File name: Pandora104s1_Downsview_20230729_L2Fit_fwvt1c2d20130709p1-8.txt File generation date: 20230801T070937.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v2d20130709.txt Level 1 file used: Pandora104s1_Downsview_20230729_L1_smca1c2d20130709p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230729 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 5 First and last pixel inside fitting window: 1634 1784 Nominal wavelengths inside fitting window [nm]: 492.1188 492.2393 492.3597 492.4802 492.6006 492.7210 492.8414 492.9618 493.0821 493.2025 493.3228 493.4431 493.5634 493.6837 493.8039 493.9242 494.0444 494.1646 494.2848 494.4049 494.5251 494.6452 494.7654 494.8854 495.0055 495.1256 495.2456 495.3657 495.4857 495.6057 495.7257 495.8456 495.9656 496.0855 496.2054 496.3253 496.4452 496.5650 496.6849 496.8047 496.9245 497.0443 497.1641 497.2838 497.4036 497.5233 497.6430 497.7627 497.8823 498.0020 498.1216 498.2412 498.3608 498.4804 498.6000 498.7195 498.8390 498.9586 499.0780 499.1975 499.3170 499.4364 499.5558 499.6753 499.7946 499.9140 500.0334 500.1527 500.2720 500.3913 500.5106 500.6299 500.7491 500.8684 500.9876 501.1068 501.2260 501.3451 501.4643 501.5834 501.7025 501.8216 501.9407 502.0597 502.1788 502.2978 502.4168 502.5358 502.6548 502.7737 502.8926 503.0116 503.1305 503.2493 503.3682 503.4871 503.6059 503.7247 503.8435 503.9623 504.0810 504.1998 504.3185 504.4372 504.5559 504.6746 504.7932 504.9119 505.0305 505.1491 505.2677 505.3862 505.5048 505.6233 505.7418 505.8603 505.9788 506.0973 506.2157 506.3341 506.4525 506.5709 506.6893 506.8076 506.9260 507.0443 507.1626 507.2809 507.3992 507.5174 507.6356 507.7538 507.8720 507.9902 508.1084 508.2265 508.3447 508.4628 508.5808 508.6989 508.8170 508.9350 509.0530 509.1710 509.2890 509.4070 509.5249 509.6429 509.7608 509.8787 509.9965 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230729T152000.5Z 8610.638895 219 1 48.83 2 36.15 123.97 159.48 43.04 0.00 1 0.00 1 0 22 3.668e-03 3.574e-03 9.080e-04 9.056e-04 6.701360e+03 5.945351e+01 5.193873e+02 -6.000000e+00 2.036054e+02 287.11 -2.00 20.00 -2.00 505.31 0.00e+00 5.679887e-04 2.511686e-05 2.371229e-05 -6.000000e+00 1.032895e-04 287.11 -2.00 20.00 -2.00 500.56 0.00e+00 4.831866e-02 1.755435e-02 1.849638e-02 -6.000000e+00 7.204095e-02 232.54 -2.00 3.57 -2.00 502.13 0.00e+00 1.238 0.000 489.00 513.00 1 6.3451e+00 1.3488e-03 2.6068e-03 -6.0000e+00 5.5219e-03 2.8691e-03 3.4150e-04 7.3399e-04 -6.0000e+00 1.4444e-03 2.8312e-03 2.4275e-02 7.9899e-05 5.7660e-05 -6.0000e+00 3.3190e-04 1.7442e-01 2.3477e-04 10 0 0 10 0 0 91.81 23.22 1.35 0.17442 0.34280 15 3 1 4 0 3255.090 23.22 14.99 18.91 -45 47 233 269 357 125 226 162 186 -100 -146 -184 -15 -53 85 -116 60 0 139 358 354 225 104 191 -310 -248 -285 48 -430 -110 -232 -153 -138 125 135 65 199 73 121 191 337 132 155 33 140 -292 -99 -540 -416 -460 23 -377 -200 -255 -144 305 263 414 408 211 281 175 97 101 36 94 -348 99 -103 -102 -188 -88 -230 -38 -89 -82 -3159 -93 -225 -314 -115 -385 -176 -67 -28 49 352 69 686 -84 78 171 179 126 -152 -373 -397 -384 -311 -310 -393 -601 -620 -92 77 22 332 10 -36 399 -60 571 537 823 271 396 46 383 261 442 328 90 11 277 126 137 294 -65 21 -69 -42 -279 81 -27 -115 -84 70 174 123 68 126 8 49 -353 -102 -91 -192 31 -242 900000 900000 -47 50 240 280 373 130 230 173 195 -104 -150 -189 -16 -55 87 -122 63 0 146 375 374 238 110 200 -321 -249 -292 48 -443 -110 -243 -162 -146 130 139 67 201 75 124 197 353 140 163 34 144 -296 -97 -546 -411 -452 23 -368 -200 -261 -147 310 266 420 418 217 288 177 97 