File name: Pandora104s1_Downsview_20221020_L2Fit_fwvt1c22d20211217p1-8.txt File generation date: 20241127T155244.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20221020_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0779 492.1984 492.3189 492.4394 492.5598 492.6803 492.8007 492.9211 493.0415 493.1619 493.2822 493.4026 493.5229 493.6432 493.7635 493.8838 494.0041 494.1243 494.2445 494.3647 494.4849 494.6051 494.7253 494.8454 494.9655 495.0856 495.2057 495.3258 495.4458 495.5659 495.6859 495.8059 495.9259 496.0458 496.1658 496.2857 496.4056 496.5255 496.6454 496.7653 496.8851 497.0050 497.1248 497.2446 497.3643 497.4841 497.6038 497.7236 497.8433 497.9630 498.0826 498.2023 498.3219 498.4416 498.5612 498.6808 498.8003 498.9199 499.0394 499.1589 499.2784 499.3979 499.5174 499.6368 499.7563 499.8757 499.9951 500.1144 500.2338 500.3532 500.4725 500.5918 500.7111 500.8304 500.9496 501.0689 501.1881 501.3073 501.4265 501.5456 501.6648 501.7839 501.9030 502.0221 502.1412 502.2603 502.3793 502.4984 502.6174 502.7364 502.8554 502.9743 503.0933 503.2122 503.3311 503.4500 503.5689 503.6877 503.8066 503.9254 504.0442 504.1630 504.2817 504.4005 504.5192 504.6379 504.7566 504.8753 504.9940 505.1126 505.2313 505.3499 505.4685 505.5870 505.7056 505.8241 505.9427 506.0612 506.1797 506.2981 506.4166 506.5350 506.6534 506.7718 506.8902 507.0086 507.1269 507.2453 507.3636 507.4819 507.6001 507.7184 507.8366 507.9549 508.0731 508.1913 508.3094 508.4276 508.5457 508.6638 508.7819 508.9000 509.0181 509.1361 509.2542 509.3722 509.4902 509.6081 509.7261 509.8440 509.9620 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221020T154432.4Z 8328.655931 353 1 51.60 2 57.11 156.95 39.21 234.85 0.00 1 0.00 1 0 15 2.953e-03 2.936e-03 1.003e-03 9.995e-04 1.778924e+03 5.694075e+01 1.232389e+02 -6.000000e+00 1.590270e+02 280.46 -2.00 20.00 -2.00 505.24 0.00e+00 6.293577e-04 2.696847e-05 3.420904e-05 -6.000000e+00 8.160451e-05 280.46 -2.00 20.00 -2.00 500.42 0.00e+00 2.048928e-02 1.944392e-02 1.536608e-02 -6.000000e+00 5.760794e-02 224.95 -2.00 3.57 -2.00 502.01 0.00e+00 1.835 0.000 489.00 513.00 1 8.1280e+00 1.4878e-03 2.9832e-03 -6.0000e+00 4.4103e-03 2.7848e-03 3.8786e-04 3.6529e-04 -6.0000e+00 1.1497e-03 4.4253e-04 3.2628e-04 8.6006e-05 1.8239e-05 -6.0000e+00 2.6057e-04 -1.2850e-02 -1.2208e-06 10 0 0 10 0 0 99.65 22.09 1.35 -0.01285 -0.01059 14 3 1 4 0 3685.110 22.09 14.90 18.97 -190 -53 -297 -83 -198 209 503 178 442 180 254 276 -177 -134 -127 -207 40 -214 -116 -189 -9 93 170 107 226 185 389 115 -116 -121 125 95 -155 -42 -247 -306 -109 15 -9 -155 211 126 88 131 163 216 377 263 16 -26 -365 -260 -289 -274 -276 -361 -366 -280 -105 79 100 418 335 334 119 251 200 48 16 -135 -14 156 -42 191 -62 -266 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50.62 2 55.40 165.42 43.75 242.79 0.00 1 0.00 1 0 15 2.454e-03 2.465e-03 8.350e-04 8.333e-04 1.458866e+03 4.735051e+01 9.439335e+01 -6.000000e+00 1.321779e+02 280.45 -2.00 20.00 -2.00 505.28 0.00e+00 6.393954e-04 2.251152e-05 3.643750e-05 -6.000000e+00 6.782884e-05 280.45 -2.00 20.00 -2.00 500.49 0.00e+00 6.135178e-02 1.614089e-02 1.456629e-02 -6.000000e+00 4.788473e-02 224.95 -2.00 3.57 -2.00 502.08 0.00e+00 1.756 0.000 489.00 513.00 1 7.8364e+00 1.2332e-03 2.8642e-03 -6.0000e+00 3.6659e-03 2.7689e-03 3.2185e-04 3.2760e-04 -6.0000e+00 9.5570e-04 5.9746e-04 5.2690e-04 7.1788e-05 1.5200e-05 -6.0000e+00 2.1664e-04 -1.5883e-02 