File name: Pandora104s1_Downsview_20220627_L2Fit_fout2c22d20211217p1-8.txt File generation date: 20241127T142420.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20220627_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 208 350 Nominal wavelengths inside fitting window [nm]: 305.0351 305.1757 305.3162 305.4567 305.5973 305.7378 305.8783 306.0188 306.1593 306.2997 306.4402 306.5806 306.7211 306.8615 307.0019 307.1423 307.2827 307.4231 307.5634 307.7038 307.8441 307.9845 308.1248 308.2651 308.4054 308.5457 308.6860 308.8262 308.9665 309.1067 309.2470 309.3872 309.5274 309.6676 309.8078 309.9480 310.0881 310.2283 310.3684 310.5086 310.6487 310.7888 310.9289 311.0690 311.2091 311.3491 311.4892 311.6292 311.7693 311.9093 312.0493 312.1893 312.3293 312.4693 312.6092 312.7492 312.8891 313.0290 313.1690 313.3089 313.4488 313.5886 313.7285 313.8684 314.0082 314.1481 314.2879 314.4277 314.5675 314.7073 314.8471 314.9869 315.1266 315.2664 315.4061 315.5458 315.6855 315.8252 315.9649 316.1046 316.2443 316.3839 316.5236 316.6632 316.8028 316.9424 317.0820 317.2216 317.3612 317.5008 317.6403 317.7799 317.9194 318.0589 318.1984 318.3379 318.4774 318.6169 318.7563 318.8958 319.0352 319.1747 319.3141 319.4535 319.5929 319.7322 319.8716 320.0110 320.1503 320.2897 320.4290 320.5683 320.7076 320.8469 320.9862 321.1254 321.2647 321.4039 321.5431 321.6824 321.8216 321.9608 322.1000 322.2391 322.3783 322.5174 322.6566 322.7957 322.9348 323.0739 323.2130 323.3521 323.4912 323.6302 323.7693 323.9083 324.0473 324.1863 324.3253 324.4643 324.6033 324.7422 324.8812 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220627T104333.0Z 8213.446910 95 1 49.65 2 80.45 66.77 66.35 77.93 0.00 1 0.00 1 0 17 5.526e-01 8.414e-03 1.504e-01 2.595e-03 7.090368e-01 1.508508e-03 9.030165e-03 -6.000000e+00 3.328784e-01 232.95 -2.00 3.57 -2.00 321.62 0.00e+00 9.544880e-03 8.264070e-04 6.660960e-03 -6.000000e+00 1.452045e-02 285.15 -2.00 20.00 -2.00 321.09 0.00e+00 5.740 0.004 302.00 328.00 3 7.1710e-01 5.6042e-03 7.4163e-02 -6.0000e+00 8.3717e-01 1.2732e-01 8.1120e-03 5.3240e-02 -6.0000e+00 9.0118e-01 -1.6878e-01 8.3099e-03 3.1850e-02 -6.0000e+00 5.3556e-01 6.0564e-02 3.8136e-03 1.1566e-02 -6.0000e+00 2.2684e-01 4.5250e-04 -4.9604e-04 7.5312e-05 2.0455e-04 -6.0000e+00 1.5214e-02 -8.8252e-03 0.0000e+00 11 8 0 10 0 0 85.66 22.09 0.31 -0.00883 -0.01255 317 65 1 5 0 156.600 22.09 14.89 18.85 -252030 -142409 -191905 -162491 -198823 -162605 -197392 -95380 -205361 -83371 -180612 -90550 -113378 -83229 -110888 -57744 -55382 -43173 -42133 -48634 -39175 -46498 -20818 -57541 -25426 -53817 -32571 -44984 -33049 -46812 4989 -28765 -2959 -10433 -212 -15648 -7736 -2286 -969 -1572 -3160 -803 -5158 5472 1583 11356 1027 8291 5408 12568 6204 15005 4117 7863 3672 6030 2409 2338 -878 3199 1610 5289 4970 5879 5774 2684 4944 3643 3475 3887 3945 1043 1467 410 452 -2241 -1282 -2827 -2426 -1181 -750 -1347 -990 -1434 -1477 -247 121 229 280 1178 100 960 -744 -1298 -1432 -280 -199 -362 329 -326 -1077 -635 -778 -484 -725 -1751 -2061 -673 -265 896 513 490 137 99 -119 129 454 960 571 355 168 419 428 881 29 195 -221 225 665 -189 -532 -422 -844 -26 -346 315 -268 640 55 79 -484 280 -200 -2668 -685 -1546 -1110 -1812 -988 -1749 -338 -2443 -317 -1920 -435 -890 -653 -1516 -585 -645 -503 -544 -714 -555 -706 -248 -1049 -360 -1062 -536 -843 -560 -983 74 -757 -71 -309 -6 -471 -229 -75 -35 -68 -158 -43 -309 311 96 653 68 538 384 891 517 1302 442 888 464 773 333 