File name: Pandora104s1_Downsview_20221021_L2Fit_fout2c22d20211217p1-8.txt File generation date: 20241127T155121.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20221021_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221021 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 208 350 Nominal wavelengths inside fitting window [nm]: 305.0351 305.1757 305.3162 305.4567 305.5973 305.7378 305.8783 306.0188 306.1593 306.2997 306.4402 306.5806 306.7211 306.8615 307.0019 307.1423 307.2827 307.4231 307.5634 307.7038 307.8441 307.9845 308.1248 308.2651 308.4054 308.5457 308.6860 308.8262 308.9665 309.1067 309.2470 309.3872 309.5274 309.6676 309.8078 309.9480 310.0881 310.2283 310.3684 310.5086 310.6487 310.7888 310.9289 311.0690 311.2091 311.3491 311.4892 311.6292 311.7693 311.9093 312.0493 312.1893 312.3293 312.4693 312.6092 312.7492 312.8891 313.0290 313.1690 313.3089 313.4488 313.5886 313.7285 313.8684 314.0082 314.1481 314.2879 314.4277 314.5675 314.7073 314.8471 314.9869 315.1266 315.2664 315.4061 315.5458 315.6855 315.8252 315.9649 316.1046 316.2443 316.3839 316.5236 316.6632 316.8028 316.9424 317.0820 317.2216 317.3612 317.5008 317.6403 317.7799 317.9194 318.0589 318.1984 318.3379 318.4774 318.6169 318.7563 318.8958 319.0352 319.1747 319.3141 319.4535 319.5929 319.7322 319.8716 320.0110 320.1503 320.2897 320.4290 320.5683 320.7076 320.8469 320.9862 321.1254 321.2647 321.4039 321.5431 321.6824 321.8216 321.9608 322.1000 322.2391 322.3783 322.5174 322.6566 322.7957 322.9348 323.0739 323.2130 323.3521 323.4912 323.6302 323.7693 323.9083 324.0473 324.1863 324.3253 324.4643 324.6033 324.7422 324.8812 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221021T121329.7Z 8329.509371 186 1 48.37 2 85.04 110.10 41.34 131.95 0.00 1 0.00 1 0 33 6.739e-01 7.448e-02 4.763e-01 6.118e-02 7.988869e-01 3.669217e-02 1.073735e-02 -6.000000e+00 4.060367e-01 224.87 -2.00 3.57 -2.00 321.65 0.00e+00 1.683991e-02 1.306333e-02 5.565536e-03 -6.000000e+00 1.990537e-02 280.35 -2.00 20.00 -2.00 321.09 0.00e+00 9.876 0.019 302.00 328.00 3 8.2599e-01 1.1650e-01 1.0697e-01 -6.0000e+00 1.0106e+00 1.8632e+00 1.3537e-01 4.3387e-02 -6.0000e+00 1.1058e+00 -1.7576e+00 8.5579e-02 2.5110e-02 -6.0000e+00 6.5207e-01 5.9161e-01 4.5889e-02 1.2966e-02 -6.0000e+00 2.7652e-01 5.2807e-06 1.1979e-04 1.8098e-03 2.2365e-04 -6.0000e+00 2.0248e-02 -1.3184e-02 0.0000e+00 12 8 8 10 0 0 10.31 22.09 1.90 -0.01318 -0.01228 15 3 1 5 0 3223.790 22.09 14.83 18.75 38899 99329 900000 3777 900000 -37132 253987 -70507 103207 165121 900000 -1958 40101 93507 132804 170486 900000 210549 12962 900000 -30660 900000 -56173 900000 -30428 -5282 -39090 900000 -39194 258495 8811 900000 -55906 900000 900000 220687 288102 -44943 900000 -57116 82876 -14764 49752 -5576 95401 -4000 36774 18128 12211 900000 67998 14184 49006 109165 55384 58912 -11842 122696 33342 19866 -32588 167955 -10516 60643 -22156 -37440 -24345 6581 27686 26153 45627 35042 -4030 18476 -14641 -13253 44403 -52802 -14933 26336 40411 -14049 64855 5353 32665 -11484 212 14260 16274 -17490 15569 -10407 41274 7660 19642 2046 4351 877 10376 1521 -7113 -5903 10532 -13205 -6034 -3880 -14156 -6948 -4002 5063 6116 8542 10479 8067 2888 -1187 -1470 -8972 -1885 -778 3268 2215 3806 -1935 -6966 -4245 7503 -2213 6052 -1086 2121 -7245 5658 -1304 -1391 -198 -256 -384 1119 -3235 -388 3286 3522 2893 5911 900000 393 900000 -3867 15114 -8391 6141 9826 900000 -117 2386 5564 7903 10145 900000 12529 1414 900000 -4713 900000 -8914 900000 -3621 -457 -4441 900000 -4028 15382 667 900000 -10887 900000 900000 13132 17144 -7294 900000 -12977 4932 -2396 4306 -845 5677 -584 3581 2157 1585 900000 5518 2148 5567 7086 6292 6374 -2562 7301 4148 2687 -7404 9994 -2276 7939 -6592 -12962 -7112 1424 5092 5518 9503 8341 -1264 4727 -4277 -3706 6341 -17995 -4176 5798 9138 -6270 14665 2325 11274 -6492 111 6704 7456 -10928 6578 -5326 12034 3145 7948 1157 2822 678 8273 1393 -6857 -5093 6831 -10293 -4596 -3094 -13057 -6408 -3906 5152 6988 10521 13158 10369 3780 -1561 -1916 -13134 -2703 -1167 4725 3124 5005 -2636 -9700 -5634 8573 -2791 7887 -1777 3812 -15694 11447 -3034 -3477 -525 -699 -1065 3082 -9181 -1011 7703 7734 SS 20221021T122534.4Z 8329.517759 189 1 50.12 2 83.01 112.27 39.84 135.76 0.00 1 0.00 1 0 25 6.680e-01 1.837e-02 4.091e-01 1.111e-02 8.093036e-01 6.522656e-03 9.534575e-03 -6.000000e+00 3.950499e-01 224.87 -2.00 3.57 -2.00 322.01 0.00e+00 9.370020e-03 3.816096e-03 4.516651e-03 -6.000000e+00 1.823052e-02 280.35 -2.00 20.00 -2.00 321.56 0.00e+00 7.535 0.008 302.00 328.00 3 1.1500e+00 2.5283e-02 8.7490e-02 -6.0000e+00 9.7589e-01 6.1229e-01 3.5713e-02 4.8890e-02 -6.0000e+00 1.0589e+00 -7.5707e-01 3.5846e-02 2.9909e-02 -6.0000e+00 6.3074e-01 2.9686e-01 1.6442e-02 1.3080e-02 -6.0000e+00 2.7127e-01 4.8294e-05 -8.5131e-04 3.2259e-04 2.2954e-04 -6.0000e+00 1.8688e-02 -1.2534e-02 0.0000e+00 12 9 8 11 8 0 38.78 22.09 0.53 -0.01253 -0.01893 73 15 1 5 0 686.170 22.09 14.90 18.90 -150390 900000 -79794 -125587 900000 900000 -18662 -224892 -75326 -175320 110875 -190078 143268 -111232 900000 -129887 124443 -114344 900000 -88095 257487 -110327 900000 75559 39646 -52082 123129 -49303 -62227 26076 -46755 126571 -56731 264538 -17845 216416 -55446 163101 26707 136751 14777 43598 16691 22656 386 23965 15077 27222 37659 15077 27671 2257 37783 -2581 40059 20210 18054 61 29272 5664 38540 3915 21318 8275 20986 15771 14151 7842 1562 10494 5658 5391 2177 11474 -1911 7242 -3117 -2518 -10802 439 -3644 1462 -2483 1244 -998 1649 -841 -1094 1507 2171 2410 -3511 -2035 -4989 -4927 -4529 2926 -2715 847 -1176 1868 -2067 -1849 -2560 828 -739 -2603 -1920 -1778 87 -1246 1945 -1260 1518 -1669 692 -1529 796 132 1210 -828 2491 574 1770 -277 1441 -435 465 1964 -149 405 -967 91 -383 374 -485 316 161 705 -269 93 -1260 -271 -1628 900000 -864 -1359 900000 900000 -202 -5072 -815 -2689 1200 -3772 1551 -1861 900000 -3867 1347 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328.00 3 1.0249e+00 7.5606e-03 7.3389e-02 -6.0000e+00 7.0865e-01 1.9642e-01 1.0786e-02 4.5774e-02 -6.0000e+00 7.6778e-01 -2.4693e-01 1.1253e-02 3.1438e-02 -6.0000e+00 4.5798e-01 9.4951e-02 5.2426e-03 1.4059e-02 -6.0000e+00 1.9649e-01 2.3989e-04 -4.2689e-04 1.0975e-04 2.1757e-04 -6.0000e+00 1.3456e-02 -1.3207e-02 0.0000e+00 12 8 8 10 0 0 46.41 22.09 0.37 -0.01321 -0.01642 192 39 1 5 0 258.950 22.09 14.83 18.97 -110663 -142757 -148926 40843 -128789 -124131 -197655 -171765 -210521 -48576 -201249 -43348 -143544 -10980 -97911 79328 -67883 3340 -53711 112613 -33801 -15274 -38975 -46828 -40879 -46608 -31107 -59837 -1453 -63894 2972 -46920 2179 -26682 22362 -25240 14281 -6805 16574 -2594 9549 -1751 11551 4017 1588 13442 -985 8673 -571 13333 295 19171 -896 15972 1476 8585 -228 7270 625 6201 3259 5546 6353 7995 7296 3619 4817 1256 4127 897 3738 1588 3866 -1300 2869 -721 1155 -5442 171 -2008 616 -2146 -260 -1465 -1742 -511 -208 235 101 1275 -208 908 -2162 -803 -2587 -21 -1335 176 -88 -229 -1320 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