1.3869e-05 10 0 0 10 0 0 90.17 21.98 1.34 -0.01588 -0.01223 14 3 1 4 0 3614.870 21.98 14.86 18.73 -330 -367 -181 -196 -96 149 471 257 441 251 353 167 -229 -167 -246 -148 9 -172 -9 -109 -54 221 285 498 426 331 323 76 -144 -333 -201 146 -398 22 6 -259 -182 40 61 15 28 -32 126 7 353 259 302 220 244 -220 -376 -463 -442 -594 -216 -377 -348 -264 -78 277 204 444 348 241 184 43 132 105 -147 -234 -150 -46 -149 -45 -264 -337 -182 406 -123 -206 -396 -181 -230 -296 -200 23 -240 19 -10 14 56 174 469 -54 66 -30 120 -280 -340 -139 -205 88 -28 -119 -352 -499 -359 -203 -148 122 41 -74 -118 214 193 321 374 441 248 316 358 437 172 178 138 74 99 252 200 277 44 -227 -95 -62 -228 -65 106 -124 -192 88 131 39 146 137 34 -103 -377 -285 -56 -143 76 -310 -351 -179 -201 -101 150 485 267 457 257 355 176 -237 -171 -250 -151 9 -173 -10 -114 -57 230 297 519 448 347 336 78 -146 -343 -202 147 -411 22 6 -275 -191 41 62 15 29 -32 129 7 370 272 315 227 248 -219 -363 -460 -432 -583 -218 -373 -353 -270 -79 281 207 453 356 247 188 43 131 102 -142 -224 -149 -45 -142 -43 -260 -330 -175 401 -121 -202 -389 -170 -218 -282 -193 23 -235 18 -10 14 55 173 474 -56 67 -30 118 -270 -320 -128 -186 80 -26 -117 -358 -510 -363 -202 -145 118 40 -75 -121 221 201 318 372 440 247 326 363 436 170 176 138 75 99 252 199 275 44 -223 -91 -59 -216 -62 102 -123 -193 90 128 38 142 135 34 -102 -370 -273 -55 -137 73 SQ 20221020T161907.9Z 8328.679952 372 1 49.75 2 55.18 166.93 44.58 244.06 0.00 1 0.00 1 0 15 2.218e-03 2.218e-03 3.458e-04 3.451e-04 1.252251e+03 1.936160e+01 8.112206e+01 -6.000000e+00 1.194481e+02 280.45 -2.00 20.00 -2.00 505.29 0.00e+00 7.022152e-04 9.319253e-06 3.945909e-05 -6.000000e+00 6.130381e-05 280.45 -2.00 20.00 -2.00 500.53 0.00e+00 -1.252549e-02 6.668972e-03 1.308908e-02 -6.000000e+00 4.328367e-02 224.95 -2.00 3.57 -2.00 502.12 0.00e+00 1.746 0.000 489.00 513.00 1 5.9985e+00 5.0875e-04 2.8271e-03 -6.0000e+00 3.3135e-03 -2.0575e-03 1.3298e-04 2.9280e-04 -6.0000e+00 8.6406e-04 3.7780e-03 7.0356e-04 2.9745e-05 1.5157e-05 -6.0000e+00 1.9597e-04 -1.1754e-02 -2.7709e-05 10 0 0 10 0 0 99.98 21.98 1.27 -0.01175 -0.00687 271 56 1 4 0 183.550 21.98 14.83 18.83 -172 -312 -278 -73 -80 186 373 351 416 248 227 207 -134 -87 -125 -93 -3 -120 -5 -109 43 178 205 277 400 172 203 68 -224 -273 -12 184 -290 47 -228 -196 -102 109 50 3 24 53 149 120 213 187 229 61 21 -186 -323 -396 -319 -384 -110 -394 -357 -285 -43 206 202 389 236 204 242 146 163 60 -19 -104 -193 51 -48 -164 -171 -306 -267 -419 -154 -154 -280 -282 -354 -315 -172 -142 -205 -135 -71 69 110 81 229 7 154 -42 104 -146 -267 -202 -311 -46 -310 -212 -286 -541 -272 -88 12 144 84 -55 12 234 218 403 460 454 281 285 300 391 232 396 185 44 160 232 107 258 134 -199 -42 -19 -84 2 37 -215 -131 -51 54 82 233 154 37 -102 -228 -374 -193 -56 -32 -161 -298 -275 -75 -84 187 383 363 430 253 228 217 -138 -89 -127 -94 -3 -120 -6 -114 45 185 213 288 420 180 211 70 -228 -282 -13 186 -282 48 -239 -207 -107 113 51 3 24 54 153 124 223 197 240 63 21 -185 -312 -395 -313 -377 -105 -390 -363 -292 -44 209 205 397 243 210 247 147 162 59 -18 -99 -182 48 -46 -159 -169 -301 -257 -396 -144 -144 -262 -267 -337 -301 -167 -139 -202 -133 -70 68 109 81 234 7 158 -43 104 -142 -253 -188 -285 -42 -294 -210 -293 -558 -276 -88 12 141 83 -56 12 244 217 401 460 457 282 282 308 394 232 396 188 44 162 235 108 259 135 -198 -41 -18 -80 2 36 -215 -133 -50 53 80 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