993 319838 -53443 124717 -50148 221102 -13647 107223 12943 -14975 -19395 -12861 -33954 -62003 -4635 -54881 10425 -39273 37191 -13647 13308 -10965 24075 6915 22069 -814 25074 2432 7121 240 6529 3428 4681 3770 -3285 13839 -3219 10253 -2303 13736 83 8260 1135 7336 1444 8878 5494 9804 3833 7184 7864 3231 2833 1019 4782 670 3146 -920 -473 -2446 607 -3859 -832 -3600 1835 -124 493 -1614 -862 -2191 -895 -1434 -584 758 -221 151 -1019 840 -2377 20 -2742 903 -1632 1426 -105 384 -1210 -372 -729 918 -188 -1538 -1237 -983 153 482 467 59 -15 -411 91 -410 818 930 735 213 381 739 1418 945 135 -89 -516 -298 385 -69 -958 -337 -1150 -214 -145 619 -222 621 69 212 -719 442 -313 900000 -1653 -298 -1592 -1781 -1244 -3548 -856 -2767 -141 -2856 471 -2303 228 -470 1343 -979 524 -1091 929 -229 532 168 -274 -400 -260 -869 -2083 -88 -1844 215 -1634 838 -573 417 -427 708 282 944 -48 1407 170 506 19 496 278 387 327 -322 1216 -368 1159 -325 1793 13 1258 192 1173 240 1348 882 1640 771 1579 1877 806 692 259 1257 213 1082 -347 -179 -900 201 -1207 -233 -1031 588 -44 204 -781 -463 -1269 -543 -936 -399 532 -157 104 -675 513 -1425 12 -1812 663 -1419 1367 -114 433 -1328 -368 -653 787 -173 -1535 -1285 -1089 181 635 683 94 -25 -656 137 -596 1154 1362 1130 348 626 1177 2136 1397 194 -124 -695 -398 564 -115 -1797 -677 -2435 -478 -345 1555 -579 1627 184 554 -1795 1026 -693 SS 20220512T111204.6Z 8167.466719 177 1 49.92 2 77.91 76.29 119.24 306.29 0.00 1 0.00 1 0 25 3.471e-01 8.394e-03 1.481e-01 3.240e-03 6.133217e-01 1.810700e-03 7.579486e-03 -6.000000e+00 2.069077e-01 230.60 -2.00 3.57 -2.00 321.13 0.00e+00 8.021723e-03 8.221404e-04 3.825817e-03 -6.000000e+00 8.932681e-03 280.47 -2.00 20.00 -2.00 320.59 0.00e+00 4.631 0.002 302.00 328.00 3 2.4599e+00 5.9948e-03 5.7836e-02 -6.0000e+00 5.1816e-01 1.0817e-01 8.0583e-03 3.7347e-02 -6.0000e+00 5.5966e-01 -1.1682e-01 8.0407e-03 2.5202e-02 -6.0000e+00 3.3227e-01 3.8126e-02 3.8603e-03 1.1605e-02 -6.0000e+00 1.4039e-01 2.4015e-04 -2.2802e-04 9.7318e-05 1.6258e-04 -6.0000e+00 9.6075e-03 5.1917e-03 0.0000e+00 11 8 0 10 0 0 99.98 21.88 0.29 0.00519 0.00348 100 20 1 5 0 499.080 21.88 14.95 18.65 -32085 -140355 -24695 -142256 -101213 -156938 -117434 -144786 -35665 -134554 -23068 -144114 -69442 -23038 -1558 -12935 -12166 -22747 9703 5155 -21850 -6901 -30290 1354 -22586 -26138 -35779 -4438 -17621 -9944 -5258 17570 1936 20044 -1639 5817 -1003 4924 -142 -1174 -1804 -1761 -4283 -981 6971 -2297 6245 130 2998 3065 8510 4090 5953 3729 8083 3404 1900 -274 -561 132 2240 5458 2460 4168 2866 2231 875 1908 571 3764 1355 451 12 947 -1169 -607 -2328 -2253 -2151 -1153 -1733 -1540 -1332 -3350 -877 -1209 873 -254 810 893 842 61 -289 -692 13 -257 337 -341 108 -135 -963 -497 -685 401 -925 -1090 -1764 -54 -404 1435 380 630 -565 231 -395 366 569 1366 464 276 -90 528 505 178 274 114 -376 -161 660 -412 -489 -647 -579 -177 -192 302 -152 453 197 -24 -407 334 -158 -119 -1724 -112 -1969 -885 -2228 -1192 -2111 -206 -2111 -132 -2831 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