File name: Pandora104s1_Downsview_20230123_L2Fit_fwvt1c19d20221101p1-8.txt File generation date: 20241127T164922.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c19p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v19d20221101.txt Level 1 file used: Pandora104s1_Downsview_20230123_L1_smca1c19d20221101p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20221101 First and last pixel inside fitting window: 1632 1782 Nominal wavelengths inside fitting window [nm]: 492.0915 492.2120 492.3326 492.4531 492.5736 492.6940 492.8145 492.9349 493.0554 493.1758 493.2962 493.4165 493.5369 493.6572 493.7776 493.8979 494.0182 494.1384 494.2587 494.3789 494.4991 494.6193 494.7395 494.8597 494.9798 495.1000 495.2201 495.3402 495.4603 495.5803 495.7004 495.8204 495.9404 496.0604 496.1804 496.3004 496.4203 496.5402 496.6601 496.7800 496.8999 497.0197 497.1396 497.2594 497.3792 497.4990 497.6188 497.7385 497.8582 497.9779 498.0976 498.2173 498.3370 498.4566 498.5763 498.6959 498.8155 498.9350 499.0546 499.1741 499.2937 499.4132 499.5327 499.6521 499.7716 499.8910 500.0104 500.1298 500.2492 500.3686 500.4879 500.6073 500.7266 500.8459 500.9651 501.0844 501.2036 501.3229 501.4421 501.5613 501.6804 501.7996 501.9187 502.0378 502.1569 502.2760 502.3951 502.5141 502.6332 502.7522 502.8712 502.9901 503.1091 503.2280 503.3470 503.4659 503.5848 503.7036 503.8225 503.9413 504.0601 504.1789 504.2977 504.4165 504.5352 504.6540 504.7727 504.8914 505.0100 505.1287 505.2473 505.3659 505.4846 505.6031 505.7217 505.8403 505.9588 506.0773 506.1958 506.3143 506.4327 506.5512 506.6696 506.7880 506.9064 507.0248 507.1431 507.2615 507.3798 507.4981 507.6164 507.7346 507.8529 507.9711 508.0893 508.2075 508.3257 508.4438 508.5620 508.6801 508.7982 508.9163 509.0343 509.1524 509.2704 509.3884 509.5064 509.6244 509.7424 509.8603 509.9782 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230123T133122.8Z 8423.563458 61 1 49.59 2 83.41 125.05 99.28 105.44 0.00 1 0.00 1 0 15 2.639e-03 2.621e-03 5.415e-04 5.404e-04 3.160384e+03 3.103504e+01 2.221033e+02 -6.000000e+00 1.374035e+02 271.77 -2.00 20.00 -2.00 505.31 0.00e+00 1.160345e-03 1.433635e-05 6.476865e-05 -6.000000e+00 7.144067e-05 271.77 -2.00 20.00 -2.00 500.68 0.00e+00 9.511077e-01 1.048058e-02 2.993531e-02 -6.000000e+00 5.173519e-02 223.72 -2.00 3.57 -2.00 502.23 0.00e+00 7.932 0.010 489.00 513.00 1 5.9492e+00 7.9915e-04 1.1522e-02 -6.0000e+00 3.9470e-03 2.9172e-04 2.0686e-04 9.0404e-04 -6.0000e+00 1.0348e-03 1.5533e-03 5.6491e-04 4.6279e-05 3.6324e-05 -6.0000e+00 2.3250e-04 6.2798e-02 1.9864e-04 10 0 0 10 0 0 99.90 21.98 1.23 0.06280 0.06672 56 11 1 4 0 885.310 21.98 14.84 18.85 -472 -513 -97 -87 230 333 311 437 429 