File name: Pandora104s1_Downsview_20221025_L2Fit_fwvt1c22d20211217p1-8.txt File generation date: 20241127T161426.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c22p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v22d20211217.txt Level 1 file used: Pandora104s1_Downsview_20221025_L1_smca1c22d20211217p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 16 for SO2 "based on session 14 for vp 20211217" First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0779 492.1984 492.3189 492.4394 492.5598 492.6803 492.8007 492.9211 493.0415 493.1619 493.2822 493.4026 493.5229 493.6432 493.7635 493.8838 494.0041 494.1243 494.2445 494.3647 494.4849 494.6051 494.7253 494.8454 494.9655 495.0856 495.2057 495.3258 495.4458 495.5659 495.6859 495.8059 495.9259 496.0458 496.1658 496.2857 496.4056 496.5255 496.6454 496.7653 496.8851 497.0050 497.1248 497.2446 497.3643 497.4841 497.6038 497.7236 497.8433 497.9630 498.0826 498.2023 498.3219 498.4416 498.5612 498.6808 498.8003 498.9199 499.0394 499.1589 499.2784 499.3979 499.5174 499.6368 499.7563 499.8757 499.9951 500.1144 500.2338 500.3532 500.4725 500.5918 500.7111 500.8304 500.9496 501.0689 501.1881 501.3073 501.4265 501.5456 501.6648 501.7839 501.9030 502.0221 502.1412 502.2603 502.3793 502.4984 502.6174 502.7364 502.8554 502.9743 503.0933 503.2122 503.3311 503.4500 503.5689 503.6877 503.8066 503.9254 504.0442 504.1630 504.2817 504.4005 504.5192 504.6379 504.7566 504.8753 504.9940 505.1126 505.2313 505.3499 505.4685 505.5870 505.7056 505.8241 505.9427 506.0612 506.1797 506.2981 506.4166 506.5350 506.6534 506.7718 506.8902 507.0086 507.1269 507.2453 507.3636 507.4819 507.6001 507.7184 507.8366 507.9549 508.0731 508.1913 508.3094 508.4276 508.5457 508.6638 508.7819 508.9000 509.0181 509.1361 509.2542 509.3722 509.4902 509.6081 509.7261 509.8440 509.9620 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221025T132602.3Z 8333.559749 83 1 49.47 2 74.42 124.84 76.04 123.30 0.00 1 0.00 1 0 15 2.313e-03 2.312e-03 6.350e-04 6.334e-04 2.871594e+03 3.733026e+01 2.056515e+02 -6.000000e+00 1.242422e+02 279.83 -2.00 20.00 -2.00 505.28 0.00e+00 7.285891e-04 1.705874e-05 4.183581e-05 -6.000000e+00 6.382714e-05 279.83 -2.00 20.00 -2.00 500.49 0.00e+00 1.624082e-01 1.228043e-02 2.200229e-02 -6.000000e+00 4.512436e-02 224.50 -2.00 3.57 -2.00 502.07 0.00e+00 3.656 0.001 489.00 513.00 1 6.9502e+00 9.3679e-04 5.5393e-03 -6.0000e+00 3.4538e-03 1.0695e-02 2.4436e-04 5.8217e-04 -6.0000e+00 9.0072e-04 1.0992e-03 9.4941e-04 5.4435e-05 2.7957e-05 -6.0000e+00 2.0434e-04 -1.0163e-02 -3.7184e-05 10 0 0 10 0 0 99.98 21.98 1.29 -0.01016 -0.00358 50 10 1 4 0 989.260 21.98 14.96 18.81 -160 -350 -334 -122 50 