326 -124 429 225 774 833 1112 1214 592 1042 798 817 1055 1202 347 491 133 137 -630 -329 -732 -677 -386 -290 -605 -499 -780 -852 -151 78 154 190 778 64 567 -427 -746 -905 -203 -167 -350 327 -343 -1104 -646 -712 -424 -673 -1763 -2173 -750 -317 1192 703 734 212 151 -175 182 625 1365 855 565 270 655 636 1388 44 290 -318 320 1036 -312 -987 -849 -1794 -59 -831 807 -712 1712 151 212 -1242 671 -454 SS 20220627T105132.7Z 8213.452462 100 1 49.23 2 79.12 68.05 64.97 79.13 0.00 1 0.00 1 0 25 3.992e-01 2.801e-02 3.734e-01 2.513e-02 6.064668e-01 1.480939e-02 9.601138e-03 -6.000000e+00 2.463852e-01 232.95 -2.00 3.57 -2.00 321.26 0.00e+00 2.650837e-02 6.732255e-03 7.112967e-03 -6.000000e+00 1.228447e-02 285.15 -2.00 20.00 -2.00 320.68 0.00e+00 5.100 0.002 302.00 328.00 3 4.6588e+00 4.9718e-02 6.2416e-02 -6.0000e+00 6.2374e-01 4.7810e-01 6.2704e-02 3.6105e-02 -6.0000e+00 6.7429e-01 -5.0281e-01 5.2220e-02 3.3809e-02 -6.0000e+00 3.9558e-01 1.9656e-01 2.5318e-02 2.2958e-02 -6.0000e+00 1.6650e-01 1.4892e-05 -1.3147e-03 7.7155e-04 3.5356e-04 -6.0000e+00 1.1612e-02 -7.0043e-03 0.0000e+00 12 8 8 10 0 0 99.61 22.09 0.49 -0.00700 -0.01688 18 4 1 5 0 2734.750 22.09 14.92 18.98 -90783 -157103 100412 900000 -79938 900000 -79342 900000 900000 -96020 900000 900000 73301 900000 -83535 900000 -74371 900000 -12483 -9730 -21306 127616 -64088 900000 6038 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3248 4762 2927 2543 123 -292 1653 2105 1763 -4797 957 -4757 635 -3035 -1707 171 1527 -4999 -1291 -108 -2699 -2173 -654 889 3150 2326 503 1340 -4235 2520 2758 750 -6551 -2774 -5804 3071 -2899 471 -1754 -4067 -4960 -599 -150 2289 2586 957 41 2239 1006 -146 2611 71 2636 -1896 -177 663 1623 -817 5440 2575 -3637 -1573 2430 2118 -538 1937 2979 89 -1256 -290 -2360 -183 -2342 2516 -983 -219 -1665 SS 20220627T111421.8Z 8213.468308 112 1 50.06 2 75.25 71.68 60.99 82.59 0.00 1 0.00 1 0 25 5.132e-01 1.761e-02 2.819e-01 1.375e-02 4.855765e-01 7.759740e-03 6.752734e-03 -6.000000e+00 3.162200e-01 232.95 -2.00 3.57 -2.00 320.71 0.00e+00 7.930073e-03 3.053170e-03 4.910139e-03 -6.000000e+00 1.413080e-02 285.15 -2.00 20.00 -2.00 320.06 0.00e+00 3.848 0.001 302.00 328.00 3 5.2019e+00 2.4573e-02 4.9863e-02 -6.0000e+00 7.9755e-01 4.3846e-02 3.0500e-02 3.5386e-02 -6.0000e+00 8.6054e-01 -7.3539e-02 2.6105e-02 2.0041e-02 -6.0000e+00 5.0427e-01 2.4878e-02 1.2965e-02 7.0743e-03 -6.0000e+00 2.1160e-01 3.7787e-05 -1.2496e-04 4.3188e-04 1.2901e-04 -6.0000e+00 1.4809e-02 -6.1436e-03 0.0000e+00 12 9 8 11 8 0 99.97 22.09 0.53 -0.00614 -0.00708 39 8 1 5 0 1283.390 22.09 14.94 18.78 310673 -69067 900000 251454 900000 -76143 900000 900000 900000 -12988 292205 -116398 -14446 -70505 -16776 -36008 -53414 43801 -56936 129570 -32624 22480 -71962 11957 -39331 165692 -4937 48404 7992 21337 -8696 12133 13432 35246 -21659 -12181 2594 6669 18553 3660 19375 -3915 7839 -2044 15845 3364 15413 3844 3511 -1719 31943 -721 8639 2810 8462 4624 2777 -4139 -3870 233 -7116 7945 346 3421 -458 3713 -2180 4561 432 1730 1039 6599 -1152 3095 -1617 723 -5168 -473 -2925 197 -1379 -4390 -3334 -1982 -763 580 234 -173 3668 -1500 1199 -947 -312 -3113 -730 -2640 -2521 -718 293 1611 -2098 -270 -2359 -1504 -681 -220 -1918 1668 -981 2246 1297 2573 -404 1816 -709 280 799 1292 -607 286 -264 -176 1669 708 -816 -622 -839 -1990 1394 -339 643 -1016 -330 -367 -828 -936 1051 564 102 484 -832 390 -47 4162 -1220 900000 3369 900000 -1372 900000 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