98 35 90 -350 99 -103 -98 -183 -86 -223 -38 -88 -80 -3003 -91 -223 -296 -109 -373 -171 -65 -27 47 340 67 675 -85 77 167 170 117 -145 -350 -366 -355 -293 -287 -384 -602 -620 -90 74 22 321 10 -36 401 -61 576 544 841 279 405 47 378 254 425 319 88 11 270 122 133 286 -63 20 -65 -38 -258 76 -26 -112 -83 70 176 124 70 129 8 50 -354 -99 -87 -182 30 -238 900000 900000 SQ 20230729T152511.4Z 8610.642492 222 1 49.10 2 35.39 125.61 158.87 45.56 0.00 1 0.00 1 0 22 2.924e-03 2.888e-03 8.829e-04 8.791e-04 7.336524e+03 5.868603e+01 5.745917e+02 -6.000000e+00 1.623247e+02 287.11 -2.00 20.00 -2.00 505.27 0.00e+00 5.692976e-04 2.423661e-05 2.272607e-05 -6.000000e+00 8.235099e-05 287.11 -2.00 20.00 -2.00 500.43 0.00e+00 1.524255e-01 1.713007e-02 1.459450e-02 -6.000000e+00 5.746870e-02 232.54 -2.00 3.57 -2.00 502.01 0.00e+00 1.226 0.000 489.00 513.00 1 6.3262e+00 1.3141e-03 2.4123e-03 -6.0000e+00 4.4044e-03 9.9094e-04 3.3501e-04 7.0817e-04 -6.0000e+00 1.1531e-03 2.8640e-03 2.5397e-02 7.6921e-05 6.0815e-05 -6.0000e+00 2.6478e-04 1.7875e-01 1.6785e-04 10 0 0 10 0 0 99.72 23.22 1.35 0.17875 0.35491 14 3 1 4 0 3506.940 23.22 15.00 18.91 -133 41 443 277 288 314 246 208 -49 -136 -87 -256 -216 -188 -216 0 -190 201 86 322 355 418 246 210 -457 -125 -318 46 -280 11 -62 -361 -79 61 88 -162 204 -17 327 192 485 200 276 127 63 -93 -253 -332 -570 -488 -303 -378 -359 -194 -197 127 22 299 348 232 168 183 87 44 -32 -212 -495 -107 -30 -222 24 -435 -280 -306 -112 -358 900 -385 -253 -385 -182 -557 -339 -348 68 7 436 203 493 123 -34 326 177 112 -430 -342 -743 -245 -245 -417 -477 -409 -567 -179 -87 4 146 34 -24 207 328 552 796 510 318 131 83 100 229 373 708 24 283 113 80 -45 244 -148 -34 133 -221 -15 -7 -114 -339 237 -215 202 45 364 51 149 -19 -108 -216 -41 -109 -101 -184 900000 900000 -136 43 467 297 310 335 257 216 -50 -137 -86 -255 -217 -192 -229 0 -205 216 93 347 384 454 266 225 -488 -128 -316 46 -280 11 -67 -375 -86 65 93 -170 212 -18 344 204 521 205 283 136 67 -96 -256 -325 -548 -465 -294 -380 -372 -204 -207 133 23 313 367 245 177 190 89 44 -32 -209 -484 -103 -29 -218 24 -440 -278 -298 -107 -341 843 -367 -243 -373 -177 -554 -339 -347 67 7 431 202 498 126 -35 323 171 106 -397 -310 -662 -217 -222 -395 -475 -396 -550 -171 -87 4 145 32 -23 201 321 540 779 506 319 131 81 96 216 368 665 23 268 107 75 -42 230 -139 -33 127 -210 -15 -7 -107 -323 227 -211 198 45 360 51 148 -19 -105 -205 -38 -100 -94 -176 900000 900000 SQ 20230729T153011.0Z 8610.645960 225 1 48.54 2 34.66 127.24 158.25 47.88 0.00 1 0.00 1 0 22 2.788e-03 2.775e-03 9.088e-04 9.061e-04 8.253969e+03 6.072593e+01 6.351031e+02 -6.000000e+00 1.547989e+02 287.11 -2.00 20.00 -2.00 505.29 0.00e+00 5.545898e-04 2.512518e-05 2.378631e-05 -6.000000e+00 7.853232e-05 287.11 -2.00 20.00 -2.00 500.50 0.00e+00 1.387614e-01 1.763589e-02 2.014822e-02 -6.000000e+00 5.480253e-02 232.54 -2.00 3.57 -2.00 502.08 0.00e+00 1.215 0.000 489.00 513.00 1 6.3763e+00 1.3555e-03 2.7533e-03 -6.0000e+00 4.2001e-03 1.7431e-03 3.4274e-04 8.5282e-04 -6.0000e+00 1.0996e-03 2.7269e-03 2.5217e-02 7.8118e-05 6.9367e-05 -6.0000e+00 2.5248e-04 1.7740e-01 1.7866e-04 10 0 0 10 0 0 99.92 23.22 1.35 0.17740 0.35231 13 3 1 4 0 3732.910 23.22 15.00 18.91 -129 37 305 198 410 180 223 169 8 -312 -268 -218 -68 -282 205 -78 -43 282 262 409 401 322 152 229 -287 -97 -434 27 -299 51 -230 -183 -78 -12 156 -29 152 -33 289 149 342 327 120 57 181 -227 -153 -693 -433 -604 -354 -290 -343 -194 -108 235 185 256 302 277 442 250 169 100 -188 -94 -330 -113 -168 -72 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