172 443 241 466 278 344 206 -209 -180 -101 -151 -8 -123 42 -172 6 300 194 296 323 196 125 95 -264 -302 49 116 -166 1 -126 -106 -91 81 -70 -61 88 -12 132 50 245 81 371 166 104 -305 -416 -448 -346 -450 -135 -355 -362 -215 -78 75 143 518 101 177 94 135 96 163 -111 -125 -93 125 -80 -63 -214 -420 -251 31 -75 -183 -354 -281 -297 -337 -138 -152 -138 -56 -52 110 240 127 472 50 208 9 163 -124 -242 -208 -369 -64 -450 -223 -375 -512 -386 -74 -92 82 51 -27 76 200 228 303 622 462 194 174 168 334 178 282 266 -43 229 153 121 97 240 -244 34 -45 -98 25 91 -153 -311 24 -14 143 162 225 97 -27 -157 -299 -231 -2 -136 -151 -338 -334 -127 50 175 460 253 486 286 348 207 -207 -186 -104 -156 -8 -124 44 -182 6 315 204 311 343 208 132 99 -272 -298 47 112 -163 1 -134 -114 -96 85 -73 -62 90 -12 137 52 260 86 392 173 107 -308 -407 -426 -324 -422 -130 -355 -372 -223 -81 77 147 534 105 184 97 137 96 160 -109 -121 -89 119 -77 -62 -213 -418 -244 30 -71 -172 -333 -268 -285 -325 -135 -150 -137 -56 -51 109 238 128 482 52 213 9 161 -119 -228 -191 -336 -59 -424 -220 -384 -528 -394 -74 -91 80 51 -28 74 197 226 301 620 465 196 172 164 338 177 282 269 -41 232 147 122 98 242 -244 33 -43 -94 24 89 -145 -301 24 -14 141 161 225 97 -27 -155 -290 -218 -2 -126 SQ 20221025T133053.7Z 8333.563122 86 1 51.05 2 73.70 125.83 75.34 124.25 0.00 1 0.00 1 0 15 2.799e-03 2.793e-03 1.072e-03 1.069e-03 2.861975e+03 6.318386e+01 1.994574e+02 -6.000000e+00 1.503767e+02 279.83 -2.00 20.00 -2.00 505.28 0.00e+00 6.946453e-04 2.889835e-05 3.906493e-05 -6.000000e+00 7.722986e-05 279.83 -2.00 20.00 -2.00 500.47 0.00e+00 1.466585e-01 2.078938e-02 2.330258e-02 -6.000000e+00 5.458553e-02 224.50 -2.00 3.57 -2.00 502.06 0.00e+00 3.506 0.001 489.00 513.00 1 7.8962e+00 1.5897e-03 5.3652e-03 -6.0000e+00 4.1783e-03 9.0963e-03 4.1226e-04 5.9469e-04 -6.0000e+00 1.0890e-03 4.3660e-04 1.4915e-04 9.1956e-05 2.5962e-05 -6.0000e+00 2.4672e-04 -1.3468e-02 2.2078e-05 11 1 0 11 8 0 99.52 21.98 1.34 -0.01347 -0.01243 17 3 1 4 0 3002.590 21.98 14.86 18.85 -267 -503 -480 -154 -226 164 434 342 372 153 354 -109 -192 -59 -181 40 -7 -2 -58 -327 -147 175 136 523 329 346 190 60 -279 -233 -9 139 -41 66 -220 -181 -80 373 -33 -123 104 -89 254 260 384 138 207 79 182 -304 -193 -562 -88 -376 -209 -508 -522 -123 -19 366 294 307 31 484 206 314 141 -72 -115 -206 -58 350 43 66 -145 -402 -218 -1461 -53 4 -280 -107 -126 -281 -46 -53 -99 -185 258 179 97 59 349 -144 162 -11 153 40 -162 -121 -390 -13 -293 -274 -617 -310 -561 -121 16 203 78 56 157 238 126 406 363 451 241 263 399 542 395 343 139 -239 -107 12 322 88 90 -344 -91 -44 -124 48 -13 -69 -219 183 30 91 33 238 -119 142 -209 -327 -101 -176 -339 -252 -483 -472 -155 -232 170 455 361 