File name: Pandora104s1_Downsview_20221219_L2Fit_fwvt1c19d20221101p1-8.txt File generation date: 20241127T164255.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c19p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v19d20221101.txt Level 1 file used: Pandora104s1_Downsview_20221219_L1_smca1c19d20221101p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20221219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20221101 First and last pixel inside fitting window: 1632 1782 Nominal wavelengths inside fitting window [nm]: 492.0915 492.2120 492.3326 492.4531 492.5736 492.6940 492.8145 492.9349 493.0554 493.1758 493.2962 493.4165 493.5369 493.6572 493.7776 493.8979 494.0182 494.1384 494.2587 494.3789 494.4991 494.6193 494.7395 494.8597 494.9798 495.1000 495.2201 495.3402 495.4603 495.5803 495.7004 495.8204 495.9404 496.0604 496.1804 496.3004 496.4203 496.5402 496.6601 496.7800 496.8999 497.0197 497.1396 497.2594 497.3792 497.4990 497.6188 497.7385 497.8582 497.9779 498.0976 498.2173 498.3370 498.4566 498.5763 498.6959 498.8155 498.9350 499.0546 499.1741 499.2937 499.4132 499.5327 499.6521 499.7716 499.8910 500.0104 500.1298 500.2492 500.3686 500.4879 500.6073 500.7266 500.8459 500.9651 501.0844 501.2036 501.3229 501.4421 501.5613 501.6804 501.7996 501.9187 502.0378 502.1569 502.2760 502.3951 502.5141 502.6332 502.7522 502.8712 502.9901 503.1091 503.2280 503.3470 503.4659 503.5848 503.7036 503.8225 503.9413 504.0601 504.1789 504.2977 504.4165 504.5352 504.6540 504.7727 504.8914 505.0100 505.1287 505.2473 505.3659 505.4846 505.6031 505.7217 505.8403 505.9588 506.0773 506.1958 506.3143 506.4327 506.5512 506.6696 506.7880 506.9064 507.0248 507.1431 507.2615 507.3798 507.4981 507.6164 507.7346 507.8529 507.9711 508.0893 508.2075 508.3257 508.4438 508.5620 508.6801 508.7982 508.9163 509.0343 509.1524 509.2704 509.3884 509.5064 509.6244 509.7424 509.8603 509.9782 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221219T133639.0Z 8388.567118 202 1 50.20 2 83.75 131.20 57.46 179.10 0.00 1 0.00 1 0 15 2.515e-03 2.521e-03 5.198e-04 5.190e-04 3.291488e+03 2.993871e+01 2.249444e+02 -6.000000e+00 1.316901e+02 273.47 -2.00 20.00 -2.00 505.35 0.00e+00 2.328009e-03 1.387396e-05 1.276941e-04 -6.000000e+00 6.831626e-05 273.47 -2.00 20.00 -2.00 500.76 0.00e+00 9.844292e-01 9.981783e-03 3.591520e-02 -6.000000e+00 4.893813e-02 222.32 -2.00 3.57 -2.00 502.32 0.00e+00 8.277 0.011 489.00 513.00 1 5.8279e+00 7.6215e-04 1.2410e-02 -6.0000e+00 3.7398e-03 -1.5692e-02 1.9610e-04 9.6299e-04 -6.0000e+00 9.7280e-04 1.6357e-03 3.6919e-04 4.4579e-05 4.6039e-05 -6.0000e+00 2.2170e-04 5.4767e-03 -2.0781e-05 10 0 0 10 0 0 99.51 21.79 1.25 0.00548 0.00804 59 12 1 4 0 850.660 21.79 14.98 18.52 -371 -384 -272 19 14 301 524 316 484 256 351 88 -209 -144 -195 -102 -45 -26 -16 -217 94 302 232 326 382 118 273 22 -126 -282 17 -96 -264 -13 -181 -68 -203 120 5 80 62 153 99 165 335 117 239 204 79 -280 -450 -475 -281 -375 -167 -424 -190 -279 53 185 273 377 146 314 205 118 118 22 -209 -264 -183 84 -183 -110 -200 -310 -255 -82 -114 -349 -362 -264 -422 -366 -211 -264 -220 -258 -94 68 80 161 157 -101 46 9 50 -193 -291 -441 -317 -139 -264 -122 -507 -461 -266 -87 64 170 12 -65 85 262 488 486 524 482 372 364 363 458 443 419 223 138 232 137 148 211 40 -68 -2 11 -37 -33 -14 -273 -206 -65 17 117 233 97 -38 -103 -304 -301 -231 -15 -140 -340 -361 -265 18 14 299 530 322 492 256 345 86 -201 -137 -185 -97 -43 -26 -17 -224 97 312 239 339 400 123 284 23 -127 -273 16 -93 -261 -14 -182 -69 -203 124 6 82 64 158 99 167 342 120 243 205 78 -286 -445 -460 -268 -361 -166 -416 -190 -282 53 185 274 382 149 319 207 118 115 22 -211 -264 -181 83 -183 -107 -196 -302 -255 -81 -111 -340 -354 -261 -420 -366 -204 -256 -214 -251 -91 66 78 160 158 -103 46 9 48 -182 -284 -421 -299 -132 -247 -120 -514 -467 -266 -86 62 166 12 -66 88 273 511 511 529 491 377 382 375 465 446 425 230 142 239 141 152 218 41 -69 -2 11 -36 -33 -15 -271 -207 -66 18 121 240 101 -40 -108 -314 -302 -226 -15 -137 SQ 20221219T135709.6Z 8388.581361 209 1 5.86 2 81.05 135.09 57.67 184.88 0.00 1 0.00 1 0 15 2.230e-03 2.235e-03 7.222e-05 7.214e-05 2.151681e+03 4.029593e+00 1.493127e+02 -6.000000e+00 1.167658e+02 273.47 -2.00 20.00 -2.00 505.31 0.00e+00 1.388385e-03 1.921058e-06 7.760351e-05 -6.000000e+00 6.057329e-05 273.47 -2.00 20.00 -2.00 500.67 0.00e+00 6.955437e-01 1.386835e-03 2.330293e-02 -6.000000e+00 4.338838e-02 222.32 -2.00 3.57 -2.00 502.24 0.00e+00 6.091 0.004 489.00 513.00 1 2.2897e-01 1.0585e-04 8.9382e-03 -6.0000e+00 3.3158e-03 -9.2048e-03 2.7349e-05 6.6512e-04 -6.0000e+00 8.6240e-04 6.2111e-01 2.0659e-04 6.2005e-06 2.9988e-05 -6.0000e+00 1.9662e-04 4.5035e-03 -7.8190e-06 10 0 0 10 0 0 76.65 21.88 1.33 0.00450 0.00594 1496 306 1 4 0 3.760 21.88 14.95 18.56 -121 -283 -150 -60 62 342 446 334 418 287 328 140 -147 -57 -115 1 -75 -65 -71 -160 89 215 218 302 302 192 173 -28 -237 -268 118 11 -195 -17 -281 -197 -88 80 -25 58 62 95 101 140 154 132 181 134 19 -235 -390 -369 -305 -331 -233 -414 -307 -221 -13 204 193 359 111 212 117 111 91 31 -81 -222 -110 41 -115 -166 -218 -364 -212 -77 -109 -230 -288 -242 -369 -303 -214 -218 -298 -122 -129 126 58 156 115 -60 -12 36 81 -234 -251 -306 -212 -71 -340 -264 -490 -477 -223 -60 53 199 105 -1 97 224 369 471 510 378 242 250 358 388 350 404 172 82 236 223 179 268 -25 -151 -3 78 -35 40 24 -209 -164 -27 16 113 212 132 -38 -112 -285 -237 -123 -12 -24 -115 -266 -146 -61 61 345 458 345 431 291 