File name: Pandora104s1_Downsview_20230625_L2Fit_fnvh3c23d20230421p1-8.txt File generation date: 20241127T183356.2Z Data description: Level 2 spectral fitting results file Data file version: fnvh3c23p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt Level 1 file used: Pandora104s1_Downsview_20230625_L1_smca1c23d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421" First and last pixel inside fitting window: 1172 1613 Nominal wavelengths inside fitting window [nm]: 435.0672 435.1951 435.3230 435.4510 435.5789 435.7067 435.8346 435.9625 436.0903 436.2181 436.3460 436.4738 436.6015 436.7293 436.8571 436.9848 437.1125 437.2402 437.3679 437.4956 437.6232 437.7509 437.8785 438.0061 438.1337 438.2613 438.3889 438.5164 438.6440 438.7715 438.8990 439.0265 439.1540 439.2814 439.4089 439.5363 439.6637 439.7911 439.9185 440.0459 440.1733 440.3006 440.4279 440.5552 440.6825 440.8098 440.9371 441.0643 441.1916 441.3188 441.4460 441.5732 441.7003 441.8275 441.9546 442.0818 442.2089 442.3360 442.4631 442.5901 442.7172 442.8442 442.9712 443.0982 443.2252 443.3522 443.4792 443.6061 443.7330 443.8599 443.9868 444.1137 444.2406 444.3674 444.4943 444.6211 444.7479 444.8747 445.0015 445.1282 445.2550 445.3817 445.5084 445.6351 445.7618 445.8884 446.0151 446.1417 446.2683 446.3950 446.5215 446.6481 446.7747 446.9012 447.0277 447.1542 447.2807 447.4072 447.5337 447.6601 447.7866 447.9130 448.0394 448.1658 448.2921 448.4185 448.5448 448.6712 448.7975 448.9238 449.0500 449.1763 449.3026 449.4288 449.5550 449.6812 449.8074 449.9336 450.0597 450.1858 450.3120 450.4381 450.5642 450.6902 450.8163 450.9423 451.0684 451.1944 451.3204 451.4464 451.5723 451.6983 451.8242 451.9501 452.0760 452.2019 452.3278 452.4537 452.5795 452.7053 452.8311 452.9569 453.0827 453.2085 453.3342 453.4599 453.5857 453.7114 453.8370 453.9627 454.0884 454.2140 454.3396 454.4652 454.5908 454.7164 454.8419 454.9675 455.0930 455.2185 455.3440 455.4695 455.5949 455.7204 455.8458 455.9712 456.0966 456.2220 456.3474 456.4727 456.5981 456.7234 456.8487 456.9740 457.0993 457.2245 457.3498 457.4750 457.6002 457.7254 457.8506 457.9757 458.1009 458.2260 458.3511 458.4762 458.6013 458.7264 458.8514 458.9765 459.1015 459.2265 459.3515 459.4764 459.6014 459.7263 459.8513 459.9762 460.1011 460.2259 460.3508 460.4756 460.6005 460.7253 460.8501 460.9748 461.0996 461.2244 461.3491 461.4738 461.5985 461.7232 461.8479 461.9725 462.0971 462.2218 462.3464 462.4709 462.5955 462.7201 462.8446 462.9691 463.0936 463.2181 463.3426 463.4671 463.5915 463.7159 463.8403 463.9647 464.0891 464.2135 464.3378 464.4622 464.5865 464.7108 464.8351 464.9593 465.0836 465.2078 465.3320 465.4562 465.5804 465.7046 465.8287 465.9529 466.0770 466.2011 466.3252 466.4492 466.5733 466.6973 466.8214 466.9454 467.0694 467.1933 467.3173 467.4412 467.5652 467.6891 467.8130 467.9368 468.0607 468.1846 468.3084 468.4322 468.5560 468.6798 468.8035 468.9273 469.0510 469.1747 469.2984 469.4221 469.5458 469.6694 469.7931 469.9167 470.0403 470.1639 470.2874 470.4110 470.5345 470.6580 470.7815 470.9050 471.0285 471.1519 471.2754 471.3988 471.5222 471.6456 471.7690 471.8923 472.0157 472.1390 472.2623 472.3856 472.5089 472.6321 472.7553 472.8786 473.0018 473.1250 473.2481 473.3713 473.4944 473.6176 473.7407 473.8638 473.9868 474.1099 474.2330 474.3560 474.4790 474.6020 474.7250 474.8479 474.9709 475.0938 475.2167 475.3396 475.4625 475.5853 475.7082 475.8310 475.9538 476.0766 476.1994 476.3222 476.4449 476.5676 476.6904 476.8130 476.9357 477.0584 477.1810 477.3037 477.4263 477.5489 477.6715 477.7940 477.9166 478.0391 478.1616 478.2841 478.4066 478.5291 478.6515 478.7739 478.8964 479.0187 479.1411 479.2635 479.3858 479.5082 479.6305 479.7528 479.8751 479.9973 480.1196 480.2418 480.3640 480.4862 480.6084 480.7306 480.8527 480.9748 481.0970 481.2191 481.3411 481.4632 481.5852 