393 160 364 -112 -195 -60 -181 40 -7 -2 -61 -346 -155 185 144 551 349 366 200 63 -289 -234 -9 137 -41 68 -232 -192 -84 388 -34 -126 106 -92 262 271 403 145 217 82 187 -308 -191 -546 -84 -360 -205 -511 -535 -127 -19 373 300 314 32 497 210 318 141 -71 -113 -201 -56 337 42 65 -144 -400 -213 -1418 -51 4 -266 -103 -122 -272 -45 -52 -97 -183 253 176 96 58 351 -146 163 -11 149 38 -154 -112 -359 -12 -276 -267 -617 -311 -558 -119 15 197 77 55 158 240 128 411 369 461 246 266 398 533 385 335 137 -236 -105 12 314 86 88 -335 -87 -41 -116 45 -12 -68 -216 181 30 91 33 239 -120 143 -209 -321 -97 -167 -323 SQ 20221025T134520.3Z 8333.573151 92 1 48.93 2 71.63 128.82 73.33 127.14 0.00 1 0.00 1 0 15 2.657e-03 2.645e-03 7.516e-04 7.502e-04 2.724928e+03 4.403208e+01 1.909668e+02 -6.000000e+00 1.427272e+02 279.83 -2.00 20.00 -2.00 505.27 0.00e+00 7.243647e-04 2.027176e-05 4.075855e-05 -6.000000e+00 7.331414e-05 279.83 -2.00 20.00 -2.00 500.47 0.00e+00 1.036354e-01 1.458398e-02 2.217923e-02 -6.000000e+00 5.182457e-02 224.50 -2.00 3.57 -2.00 502.06 0.00e+00 3.133 0.001 489.00 513.00 1 7.3848e+00 1.1153e-03 4.8632e-03 -6.0000e+00 3.9668e-03 1.0607e-02 2.8948e-04 5.5813e-04 -6.0000e+00 1.0342e-03 7.6924e-04 4.2534e-04 6.4251e-05 2.5471e-05 -6.0000e+00 2.3447e-04 -1.2523e-02 -4.8200e-06 10 0 0 10 0 0 99.78 21.98 1.36 -0.01252 -0.00957 21 4 1 4 0 2329.860 21.98 14.77 18.83 -393 -296 -278 -115 -61 42 488 328 380 362 394 -37 -105 -78 -137 -28 -70 -226 37 -276 27 95 271 237 350 298 271 3 -215 -407 87 69 -104 62 -205 -191 -270 93 106 57 84 63 23 208 79 224 308 184 157 -122 -257 -462 -292 -521 -103 -452 -306 -160 -104 158 257 362 300 310 175 183 323 84 28 -60 -246 316 -99 -137 -249 -282 -276 -1641 -211 20 -275 -187 -241 -176 -195 110 -139 132 -1 62 195 130 345 108 29 107 184 -296 -263 -223 -135 -145 -264 -316 -371 -404 -281 -73 70 69 111 -111 121 47 109 464 469 346 247 207 186 319 238 463 99 135 34 291 6 394 23 -87 -27 33 -63 -40 -9 -270 -142 95 87 43 91 178 24 -155 -199 -344 -191 20 -109 -375 -286 -275 -116 -62 44 511 345 400 376 405 -38 -106 -79 -137 -28 -70 -232 38 -292 28 100 284 250 369 314 285 3 -222 -410 86 68 -105 64 -216 -202 -283 96 110 59 86 65 24 216 83 235 322 190 160 -123 -255 -450 -281 -502 -101 -455 -312 -164 -107 161 262 371 307 318 179 185 323 83 28 -58 -238 305 -97 -135 -248 -280 -270 -1599 -202 19 -263 -180 -233 -171 -191 109 -138 130 -1 61 192 129 346 109 29 106 180 -286 -250 -209 -125 -135 -250 -308 -370 -404 -279 -72 68 67 110 -110 122 47 110 469 475 352 252 208 185 315 232 452 97 133 33 286 6 385 23 -84 -26 31 -59 -38 -9 -264 -139 94 86 43 91 179 24 -156 -198 -338 -184 19 -104 SQ 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