File name: Pandora104s1_Downsview_20230208_L2Fit_fout2c19d20221101p1-8.txt
File generation date: 20241127T170404.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c19p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v19d20221101.txt
Level 1 file used: Pandora104s1_Downsview_20230208_L1_smca1c19d20221101p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230208
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: based on session 14 for VP 20221101
First and last pixel inside fitting window: 207 349
Nominal wavelengths inside fitting window [nm]: 305.0318 305.1723 305.3129 305.4534 305.5939 305.7344 305.8749 306.0154 306.1558 306.2963 306.4367 306.5771 306.7176 306.8580 306.9984 307.1388 307.2791 307.4195 307.5598 307.7002 307.8405 307.9808 308.1211 308.2614 308.4017 308.5420 308.6823 308.8225 308.9628 309.1030 309.2432 309.3834 309.5236 309.6638 309.8040 309.9441 310.0843 310.2244 310.3646 310.5047 310.6448 310.7849 310.9250 311.0650 311.2051 311.3451 311.4852 311.6252 311.7652 311.9052 312.0452 312.1852 312.3252 312.4651 312.6051 312.7450 312.8850 313.0249 313.1648 313.3047 313.4446 313.5844 313.7243 313.8641 314.0040 314.1438 314.2836 314.4234 314.5632 314.7030 314.8427 314.9825 315.1223 315.2620 315.4017 315.5414 315.6811 315.8208 315.9605 316.1002 316.2398 316.3795 316.5191 316.6587 316.7983 316.9379 317.0775 317.2171 317.3566 317.4962 317.6357 317.7753 317.9148 318.0543 318.1938 318.3333 318.4727 318.6122 318.7516 318.8911 319.0305 319.1699 319.3093 319.4487 319.5881 319.7275 319.8668 320.0062 320.1455 320.2848 320.4242 320.5635 320.7027 320.8420 320.9813 321.1205 321.2598 321.3990 321.5382 321.6774 321.8166 321.9558 322.0950 322.2342 322.3733 322.5125 322.6516 322.7907 322.9298 323.0689 323.2080 323.3470 323.4861 323.6252 323.7642 323.9032 324.0422 324.1812 324.3202 324.4592 324.5982 324.7371 324.8761
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230208T151119.1Z 8439.632860 344 1 49.60 2 66.94 142.77 102.65 291.64 0.00 1 0.00 1 0 17 2.343e-02 5.939e-03 3.346e-03 3.827e-04 3.741839e-01 1.950175e-04 4.457155e-03 -6.000000e+00 1.348281e-02 224.36 -2.00 3.57 -2.00 319.01 0.00e+00 2.020683e-03 4.472027e-05 4.436902e-04 -6.000000e+00 5.810729e-04 271.77 -2.00 20.00 -2.00 318.47 0.00e+00 2.533 0.000 302.00 328.00 3 1.1293e+00 5.3102e-04 3.1252e-02 -6.0000e+00 3.3360e-02 2.9822e-02 6.1022e-04 1.9181e-02 -6.0000e+00 3.6400e-02 -1.1593e-02 4.4892e-04 9.9302e-03 -6.0000e+00 2.1597e-02 -5.6128e-03 2.3640e-04 3.5497e-03 -6.0000e+00 9.0520e-03 9.0367e-03 2.6621e-04 1.1326e-05 3.5481e-05 -6.0000e+00 6.4866e-04 8.9826e-02 0.0000e+00 10 0 0 10 0 0 99.98 22.19 0.24 0.08983 0.09183 1134 232 1 5 0 43.730 22.19 14.98 19.12 -3874 -126 -5598 -4198 -10283 -3760 -9406 -3508 -8371 -7718 -10658 -5560 -4656 -546 -636 -135 560 1182 1799 1871 1761 -173 1482 -843 -965 -3284 -2382 -3948 -1360 -1881 1078 -232 435 -3019 -4170 -2992 -2521 -991 -1025 -1324 -2083 -832 -749 -403 -75 781 -219 557 0 948 1384 1887 1225 1450 596 1084 309 -164 179 706 1758 1945 1823 1375 385 -231 659 405 1850 710 149 -201 -127 -150 -428 -764 -838 -1187 -927 -1153 -1756 -1441 -2141 -1441 -723 -106 203 401 533 434 424 483 -46 671 422 246 120 299 -324 -685 -477 -830 277 14 -535 -1530 -468 -545 555 334 698 15 382 78 653 800 935 270 191 -156 -302 -140 305 153 237 335 -246 834 -32 -278 -715 -648 -345 16 99 -40 109 249 221 -224 -45 -239 123 -131 -4 -210 -142 -341 -117 -339 -136 -371 -352 -504 -279 -276 -37 -50 -12 51 115 181 198 188 -19 164 -102 -124 -443 -312 -502 -165 -236 148 -36 74 -530 -695 -506 -476 -221 -273 -403 -691 -286 -266 -144 -27 280 -78 199 0 351 552 813 563 703 299 558 162 -86 92 360 928 1121 1146 853 240 -147 399 248 1237 497 112 -156 -96 -108 -312 -503 -514 -723 -617 -882 -1390 -1258 -2004 -1405 -752 -117 234 468 615 480 436 458 -41 601 414 269 147 371 -428 -886 -620 -986 312 16 -688 -1912 -610 -743 801 521 1152 25 619 118 922 1076 1270 385 291 -250 -487 -220 462 224 331 487 -342 1181 -46 -435 -1191 -1110 -606 29 179 -76 211 490 435 -432 -83 -453 229
SS 20230208T153512.2Z 8439.649447 356 1 49.65 2 64.50 148.51 106.54 296.01 0.00 1 0.00 1 0 17 2.148e-02 5.836e-03 1.229e-02 1.535e-03 3.404470e-01 7.845947e-04 4.055267e-03 -6.000000e+00 1.236274e-02 224.36 -2.00 3.57 -2.00 319.26 0.00e+00 2.054432e-03 1.885688e-04 4.343502e-04 -6.000000e+00 5.326372e-04 271.77 -2.00 20.00 -2.00 318.72 0.00e+00 2.308 0.000 302.00 328.00 3 2.9349e+00 2.1481e-03 2.8457e-02 -6.0000e+00 3.0589e-02 1.3618e-02 2.4742e-03 1.7434e-02 -6.0000e+00 3.3374e-02 1.6430e-02 1.8067e-03 9.0524e-03 -6.0000e+00 1.9802e-02 -1.8072e-02 9.4624e-04 3.3632e-03 -6.0000e+00 8.3015e-03 1.9224e-03 4.6266e-04 4.6681e-05 3.4554e-05 -6.0000e+00 5.9489e-04 8.8254e-02 0.0000e+00 10 0 0 10 0 0 100.00 22.19 0.25 0.08825 0.09173 1385 284 1 5 0 35.760 22.19 14.83 18.93 -4767 5936 4349 -4973 -5234 -7872 -515 -7135 4280 -9278 632 -7522 4978 -2487 4380 -2311 3854 1292 4169 1414 1104 -191 209 -76 -314 -2548 -3554 -483 -1856 803 855 2362 -102 -249 -4400 1122 -2072 1199 -1017 -946 -2753 -1512 -2133 -1002 -1018 -66 -260 -439 198 96 2125 498 1630 365 1269 498 969 -581 403 238 2295 1641 2057 909 -23 -73 445 757 1606 1109 -269 96 -480 210 -817 102 -1175 81 -529 -665 -1612 -1206 -2177 -1286 -827 -148 441 267 581 246 746 404 500 528 677 -38 321 256 -18 -813 -338 -950 384 -180 -480 -1558 -464 -557 526 528 483 183 208 226 449 763 817 361 81 -250 -351 -76 235 128 153 242 -314 879 49 -355 -748 -819 -308 -164 244 -185 258 90 391 -226 161 -315 178 -191 228 173 -198 -193 -297 -20 -333 194 -467 31 -413 285 -182 346 -215 354 130 424 155 123 -21 24 -9 -41 -329 -483 -61 -230 99 118 353 -17 -42 -726 180 -385 242 -251 -265 -847 -481 -706 -330 -338 -22 -85 -144 64 32 754 194 665 159 561 228 449 -271 182 108 1137 841 1140 543 -14 -43 249 423 984 726 -190 70 -365 151 -549 61 -661 44 -317 -456 -1249 -1026 -1988 -1220 -839 -159 495 305 655 266 746 373 429 456 634 -40 371 327 -25 -1081 -416 -1073 411 -203 -588 -2013 -624 -783 780 841 814 311 342 348 638 1031 1116 516 125 -405 -572 -121 360 189 216 329 -406 1155 70 -554 -1238 -1391 -534 -298 469 -374 530 188 818 -463 317 -595 329
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