282 157 -70 -207 -207 -136 -78 -244 26 -157 107 275 327 278 326 270 188 83 -148 -335 -152 83 -252 -30 -177 -67 -60 132 1 100 -4 165 116 232 293 227 261 195 53 -208 -355 -427 -394 -463 -161 -431 -267 -100 81 203 305 283 200 203 214 70 164 -7 -118 -267 -268 -60 -93 -124 -126 -276 -386 -250 -238 -139 -384 -212 -389 -338 -228 -177 -336 -103 -175 56 234 136 307 64 71 4 224 -118 -281 -463 -510 -274 -374 -209 -367 -571 -319 -260 -81 204 122 64 185 294 402 649 611 501 200 322 256 394 251 588 209 167 217 265 193 288 140 -145 -94 -82 -107 -13 4 -287 -163 -52 61 -13 247 118 107 -55 -234 -401 -355 -159 -55 900000 -442 -497 -97 -85 227 337 317 445 431 279 154 -67 -209 -207 -136 -76 -243 27 -162 110 284 337 289 341 282 196 86 -150 -327 -145 79 -246 -31 -187 -71 -62 137 1 101 -4 168 120 243 310 241 277 203 55 -210 -347 -408 -370 -436 -156 -434 -276 -104 85 210 315 294 209 212 223 72 165 -7 -116 -261 -259 -58 -91 -122 -126 -277 -380 -240 -227 -132 -365 -204 -376 -329 -225 -176 -336 -102 -174 56 234 138 301 64 70 4 223 -114 -267 -432 -469 -254 -356 -208 -361 -566 -313 -251 -81 204 118 62 184 296 407 658 624 516 206 328 256 388 245 572 207 166 215 263 190 284 139 -142 -90 -78 -101 -13 4 -286 -165 -53 62 -14 257 123 112 -58 -244 -408 -353 -155 -54 900000 SQ 20230123T141139.2Z 8423.591426 81 1 6.23 2 77.75 132.78 92.56 111.84 0.00 1 0.00 1 0 15 2.648e-03 2.647e-03 1.766e-03 1.765e-03 1.866301e+03 9.732081e+01 1.319358e+02 -6.000000e+00 1.378521e+02 271.77 -2.00 20.00 -2.00 505.29 0.00e+00 8.156311e-04 4.687376e-05 4.701864e-05 -6.000000e+00 7.167607e-05 271.77 -2.00 20.00 -2.00 500.61 0.00e+00 4.737091e-01 3.424267e-02 1.862369e-02 -6.000000e+00 5.190983e-02 223.72 -2.00 3.57 -2.00 502.18 0.00e+00 4.579 0.002 489.00 513.00 1 6.6090e+00 2.6118e-03 6.6688e-03 -6.0000e+00 3.9602e-03 7.9223e-03 6.8098e-04 5.3317e-04 -6.0000e+00 1.0384e-03 1.3343e-03 7.9050e-04 1.5157e-04 2.2407e-05 -6.0000e+00 2.3330e-04 7.9102e-02 9.0661e-05 12 1 1 12 1 1 999.00 22.09 1.32 0.07910 0.08459 2 5 1 4 0 2019.090 22.09 14.83 18.85 -295 -146 -262 -392 109 292 268 528 132 342 210 479 113 -151 -157 -306 7 89 -165 -82 176 628 85 455 432 278 -290 -113 -258 -35 -266 95 -81 -169 -209 -45 180 -247 143 -3 189 26 -68 -15 316 166 303 94 -309 -476 -295 -238 -322 -355 -348 -135 -306 -143 224 43 514 72 -67 313 178 92 130 -181 -494 -183 81 -152 -236 2 -282 -29 -122 158 288 -395 20 -296 -469 -194 -52 -353 -109 -169 77 -27 203 52 -36 -122 43 -120 -10 137 -150 -569 -168 -229 -131 -334 -662 -204 -386 -165 280 521 140 101 119 47 359 521 310 90 166 372 271 344 437 154 181 223 115 -50 517 291 -297 -3 155 140 379 10 -38 -281 -397 -321 104 121 195 287 -375 -167 -429 -178 -4 153 900000 -284 -145 -263 -393 