481.7073 481.8293 481.9513 482.0733 482.1952 482.3172 482.4391 482.5610 482.6829 482.8048 482.9267 483.0485 483.1703 483.2921 483.4139 483.5357 483.6575 483.7792 483.9010 484.0227 484.1444 484.2660 484.3877 484.5093 484.6310 484.7526 484.8742 484.9957 485.1173 485.2388 485.3604 485.4819 485.6034 485.7249 485.8463 485.9678 486.0892 486.2106 486.3320 486.4533 486.5747 486.6960 486.8174 486.9387 487.0600 487.1812 487.3025 487.4237 487.5449 487.6662 487.7873 487.9085 488.0297 488.1508 488.2719 488.3930 488.5141 488.6352 488.7562 488.8773 488.9983 489.1193 489.2403 489.3612 489.4822 489.6031 489.7240 489.8449 489.9658 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Oxygen dimer effective temperature [K] Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Ozone effective temperature [K] Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 73: Lower limit used for wavelength scaling [nm] Column 74: Upper limit used for wavelength scaling [nm] Column 75: Order of smoothing polynomial Column 76: Smoothing polynomial coefficient, order 0 Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 81: Smoothing polynomial coefficient, order 1 Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 86: Smoothing polynomial coefficient, order 2 Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 91: Smoothing polynomial coefficient, order 3 Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 96: Smoothing polynomial coefficient, order 4 Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 101: Mean value of measured data inside fitting window [same units as measurements] Column 102: Offset polynomial coefficient, order 0 Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 107: Offset polynomial coefficient, order 1 Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 112: Wavelength change polynomial coefficient, order 0 Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 117: Wavelength change polynomial coefficient, order 1 Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined Column 131: Wavelength effective temperature [°C], 999=no effective temperature given Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 135: Number of bright count cycles Column 136: Number of dark count cycles Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 140: Integration time [ms] Column 141: Temperature at electronics board [°C], 999=no temperature signal Column 142: Spectrometer control temperature [°C], 999=no temperature signal Column 143: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 144-585: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 586-1027: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- EK 20230625T100314.7Z 8576.418921 55 1 12.09 6 86.82 60.17 130.49 346.03 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3.5963e-05 1.8899e-06 -6.0000e+00 4.1344e-05 -7.2067e-05 3.1768e-05 9.0588e-07 -6.0000e+00 3.5990e-05 -3.6973e-03 -5.6500e-07 12 8 8 10 0 0 24.91 23.22 1.39 -0.00370 0.00607 14 3 1 1 0 862.730 23.22 15.00 18.96 321 -161 187 128 89 114 21 198 74 15 139 118 -1 -201 -239 236 -96 -361 129 141 58 17 5 -65 -307 -118 285 472 -436 129 -133 -261 -416 -126 -226 149 87 -118 -362 8 -71 -10 -134 -180 72 39 373 -223 48 109 -54 61 -114 -4 -165 59 142 255 358 -1504 258 491 155 -256 142 33 -225 318 5 -291 -167 317 -56 -294 -267 -81 -185 -40 201 -188 -13 -151 385 387 309 -82 235 156 303 42 68 -8 212 -143 62 217 -67 -86 25 87 -51 -175 -34 162 76 110 -271 295 115 266 56 -201 -136 77 -51 -199 -14 -49 -345 -112 162 -79 25 -63 298 -111 398 50 2 21 -122 143 -326 -9 -121 -17 -218 -264 -173 -17 -31 -375 3 -77 -27 319 77 75 -65 -67 -222 104 -321 67 191 -126 -10 -315 130 21 107 279 246 146 83 50 222 -259 -499 44 408 202 73 -7 -38 17 -56 54 77 91 60 49 -18 103 -197 285 156 173 104 -181 122 207 -8 -88 -64 382 -231 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