File name: Pandora104s1_Downsview_20221113_L2Fit_fout2c19d20221101p1-8.txt File generation date: 20241127T161118.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v19d20221101.txt Level 1 file used: Pandora104s1_Downsview_20221113_L1_smca1c19d20221101p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20221101 First and last pixel inside fitting window: 207 349 Nominal wavelengths inside fitting window [nm]: 305.0318 305.1723 305.3129 305.4534 305.5939 305.7344 305.8749 306.0154 306.1558 306.2963 306.4367 306.5771 306.7176 306.8580 306.9984 307.1388 307.2791 307.4195 307.5598 307.7002 307.8405 307.9808 308.1211 308.2614 308.4017 308.5420 308.6823 308.8225 308.9628 309.1030 309.2432 309.3834 309.5236 309.6638 309.8040 309.9441 310.0843 310.2244 310.3646 310.5047 310.6448 310.7849 310.9250 311.0650 311.2051 311.3451 311.4852 311.6252 311.7652 311.9052 312.0452 312.1852 312.3252 312.4651 312.6051 312.7450 312.8850 313.0249 313.1648 313.3047 313.4446 313.5844 313.7243 313.8641 314.0040 314.1438 314.2836 314.4234 314.5632 314.7030 314.8427 314.9825 315.1223 315.2620 315.4017 315.5414 315.6811 315.8208 315.9605 316.1002 316.2398 316.3795 316.5191 316.6587 316.7983 316.9379 317.0775 317.2171 317.3566 317.4962 317.6357 317.7753 317.9148 318.0543 318.1938 318.3333 318.4727 318.6122 318.7516 318.8911 319.0305 319.1699 319.3093 319.4487 319.5881 319.7275 319.8668 320.0062 320.1455 320.2848 320.4242 320.5635 320.7027 320.8420 320.9813 321.1205 321.2598 321.3990 321.5382 321.6774 321.8166 321.9558 322.0950 322.2342 322.3733 322.5125 322.6516 322.7907 322.9298 323.0689 323.2080 323.3470 323.4861 323.6252 323.7642 323.9032 324.0422 324.1812 324.3202 324.4592 324.5982 324.7371 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221113T164353.0Z 8352.697141 410 1 12.40 2 62.01 175.07 86.77 303.72 0.00 1 0.00 1 0 17 1.402e-02 7.039e-03 9.535e-03 3.196e-03 2.670047e-01 1.642891e-03 3.323416e-03 -6.000000e+00 8.137718e-03 222.73 -2.00 3.57 -2.00 317.10 0.00e+00 6.111230e-04 2.249259e-04 2.385603e-04 -6.000000e+00 3.567812e-04 277.38 -2.00 20.00 -2.00 316.49 0.00e+00 2.120 0.000 302.00 328.00 3 4.7188e+00 4.2684e-03 2.4734e-02 -6.0000e+00 2.0032e-02 5.8590e-02 4.7881e-03 1.3672e-02 -6.0000e+00 2.1742e-02 -9.4058e-03 2.8843e-03 6.8530e-03 -6.0000e+00 1.2967e-02 -3.0184e-03 1.4246e-03 2.0100e-03 -6.0000e+00 5.5773e-03 4.2577e-04 -3.8441e-04 9.3305e-05 2.2695e-05 -6.0000e+00 3.8397e-04 -1.2833e-02 0.0000e+00 12 9 1 12 1 1 67.55 21.69 0.15 -0.01283 -0.01572 5 5 1 5 0 2038.050 21.69 14.90 18.33 -1963 -1573 1635 -2096 -2317 -2342 910 -42 1199 -2416 -6286 -5088 -4987 -3123 -2098 -1080 547 -1350 508 2945 1724 -99 2174 679 -451 1783 751 -1058 -1075 -2100 1861 1991 861 -1210 -3739 -2567 -2611 -1024 -138 308 -1394 -1013 -54 383 1011 -100 143 -1193 1161 -557 451 1917 946 1221 634 1388 519 1207 53 -135 930 1803 1715 1126 1141 -515 -154 178 692 1512 568 -676 51 -367 -305 -178 -920 -372 -932 -798 -1318 -1855 -1673 -2004 -1371 -695 211 703 -39 -12 88 204 -62 -231 784 439 -281 -398 639 -214 -457 -828 -415 -72 -132 -1055 -1152 -258 -540 650 979 647 294 339 349 732 762 832 184 107 -343 149 79 729 92 369 167 492 390 310 -427 -326 -903 -166 -122 -170 -82 258 440 -118 -275 -291 -319 -221 -197 205 -268 -267 -254 97 -5 158 -352 -956 -762 -819 -574 -434 -245 130 -334 130 754 465 -27 581 191 -136 546 235 -325 -314 -598 522 604 281 -429 -1312 -852 -902 -390 -60 155 -773 -589 -32 230 604 -60 86 -713 675 -326 268 1193 623 834 449 992 382 887 39 -98 680 1359 1376 953 997 -443 -124 138 541 1277 521 -650 49 -352 -283 -155 -749 -286 -714 -656 -1185 -1805 -1723 -2143 -1512 -803 253 865 -48 -14 105 231 -66 -235 802 477 -328 -494 835 -287 -600 -1034 -493 -84 -162 -1366 -1532 -353 -756 941 1471 999 452 505 496 992 1006 1114 255 156 -514 224 116 1055 130 509 222 638 518 433 -623 -489 -1371 -255 -193 -280 -138 440 756 -203 -465 -483 -518 SS 20221113T165408.9Z 8352.704270 416 1 50.43 2 61.89 177.83 88.25 305.37 0.00 1 0.00 1 0 17 1.764e-02 7.182e-03 1.028e-02 2.607e-03 2.660754e-01 1.335560e-03 3.333157e-03 -6.000000e+00 1.024055e-02 222.72 -2.00 3.57 -2.00 317.82 0.00e+00 9.818813e-04 2.185313e-04 3.698777e-04 -6.000000e+00 4.490134e-04 277.38 -2.00 20.00 -2.00 317.20 0.00e+00 2.112 0.000 302.00 328.00 3 5.2683e+00 3.5141e-03 2.4697e-02 -6.0000e+00 2.5209e-02 7.1227e-02 3.9628e-03 1.3729e-02 -6.0000e+00 2.7362e-02 -8.8289e-03 2.4885e-03 6.9264e-03 -6.0000e+00 1.6318e-02 -5.9592e-03 1.2656e-03 2.0829e-03 -6.0000e+00 7.0178e-03 2.4632e-04 -6.5846e-04 7.7632e-05 2.3044e-05 -6.0000e+00 4.8342e-04 -1.1822e-02 0.0000e+00 11 9 0 11 8 0 99.94 21.79 0.30 -0.01182 -0.01677 18 4 1 5 0 2801.330 21.79 14.78 18.59 -2385 9042 -5314 3130 -8111 276 -2989 -2310 -1641 -4504 -668 -2820 1273 -2852 203 136 1520 -2431 5352 -314 922 -2000 1718 -667 2511 -1270 -286 -1929 -2216 -692 1568 -172 995 811 -3242 -3288 -3543 -1973 -913 -1475 -1453 -662 -929 147 -427 1631 -206 761 144 65 667 1714 1376 1055 490 540 893 -324 520 -414 1259 1467 2436 1126 1128 -428 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20221113T174327.6Z 8352.738514 444 1 51.24 2 62.59 191.05 94.92 313.66 0.00 1 0.00 1 0 17 2.396e-02 6.813e-03 1.446e-02 3.338e-03 2.776653e-01 1.711088e-03 3.420753e-03 -6.000000e+00 1.390816e-02 222.72 -2.00 3.57 -2.00 318.01 0.00e+00 9.564226e-04 2.945731e-04 3.474727e-04 -6.000000e+00 6.097400e-04 277.38 -2.00 20.00 -2.00 317.39 0.00e+00 2.161 0.000 302.00 328.00 3 5.5480e+00 4.5171e-03 2.5381e-02 -6.0000e+00 3.4237e-02 8.5608e-02 5.1054e-03 1.4225e-02 -6.0000e+00 3.7159e-02 -8.9477e-03 3.2636e-03 7.1956e-03 -6.0000e+00 2.2161e-02 -5.7377e-03 1.6727e-03 2.1897e-03 -6.0000e+00 9.5327e-03 1.7291e-04 -3.9341e-04 9.9652e-05 2.3550e-05 -6.0000e+00 6.5606e-04 -1.3386e-02 0.0000e+00 11 9 0 11 8 0 99.96 21.79 0.35 -0.01339 -0.01634 14 3 1 5 0 3659.470 21.79 14.83 18.50 11897 -717 1892 -260 -1502 -10477 475 -4359 -9032 -5566 -8531 -10464 -4710 -777 -758 1511 2604 -40 2977 3096 1588 3070 2422 4467 1665 -788 -1903 512 -1771 -1131 -4108 1685 -1284 -1183 -3148 -3364 -650 -742 -1105 -1026 0 -149 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