327 138 -143 -57 -115 1 -74 -66 -73 -168 92 224 227 306 308 196 176 -29 -241 -261 113 11 -194 -17 -290 -203 -89 81 -26 59 63 95 102 143 160 137 186 136 19 -239 -384 -354 -289 -317 -231 -410 -310 -225 -13 206 194 365 114 217 118 111 90 31 -81 -219 -107 40 -114 -167 -215 -356 -210 -75 -105 -221 -278 -237 -363 -300 -207 -213 -292 -120 -126 123 57 156 118 -62 -12 36 79 -224 -244 -291 -199 -67 -335 -262 -501 -487 -225 -59 52 196 105 -1 97 226 374 480 523 390 248 253 356 393 352 410 170 81 234 220 176 264 -25 -152 -3 76 -34 40 24 -208 -165 -28 17 116 220 138 -39 -113 -294 -238 -121 -12 -24 SQ 20221219T135715.8Z 8388.581432 209 2 5.93 2 81.03 135.11 57.67 184.91 0.00 1 0.00 1 0 22 2.208e-03 2.213e-03 7.457e-05 7.449e-05 2.158610e+03 4.154037e+00 1.493531e+02 -6.000000e+00 1.156264e+02 273.47 -2.00 20.00 -2.00 505.31 0.00e+00 1.423769e-03 1.983493e-06 7.964573e-05 -6.000000e+00 5.998230e-05 273.47 -2.00 20.00 -2.00 500.67 0.00e+00 7.001972e-01 1.431883e-03 2.357446e-02 -6.000000e+00 4.296529e-02 222.32 -2.00 3.57 -2.00 502.23 0.00e+00 6.084 0.004 489.00 513.00 1 2.8923e-01 1.0925e-04 8.9408e-03 -6.0000e+00 3.2834e-03 -9.1443e-03 2.8263e-05 6.6709e-04 -6.0000e+00 8.5400e-04 5.8493e-01 2.2143e-04 6.4016e-06 3.0248e-05 -6.0000e+00 1.9470e-04 4.5915e-03 -8.8894e-06 10 0 0 10 0 0 96.58 21.88 1.33 0.00459 0.00613 1496 306 1 4 0 3.760 21.88 14.95 18.56 -118 -269 -146 -41 73 317 432 327 426 278 325 143 -147 -50 -104 -1 -71 -77 -63 -161 89 206 216 286 292 164 165 -36 -222 -245 142 7 -182 -23 -287 -208 -96 80 -9 58 72 89 116 141 170 126 179 115 15 -231 -378 -336 -295 -326 -237 -421 -313 -228 -8 212 191 345 109 196 124 100 93 23 -81 -229 -115 35 -116 -168 -228 -364 -200 -81 -112 -218 -295 -236 -365 -293 -207 -213 -309 -139 -121 120 54 143 99 -64 -6 24 54 -229 -256 -293 -211 -81 -338 -256 -487 -489 -218 -77 60 218 98 -18 93 220 362 469 501 354 220 244 369 393 366 416 167 104 228 213 185 269 -24 -142 15 77 -41 51 19 -201 -171 -24 22 113 226 129 -43 -117 -301 -254 -125 2 -9 -110 -256 -144 -41 74 324 450 330 428 285 329 144 -145 -49 -101 -1 -71 -79 -64 -164 90 210 220 293 301 169 169 -37 -220 -242 139 6 -183 -23 -299 -217 -98 81 -9 58 72 90 118 147 178 132 187 118 15 -229 -376 -327 -284 -316 -238 -422 -320 -235 -8 216 195 355 113 203 127 101 92 22 -79 -220 -113 35 -112 -165 -228 -360 -193 -79 -109 -213 -289 -225 -350 -283 -203 -210 -307 -138 -119 119 54 145 98 -64 -6 24 53 -221 -242 -282 -201 -78 -324 -257 -486 -487 -214 -77 59 217 96 -18 94 224 371 482 518 369 228 249 371 389 358 411 167 104 228 212 184 268 -24 -139 14 76 -40 50 19 -202 -174 -25 22 114 228 131 -44 -119 -302 -257 -124 2 -9 SQ 20221219T135721.9Z 8388.581503 209 3 5.96 2 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