File name: Pandora104s1_Downsview_20230811_L2Fit_fout2c23d20230421p1-8.txt File generation date: 20241127T190447.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c23p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt Level 1 file used: Pandora104s1_Downsview_20230811_L1_smca1c23d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421" First and last pixel inside fitting window: 206 348 Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230811T105203.0Z 8623.452813 197 1 50.06 2 84.96 73.65 36.37 103.57 0.00 1 0.00 1 0 17 4.914e-01 4.088e-02 4.444e-01 4.273e-02 1.006546e+00 2.605149e-02 1.146608e-02 -6.000000e+00 2.965449e-01 232.05 -2.00 3.57 -2.00 322.18 0.00e+00 -7.039868e-03 1.057509e-02 9.535274e-03 -6.000000e+00 1.356901e-02 287.36 -2.00 20.00 -2.00 321.61 0.00e+00 9.739 0.018 302.00 328.00 3 1.1232e-01 9.3306e-02 1.2810e-01 -6.0000e+00 7.4687e-01 2.1465e+00 1.0994e-01 1.0153e-01 -6.0000e+00 8.0717e-01 -2.2145e+00 6.3319e-02 3.0476e-02 -6.0000e+00 4.7775e-01 7.4232e-01 3.4391e-02 1.4728e-02 -6.0000e+00 2.0237e-01 1.0271e-05 8.3263e-04 1.1599e-03 1.0071e-04 -6.0000e+00 1.3748e-02 -6.7869e-03 0.0000e+00 12 8 8 10 0 0 14.27 22.90 1.09 -0.00679 -0.00053 32 7 1 5 0 1564.200 22.90 15.00 18.66 -10983 900000 57100 11995 -6214 -63032 41362 46172 -34169 900000 166880 59882 292605 35795 48197 64077 16811 47047 97930 -21415 31699 -33078 -55647 48042 -4781 -42957 -22655 176581 900000 17880 -22830 70864 53026 900000 13608 184138 -26527 58559 18671 47820 -7958 138655 -24206 -10133 32602 -30708 75636 30229 23166 92887 51782 37544 63480 64553 73851 20857 25009 38295 -29533 -25399 -9331 715 -19957 -33939 21534 -14099 -453 49184 30002 28477 59638 21666 40316 33824 32265 7993 -26365 -16211 23735 -7314 11019 -17184 6225 -9316 -13093 1415 -4829 -2765 4038 9535 7333 22925 -25320 2145 7531 1608 966 6597 8878 -7051 -3712 1322 -7137 -16531 187 -2101 1423 -7375 -2229 2233 3852 3595 897 2251 378 -761 2176 291 206 3682 1576 -720 4 -259 -2505 3206 -481 1101 -787 -138 951 -682 -427 -622 -329 -1427 -383 -229 170 1747 -1853 2011 349 -1220 900000 2972 833 -410 -6343 1722 1923 -2727 900000 6949 2494 12185 2033 2737 3396 1464 3028 4078 -2513 2040 -3632 -7373 2364 -416 -5367 -2144 7353 900000 880 -1901 2951 2610 900000 927 7668 -2511 2660 1484 3259 -1024 5774 -3666 -1266 2468 -4185 3780 2392 2026 4255 3881 3596 5023 5376 5843 2866 3333 4306 -5478 -4548 -1360 98 -3740 -8197 3228 -2994 -83 5735 4623 5099 8444 4601 6883 5634 4837 1331 -5709 -3240 3558 -1797 2661 -6369 2048 -3802 -5834 572 -2152 -1232 1648 3534 2596 6587 -11599 786 3010 810 575 4286 6359 -6137 -2983 903 -4696 -11496 117 -1426 978 -5989 -1913 2139 4186 4372 1177 2953 494 -982 2727 389 289 5213 2231 -990 6 -329 -3172 3778 -570 1334 -1131 -235 1829 -1480 -996 -1587 -906 -4260 -1157 -699 518 5093 -5207 5016 829 SS 20230811T110357.6Z 8623.461083 200 1 49.96 2 82.89 75.65 34.33 106.31 0.00 1 0.00 1 0 17 6.108e-01 1.883e-02 3.549e-01 7.803e-03 9.048711e-01 4.791553e-03 1.069286e-02 -6.000000e+00 3.712384e-01 232.05 -2.00 3.57 -2.00 322.34 0.00e+00 9.246655e-03 3.116361e-03 6.154037e-03 -6.000000e+00 1.696616e-02 287.36 -2.00 20.00 -2.00 321.89 0.00e+00 7.419 0.008 302.00 328.00 3 3.7912e-01 2.0969e-02 9.2571e-02 -6.0000e+00 9.2990e-01 8.4449e-01 2.9643e-02 5.8788e-02 -6.0000e+00 1.0030e+00 -1.1615e+00 2.6852e-02 3.2961e-02 -6.0000e+00 