File name: Pandora104s1_Downsview_20230207_L2Fit_fwvt1c19d20221101p1-8.txt
File generation date: 20241127T170727.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c19p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v19d20221101.txt
Level 1 file used: Pandora104s1_Downsview_20230207_L1_smca1c19d20221101p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230207
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 14 for VP 20221101
First and last pixel inside fitting window: 1632 1782
Nominal wavelengths inside fitting window [nm]: 492.0915 492.2120 492.3326 492.4531 492.5736 492.6940 492.8145 492.9349 493.0554 493.1758 493.2962 493.4165 493.5369 493.6572 493.7776 493.8979 494.0182 494.1384 494.2587 494.3789 494.4991 494.6193 494.7395 494.8597 494.9798 495.1000 495.2201 495.3402 495.4603 495.5803 495.7004 495.8204 495.9404 496.0604 496.1804 496.3004 496.4203 496.5402 496.6601 496.7800 496.8999 497.0197 497.1396 497.2594 497.3792 497.4990 497.6188 497.7385 497.8582 497.9779 498.0976 498.2173 498.3370 498.4566 498.5763 498.6959 498.8155 498.9350 499.0546 499.1741 499.2937 499.4132 499.5327 499.6521 499.7716 499.8910 500.0104 500.1298 500.2492 500.3686 500.4879 500.6073 500.7266 500.8459 500.9651 501.0844 501.2036 501.3229 501.4421 501.5613 501.6804 501.7996 501.9187 502.0378 502.1569 502.2760 502.3951 502.5141 502.6332 502.7522 502.8712 502.9901 503.1091 503.2280 503.3470 503.4659 503.5848 503.7036 503.8225 503.9413 504.0601 504.1789 504.2977 504.4165 504.5352 504.6540 504.7727 504.8914 505.0100 505.1287 505.2473 505.3659 505.4846 505.6031 505.7217 505.8403 505.9588 506.0773 506.1958 506.3143 506.4327 506.5512 506.6696 506.7880 506.9064 507.0248 507.1431 507.2615 507.3798 507.4981 507.6164 507.7346 507.8529 507.9711 508.0893 508.2075 508.3257 508.4438 508.5620 508.6801 508.7982 508.9163 509.0343 509.1524 509.2704 509.3884 509.5064 509.6244 509.7424 509.8603 509.9782
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20230207T130059.8Z 8438.542359 275 1 49.89 2 85.34 116.39 83.60 280.47 0.00 1 0.00 1 0 15 2.988e-03 2.966e-03 4.319e-04 4.311e-04 3.877297e+03 2.491146e+01 2.732300e+02 -6.000000e+00 1.556026e+02 271.77 -2.00 20.00 -2.00 505.37 0.00e+00 2.143599e-03 1.148278e-05 1.160336e-04 -6.000000e+00 8.088107e-05 271.77 -2.00 20.00 -2.00 500.91 0.00e+00 9.707332e-01 8.277195e-03 3.883574e-02 -6.000000e+00 5.860054e-02 224.32 -2.00 3.57 -2.00 502.44 0.00e+00 10.358 0.022 489.00 513.00 1 5.2401e+00 6.3097e-04 1.5366e-02 -6.0000e+00 4.4706e-03 -2.6450e-02 1.6232e-04 1.1611e-03 -6.0000e+00 1.1717e-03 2.2191e-03 5.5267e-04 3.6965e-05 4.9830e-05 -6.0000e+00 2.6311e-04 3.9754e-02 3.6374e-04 10 0 0 10 0 0 99.68 22.19 1.68 0.03975 0.04359 55 11 1 4 0 906.920 22.19 14.83 19.08 -712 -512 -244 -28 222 405 438 538 456 315 233 -191 -198 -378 -110 -210 -151 1 -92 136 249 310 313 458 266 306 29 -105 -333 -166 -92 -354 -6 -122 -63 22 80 63 61 127 90 193 164 346 317 262 301 55 -68 -371 -491 -477 -419 -268 -300 -146 -137 19 255 238 360 243 332 182 208 102 -28 -81 -282 -198 -158 -109 -156 -139 -254 -215 -215 -171 -802 -525 -325 -366 -371 -314 -180 -299 -115 -171 71 97 244 270 168 161 230 141 -111 -363 -476 -626 -347 -371 -234 -376 -542 -363 -207 -87 102 165 2 225 370 601 634 765 620 423 279 259 302 339 501 255 184 184 258 104 283 56 -165 -82 -84 -203 -66 40 -83 -149 42 47 75 228 149 122 -26 -283 -510 -346 -317 -94 900000 -638 -475 -235 -28 212 394 430 529 441 300 231 -187 -193 -365 -107 -206 -145 1 -92 136 250 311 315 466 271 310 30 -104 -317 -155 -86 -339 -6 -126 -66 23 81 63 61 127 91 198 163 347 320 263 300 57 -68 -364 -470 -450 -396 -262 -304 -145 -137 19 254 237 362 245 336 184 207 100 -28 -81 -281 -194 -156 -108 -157 -136 -248 -215 -212 -167 -785 -512 -320 -363 -370 -303 -175 -293 -112 -167 69 95 242 274 172 163 228 138 -106 -356 -458 -595 -332 -348 -229 -384 -559 -370 -208 -86 102 167 2 235 374 611 647 786 644 440 287 262 301 349 518 256 185 186 261 104 285 57 -165 -84 -85 -205 -67 40 -85 -154 45 50 80 244 161 132 -28 -304 -536 -354 -321 -95 900000
SQ 20230207T131153.5Z 8438.549924 278 1 18.75 2 83.59 118.36 85.50 282.23 0.00 1 0.00 1 0 15 2.661e-03 2.656e-03 1.292e-04 1.291e-04 3.151505e+03 7.340844e+00 2.237294e+02 -6.000000e+00 1.385279e+02 271.77 -2.00 20.00 -2.00 505.34 0.00e+00 1.739818e-03 3.434810e-06 9.601651e-05 -6.000000e+00 7.201079e-05 271.77 -2.00 20.00 -2.00 500.83 0.00e+00 7.802701e-01 2.483938e-03 3.165561e-02 -6.000000e+00 5.219008e-02 224.32 -2.00 3.57 -2.00 502.36 0.00e+00 8.111 0.010 489.00 513.00 1 2.2814e+00 1.8922e-04 1.1930e-02 -6.0000e+00 3.9814e-03 -2.6555e-02 4.8998e-05 9.2025e-04 -6.0000e+00 1.0439e-03 5.9651e-02 8.3113e-04 1.1069e-05 4.1594e-05 -6.0000e+00 2.3436e-04 5.5337e-02 2.4702e-04 10 0 0 10 0 0 95.18 22.19 1.47 0.05534 0.06110 520 107 1 4 0 35.830 22.19 14.77 18.88 -454 -332 -165 46 279 503 403 472 381 324 240 -146 -84 -230 -127 -93 -138 -37 -67 68 259 252 343 397 264 228 74 -127 -290 -116 -47 -311 -57 -193 -171 -68 100 41 13 89 50 171 160 302 226 273 175 74 -176 -381 -500 -410 -440 -278 -366 -321 -173 -25 226 193 423 233 242 205 134 124 -12 -83 -276 -259 -105 -98 -206 -149 -365 -279 -231 -176 -306 -410 -300 -354 -332 -206 -234 -297 -171 -165 62 111 167 212 49 80 67 136 -158 -332 -398 -506 -202 -402 -261 -428 -538 -312 -161 -67 172 151 33 169 275 446 571 635 503 319 220 302 362 379 516 314 174 240 280 174 304 79 -155 -74 12 -112 0 -14 -126 -142 16 32 126 215 210 68 -59 -250 -374 -285 -199 -133 900000 -420 -318 -158 45 277 510 396 465 384 321 236 -142 -81 -220 -121 -90 -138 -37 -67 68 259 253 345 404 268 231 75 -126 -286 -112 -45 -309 -57 -199 -177 -70 101 42 13 88 50 174 165 315 228 275 181 76 -176 -370 -492 -397 -428 -268 -366 -329 -173 -26 233 198 422 234 244 206 138 125 -12 -83 -270 -250 -102 -96 -204 -150 -368 -276 -223 -168 -293 -393 -291 -346 -326 -205 -236 -300 -173 -166 63 108 165 214 50 81 67 132 -156 -321 -378 -474 -190 -390 -255 -435 -551 -316 -161 -65 169 151 33 175 277 453 581 651 521 331 225 304 372 384 526 313 174 240 280 174 303 79 -154 -74 12 -111 0 -14 -128 -145 16 33 133 227 223 70 -61 -265 -388 -288 -198 -133 900000
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