110 303 280 551 136 346 211 483 113 -151 -156 -311 7 93 -170 -84 181 641 87 471 446 286 -297 -116 -262 -34 -266 96 -84 -176 -219 -46 183 -250 146 -3 195 27 -70 -16 329 172 309 95 -313 -468 -289 -230 -312 -355 -350 -135 -311 -145 226 43 519 73 -68 316 177 92 128 -178 -481 -180 79 -147 -232 2 -281 -29 -119 153 278 -384 20 -286 -455 -190 -52 -352 -108 -168 77 -27 200 52 -36 -123 43 -119 -10 130 -143 -539 -160 -218 -127 -336 -670 -203 -380 -159 277 509 139 102 118 48 361 527 316 92 166 375 269 337 430 154 180 222 115 -49 511 289 -292 -3 151 135 366 10 -38 -276 -396 -323 104 122 198 292 -383 -168 -423 -175 -4 149 900000 SQ 20230123T152035.5Z 8423.639299 121 1 16.35 2 69.76 147.53 81.75 123.56 0.00 1 0.00 1 0 15 2.162e-03 2.161e-03 8.024e-04 8.012e-04 8.726128e+02 4.255355e+01 5.911864e+01 -6.000000e+00 1.125192e+02 271.77 -2.00 20.00 -2.00 505.27 0.00e+00 4.777598e-04 2.125564e-05 2.744314e-05 -6.000000e+00 5.851269e-05 271.77 -2.00 20.00 -2.00 500.56 0.00e+00 2.597133e-01 1.554807e-02 9.854189e-03 -6.000000e+00 4.238407e-02 223.72 -2.00 3.57 -2.00 502.13 0.00e+00 2.862 0.000 489.00 513.00 1 6.5519e+00 1.1853e-03 4.1239e-03 -6.0000e+00 3.2334e-03 8.6259e-03 3.1099e-04 2.9665e-04 -6.0000e+00 8.4810e-04 1.8339e-03 9.6970e-04 6.9003e-05 1.1266e-05 -6.0000e+00 1.9060e-04 8.2142e-02 5.1337e-05 12 1 1 12 1 1 99.53 22.19 1.35 0.08214 0.08887 12 8 1 4 0 1244.320 22.19 15.01 18.99 -366 -307 -231 15 203 429 297 351 262 204 256 3 -67 -120 4 31 -131 -67 -161 -11 246 235 239 257 108 135 53 -192 -124 57 77 -173 83 -203 -164 -72 119 37 20 42 -40 92 77 245 5 220 27 44 -215 -196 -589 -24 -253 -220 -403 -334 -180 -138 50 176 194 262 47 76 232 297 32 -170 -139 -227 55 -129 -62 -217 -274 -252 50 45 -33 -223 -168 -51 -391 -122 -239 -298 -112 -183 -13 336 234 238 -171 14 -97 152 -135 -244 -290 -349 1 -253 -272 -351 -497 -264 -100 -160 276 61 56 -2 88 319 472 401 180 101 150 260 337 334 628 200 91 194 206 126 273 194 -251 -40 141 -2 -75 134 -148 -121 -61 30 68 175 95 16 -142 -293 -235 -366 47 66 900000 -362 -303 -237 15 209 450 314 371 273 208 259 3 -68 -121 4 31 -134 -70 -166 -11 253 241 246 267 112 140 54 -199 -123 57 78 -172 86 -211 -171 -74 121 38 21 44 -42 96 79 253 5 227 27 46 -218 -192 -584 -23 -247 -213 -406 -345 -182 -139 52 181 195 264 48 76 237 297 32 -167 -135 -217 53 -125 -61 -217 -273 -246 48 44 -33 -218 -160 -49 -379 -119 -237 -297 -112 -183 -13 335 236 237 -173 14 -95 153 -132 -234 -273 -335 1 -242 -263 -352 -500 -262 -98 -158 273 59 56 -2 90 326 483 412 181 101 152 259 331 324 611 197 90 191 203 124 267 190 -244 -39 136 -2 -72 127 -144 -120 -61 30 69 178 94 16 -142 -288 -232 -353 44 63 900000 SQ 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