5.9382e-01 4.7223e-01 1.1974e-02 1.2236e-02 -6.0000e+00 2.5004e-01 1.0087e-04 -1.2803e-03 2.2537e-04 2.6691e-04 -6.0000e+00 1.7307e-02 -7.3956e-03 0.0000e+00 12 8 8 10 0 0 34.92 22.90 0.47 -0.00740 -0.01702 134 27 1 5 0 372.690 22.90 14.99 18.66 -166080 45655 -166887 114523 -181001 900000 -200718 900000 -198120 95370 -138526 -55491 -122645 88160 181988 -46962 -38836 -3113 33655 21159 228813 -58022 900000 -17806 133454 -98745 900000 -91567 80477 -63204 65566 -64184 143398 5826 34771 7403 65125 14222 43880 142865 38670 107213 21694 128469 14873 46125 5017 67858 14454 48115 9661 72424 18471 49201 24256 34819 11880 33711 21848 7417 22154 17372 29037 14104 32131 21970 27590 9394 29509 5005 20213 -1090 14770 1956 10984 -4152 6368 -3731 1397 1649 -3527 3058 -895 5543 -2017 7054 1828 4461 1615 5761 -2068 -827 -4948 -2584 -5679 -1068 -3761 -1610 -2467 -1329 -1305 -1444 -1927 -2604 -314 -4155 -2207 -4340 22 -1693 1287 -663 468 -1562 -595 -1548 384 610 790 718 152 2055 1973 3321 25 2248 -75 1632 -433 97 -534 545 -651 666 -343 386 -199 828 391 -135 -486 -926 -956 -3329 347 -4038 871 -4129 900000 -4856 900000 -5067 725 -2011 -422 -2120 670 1384 -779 -671 -41 326 234 1740 -1324 900000 -271 1015 -3481 900000 -2848 612 -1573 598 -2440 1090 155 661 175 891 368 1001 1412 1206 1794 891 1856 607 1543 236 1961 689 1939 574 2864 1251 2918 1777 2359 1035 2330 1631 615 1593 1417 2409 1560 3310 2552 3013 1286 3590 903 3465 -242 2777 392 1830 -718 920 -609 242 346 -936 886 -306 1904 -792 2687 771 1903 708 2365 -869 -325 -1977 -1041 -2685 -574 -2457 -1197 -2107 -1181 -1121 -1123 -1338 -1739 -217 -3191 -1744 -3789 20 -1834 1551 -906 661 -2272 -834 -2127 515 853 1159 1109 235 2973 2694 4383 33 2854 -94 2043 -630 166 -1041 1158 -1494 1630 -911 1090 -579 2408 1146 -390 -1312 -2325 -2242 SS 20230811T111517.1Z 8623.468948 203 1 49.77 2 80.90 77.54 32.42 109.12 0.00 1 0.00 1 0 17 6.628e-01 1.038e-02 1.903e-01 2.749e-03 7.728438e-01 1.604065e-03 9.614969e-03 -6.000000e+00 3.968706e-01 232.05 -2.00 3.57 -2.00 321.81 0.00e+00 6.472202e-03 9.486425e-04 8.127074e-03 -6.000000e+00 1.754973e-02 287.36 -2.00 20.00 -2.00 321.28 0.00e+00 5.993 0.004 302.00 328.00 3 3.4093e-01 6.3376e-03 8.2537e-02 -6.0000e+00 9.9514e-01 1.9745e-01 9.4402e-03 6.6678e-02 -6.0000e+00 1.0727e+00 -2.7504e-01 9.6258e-03 3.4036e-02 -6.0000e+00 6.3867e-01 1.0737e-01 4.3422e-03 9.1999e-03 -6.0000e+00 2.7058e-01 4.8879e-04 -3.4878e-04 7.9674e-05 1.9492e-04 -6.0000e+00 1.8349e-02 -7.3549e-03 0.0000e+00 12 8 8 10 0 0 2.79 22.90 0.34 -0.00735 -0.00998 328 67 1 5 0 151.720 22.90 15.00 18.65 -155864 -137196 -184860 -170919 -213317 -251602 -239448 -265255 -207879 -251556 -151076 -201164 100972 -160478 -32444 -114829 10245 -23393 22665 -30724 -14577 -36721 -18657 -37522 -8015 -58123 -53976 -71277 -70688 -45784 -51755 -6641 -42686 12251 -31649 15253 -26065 22192 -3738 26668 21181 20401 1452 12063 6328 2238 9140 -196 4450 5433 10938 3293 13192 5325 14701 3351 12255 3220 8421 4256 9643 5430 12196 10147 7723 5598 2895 3389 3060 5106 1667 3897 373 2072 -1401 1706 -3352 -1185 -3060 28 -1394 938 -1191 -441 -519 73 81 491 191 303 297 -1237 -1436 -2468 -397 -783 164 -376 386 -1059 -564 -1761 -974 -232 -855 -1912 -1596 -703 -561 475 -45 720 -120 137 -697 573 300 1113 50 905 87 917 877 1250 202 552 -569 169 607 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