File name: Pandora104s1_Downsview_20230630_L2Fit_fwvt1c23d20230421p1-8.txt
File generation date: 20241127T185521.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c23p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt
Level 1 file used: Pandora104s1_Downsview_20230630_L1_smca1c23d20230421p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230630
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421"
First and last pixel inside fitting window: 1630 1780
Nominal wavelengths inside fitting window [nm]: 492.0182 492.1387 492.2593 492.3798 492.5004 492.6209 492.7414 492.8618 492.9823 493.1027 493.2231 493.3435 493.4639 493.5843 493.7046 493.8250 493.9453 494.0656 494.1859 494.3061 494.4264 494.5466 494.6668 494.7870 494.9072 495.0274 495.1475 495.2676 495.3877 495.5078 495.6279 495.7480 495.8680 495.9880 496.1080 496.2280 496.3480 496.4680 496.5879 496.7078 496.8277 496.9476 497.0675 497.1873 497.3071 497.4270 497.5468 497.6665 497.7863 497.9060 498.0258 498.1455 498.2652 498.3849 498.5045 498.6242 498.7438 498.8634 498.9830 499.1026 499.2221 499.3416 499.4612 499.5807 499.7002 499.8196 499.9391 500.0585 500.1779 500.2973 500.4167 500.5361 500.6554 500.7747 500.8941 501.0133 501.1326 501.2519 501.3711 501.4903 501.6096 501.7287 501.8479 501.9671 502.0862 502.2053 502.3244 502.4435 502.5626 502.6816 502.8007 502.9197 503.0387 503.1576 503.2766 503.3955 503.5145 503.6334 503.7523 503.8711 503.9900 504.1088 504.2277 504.3465 504.4652 504.5840 504.7028 504.8215 504.9402 505.0589 505.1776 505.2963 505.4149 505.5335 505.6521 505.7707 505.8893 506.0079 506.1264 506.2449 506.3634 506.4819 506.6004 506.7188 506.8373 506.9557 507.0741 507.1924 507.3108 507.4292 507.5475 507.6658 507.7841 507.9023 508.0206 508.1388 508.2571 508.3753 508.4935 508.6116 508.7298 508.8479 508.9660 509.0841 509.2022 509.3202 509.4383 509.5563 509.6743 509.7923 509.9103
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20230630T145250.1Z 8581.620025 242 1 48.85 2 36.78 111.86 158.69 12.42 0.00 1 0.00 1 0 15 2.365e-03 2.356e-03 6.569e-04 6.558e-04 3.753181e+03 4.020459e+01 2.652554e+02 -6.000000e+00 1.300085e+02 285.44 -2.00 20.00 -2.00 505.27 0.00e+00 8.791819e-04 1.798113e-05 5.216826e-05 -6.000000e+00 6.617859e-05 285.44 -2.00 20.00 -2.00 500.45 0.00e+00 1.106292e-02 1.287377e-02 2.650600e-02 -6.000000e+00 4.659792e-02 232.97 -2.00 3.57 -2.00 502.04 0.00e+00 1.248 0.000 489.00 513.00 1 7.2626e+00 9.8509e-04 3.0988e-03 -6.0000e+00 3.5688e-03 -5.9525e-03 2.5608e-04 6.2829e-04 -6.0000e+00 9.3370e-04 1.1330e-03 2.0635e-04 5.6057e-05 3.2266e-05 -6.0000e+00 2.0883e-04 -2.7392e-03 1.4521e-05 10 0 0 10 0 0 97.09 22.80 1.29 -0.00274 -0.00131 23 5 1 4 0 2123.620 22.80 15.00 18.56 -82 -175 -339 -104 -32 65 366 301 319 280 204 328 49 -113 -240 -194 -45 -134 81 -61 -147 211 280 169 463 216 233 49 -149 -177 -320 52 -229 6 -84 -202 -101 78 61 32 18 223 146 160 181 237 203 80 6 20 -330 -261 -281 -457 -323 -250 -327 -312 -125 -17 96 316 358 116 175 139 100 65 1 -121 -439 -122 78 -220 -52 -274 -246 -218 -181 -129 -184 -138 -362 -194 -270 -211 -279 -116 -89 -33 135 215 527 202 84 224 175 67 -222 -328 -537 -324 -297 -485 -354 -581 -331 -326 88 23 175 37 69 78 238 527 453 468 232 106 119 194 126 355 476 236 88 388 185 231 266 -65 -32 151 -86 3 75 -84 -188 -182 -50 -34 159 162 125 3 -76 -327 -287 -208 -29 -78 -168 -331 -104 -32 67 381 315 335 293 211 336 50 -113 -241 -194 -46 -137 84 -64 -154 221 293 177 486 227 244 52 -155 -180 -317 51 -229 6 -88 -213 -106 81 63 33 18 228 150 166 189 248 212 83 6 20 -330 -256 -271 -440 -315 -249 -332 -321 -128 -17 98 323 367 119 179 141 101 65 1 -119 -429 -118 76 -216 -51 -273 -243 -212 -174 -124 -176 -132 -351 -188 -264 -208 -276 -114 -87 -32 133 213 527 204 85 222 171 65 -212 -309 -500 -302 -279 -467 -350 -583 -330 -323 86 22 171 37 69 78 240 532 458 476 236 108 120 192 123 347 468 233 87 382 182 226 261 -63 -31 144 -82 3 71 -82 -185 -180 -50 -34 159 162 126 3 -76 -324 -279 -199 -28
SQ 20230630T150532.5Z 8581.628849 246 1 49.48 2 34.68 115.33 158.12 19.82 0.00 1 0.00 1 0 15 2.285e-03 2.286e-03 5.671e-04 5.661e-04 3.789511e+03 3.461460e+01 2.596893e+02 -6.000000e+00 1.256396e+02 285.44 -2.00 20.00 -2.00 505.27 0.00e+00 7.325105e-04 1.559097e-05 4.539618e-05 -6.000000e+00 6.395505e-05 285.44 -2.00 20.00 -2.00 500.46 0.00e+00 1.471678e-02 1.111321e-02 2.839025e-02 -6.000000e+00 4.502782e-02 232.97 -2.00 3.57 -2.00 502.06 0.00e+00 1.215 0.000 489.00 513.00 1 6.9990e+00 8.5191e-04 3.1176e-03 -6.0000e+00 3.4486e-03 -7.0602e-03 2.2053e-04 6.5777e-04 -6.0000e+00 9.0216e-04 1.4841e-03 1.3592e-04 4.8228e-05 2.9652e-05 -6.0000e+00 2.0183e-04 -2.2920e-03 1.6018e-05 10 0 0 10 0 0 90.88 22.80 1.34 -0.00229 -0.00135 30 6 1 4 0 1648.970 22.80 15.00 18.55 -154 -187 -278 -242 29 118 566 250 314 226 246 339 13 -193 -131 -262 -70 -153 -41 -102 -6 132 142 253 320 309 142 258 -126 -248 -286 81 -228 -9 -82 -204 -80 -19 -4 19 105 34 298 133 297 254 148 104 164 1 -208 -329 -341 -378 -220 -264 -382 -215 -169 157 127 318 199 157 140 69 119 65 -80 -135 -392 -64 -6 -134 -25 -265 -308 0 -164 -223 -217 -285 -280 -347 -192 -221 -212 -194 -36 7 200 104 402 70 -10 229 105 122 -345 -224 -491 -354 -312 -201 -262 -510 -456 -162 -52 66 171 57 16 146 341 333 548 433 292 139 131 298 239 395 471 171 115 254 137 169 270 -192 62 97 -79 -77 -19 -155 -223 -110 -81 68 121 202 43 -39 -30 -211 -305 -155 -48 -148 -182 -279 -240 30 122 597 268 337 241 256 350 13 -194 -131 -260 -70 -157 -43 -105 -7 135 145 259 331 320 147 264 -128 -254 -284 80 -228 -9 -84 -213 -83 -19 -4 20 109 36 300 135 305 263 153 106 166 1 -211 -324 -329 -362 -214 -268 -380 -217 -171 158 128 320 202 159 142 69 117 66 -80 -135 -387 -62 -6 -133 -26 -259 -311 0 -159 -215 -209 -277 -275 -342 -191 -224 -205 -188 -34 7 193 101 398 70 -10 225 102 121 -334 -213 -458 -330 -297 -189 -258 -514 -457 -159 -50 64 166 56 16 148 347 341 561 448 304 143 133 296 234 384 463 169 113 251 135 165 265 -188 60 91 -74 -72 -18 -151 -221 -110 -82 69 124 207 42 -38 -31 -213 -299 -148 -46
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