File name: Pandora104s1_Downsview_20231010_L2Fit_fwvt1c23d20230421p1-8.txt File generation date: 20241127T195103.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c23p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt Level 1 file used: Pandora104s1_Downsview_20231010_L1_smca1c23d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231010 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421" First and last pixel inside fitting window: 1630 1780 Nominal wavelengths inside fitting window [nm]: 492.0182 492.1387 492.2593 492.3798 492.5004 492.6209 492.7414 492.8618 492.9823 493.1027 493.2231 493.3435 493.4639 493.5843 493.7046 493.8250 493.9453 494.0656 494.1859 494.3061 494.4264 494.5466 494.6668 494.7870 494.9072 495.0274 495.1475 495.2676 495.3877 495.5078 495.6279 495.7480 495.8680 495.9880 496.1080 496.2280 496.3480 496.4680 496.5879 496.7078 496.8277 496.9476 497.0675 497.1873 497.3071 497.4270 497.5468 497.6665 497.7863 497.9060 498.0258 498.1455 498.2652 498.3849 498.5045 498.6242 498.7438 498.8634 498.9830 499.1026 499.2221 499.3416 499.4612 499.5807 499.7002 499.8196 499.9391 500.0585 500.1779 500.2973 500.4167 500.5361 500.6554 500.7747 500.8941 501.0133 501.1326 501.2519 501.3711 501.4903 501.6096 501.7287 501.8479 501.9671 502.0862 502.2053 502.3244 502.4435 502.5626 502.6816 502.8007 502.9197 503.0387 503.1576 503.2766 503.3955 503.5145 503.6334 503.7523 503.8711 503.9900 504.1088 504.2277 504.3465 504.4652 504.5840 504.7028 504.8215 504.9402 505.0589 505.1776 505.2963 505.4149 505.5335 505.6521 505.7707 505.8893 506.0079 506.1264 506.2449 506.3634 506.4819 506.6004 506.7188 506.8373 506.9557 507.0741 507.1924 507.3108 507.4292 507.5475 507.6658 507.7841 507.9023 508.0206 508.1388 508.2571 508.3753 508.4935 508.6116 508.7298 508.8479 508.9660 509.0841 509.2022 509.3202 509.4383 509.5563 509.6743 509.7923 509.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231010T135437.4Z 8683.579600 245 1 46.84 2 66.22 126.76 29.62 167.12 0.00 1 0.00 1 0 15 2.508e-03 2.501e-03 8.069e-04 8.055e-04 1.537670e+03 4.581534e+01 9.743618e+01 -6.000000e+00 1.357499e+02 281.73 -2.00 20.00 -2.00 505.26 0.00e+00 7.167212e-04 2.187356e-05 4.121801e-05 -6.000000e+00 6.957054e-05 281.73 -2.00 20.00 -2.00 500.44 0.00e+00 2.004134e-01 1.565916e-02 1.572795e-02 -6.000000e+00 4.910094e-02 226.04 -2.00 3.57 -2.00 502.04 0.00e+00 2.462 0.000 489.00 513.00 1 7.3924e+00 1.1978e-03 3.8051e-03 -6.0000e+00 3.7579e-03 3.9186e-03 3.1266e-04 3.6832e-04 -6.0000e+00 9.8312e-04 8.3402e-04 2.7275e-04 6.9445e-05 1.6132e-05 -6.0000e+00 2.2123e-04 -4.0223e-03 7.1485e-06 12 1 1 12 1 1 97.30 22.80 1.30 -0.00402 -0.00213 14 3 1 4 0 3122.050 22.80 15.00 18.52 -472 -261 -396 -272 -143 40 474 421 288 387 270 310 -101 -32 -161 -108 -7 -152 24 73 -118 321 99 290 298 366 101 171 -110 -333 -345 33 -395 -52 -54 -250 76 -29 160 -122 186 -124 163 222 346 236 372 141 72 19 -29 -253 -349 -389 -284 -121 -300 -287 -231 182 197 297 232 81 94 103 238 50 -6 -195 -334 -88 111 -295 47 -257 -252 -195 -284 -353 292 -303 -376 -303 -267 -500 -256 -217 -67 22 214 101 197 -34 90 197 -57 -47 -390 -115 -531 -146 -393 -202 -74 -442 -408 -249 -11 12 295 69 121 305 400 370 591 346 331 131 149 320 235 340 485 167 100 293 223 253 328 -83 -106 100 40 -21 -99 -132 -376 -185 -82 134 68 130 83 -107 -59 -259 -382 -276 -30 -451 -250 -387 -272 -145 42 492 441 302 404 279 317 -102 -33 -161 -108 -7 -155 25 76 -124 336 103 304 313 385 106 179 -114 -338 -343 33 -394 -53 -57 -264 80 -30 165 -125 190 -128 167 230 360 247 388 146 74 20 -29 -248 -338 -374 -277 -120 -304 -294 -237 186 201 303 237 83 96 105 239 50 -6 -191 -325 -85 108 -289 46 -255 -248 -189 -273 -338 279 -291 -364 -294 -261 -493 -253 -215 -66 22 211 100 197 -34 91 197 -57 -46 -376 -109 -498 -137 -372 -195 -74 -444 -407 -246 -11 12 288 69 121 308 405 375 599 353 337 133 149 316 231 332 477 165 98 288 219 248 322 -81 -102 95 38 -20 -94 -129 -369 -183 -82 134 68 130 84 -108 -59 -256 -371 -264 -28 SQ 20231010T140358.7Z 8683.586096 247 1 14.38 2 64.89 128.85 29.35 171.60 0.00 1 0.00 1 0 15 2.040e-03 2.048e-03 1.548e-04 1.545e-04 1.492918e+03 8.740794e+00 9.997978e+01 -6.000000e+00 1.104691e+02 281.73 -2.00 20.00 -2.00 505.26 0.00e+00 6.450422e-04 4.199148e-06 3.864039e-05 -6.000000e+00 5.661306e-05 281.73 -2.00 20.00 -2.00 500.46 0.00e+00 1.553772e-01 3.006169e-03 1.421807e-02 -6.000000e+00 3.996082e-02 226.03 -2.00 3.57 -2.00 502.05 0.00e+00 2.341 0.000 489.00 513.00 1 3.1131e+00 2.3007e-04 3.5972e-03 -6.0000e+00 3.0583e-03 6.3738e-03 6.0090e-05 3.4494e-04 -6.0000e+00 8.0019e-04 6.1504e-02 1.5989e-04 1.3257e-05 1.5874e-05 -6.0000e+00 1.7997e-04 -3.7080e-03 -8.4657e-07 10 0 0 10 0 0 99.76 22.80 1.31 -0.00371 -0.00260 565 116 1 4 0 25.260 22.80 15.00 18.48 -15 -79 -303 -87 -22 75 369 331 301 327 213 347 -8 -147 -34 -118 24 -92 -56 -113 -83 199 203 251 329 223 129 117 -149 -205 -207 164 -160 -99 -156 -306 -194 10 98 -17 94 88 135 110 186 176 166 138 87 -37 -286 -308 -251 -287 -207 -240 -429 -202 -206 66 152 292 205 101 153 39 131 12 -42 -126 -242 -66 15 -134 -161 -222 -307 -79 -96 -52 -296 -174 -223 -261 -184 -213 -264 -188 -158 -71 126 55 192 44 -7 -32 79 35 -304 -184 -376 -135 -159 -296 -275 -529 -357 -111 -8 141 182 36 4 101 190 361 462 422 210 176 179 347 342 414 373 134 152 273 164 229 210 -64 -69 104 31 0 68 -109 -227 -112 -51 11 108 187 90 -36 -167 -260 -202 -92 3 -14 -77 -290 -86 -22 79 392 341 311 335 224 360 -8 -148 -34 -118 24 -95 -57 -118 -87 206 211 260 343 234 134 121 -153 -212 -206 163 -161 -102 -162 -322 -203 10 100 -17 95 88 137 113 193 184 173 143 88 -37 -291 -303 -242 -275 -202 -243 -429 -206 -209 66 153 295 209 103 155 39 130 13 -42 -126 -238 -64 15 -134 -157 -217 -309 -77 -93 -51 -286 -169 -218 -257 -183 -205 -257 -183 -153 -69 123 54 192 45 -7 -32 77 34 -299 -177 -356 -127 -153 -282 -274 -537 -360 -110 -7 136 177 36 4 104 195 372 477 421 210 182 182 346 336 405 369 134 151 271 162 225 208 -63 -67 98 29 0 65 -106 -225 -112 -52 11 105 184 89 -36 -165 -262 -198 -88 3 SQ 20231010T140413.3Z 8683.586266 247 2 14.28 2 64.86 128.90 29.34 171.72 0.00 1 0.00 1 0 15 2.052e-03 2.050e-03 2.175e-04 2.169e-04 1.507447e+03 1.230391e+01 9.998740e+01 -6.000000e+00 1.110860e+02 281.73 -2.00 20.00 -2.00 505.24 0.00e+00 6.154077e-04 5.868400e-06 3.722037e-05 -6.000000e+00 5.692995e-05 281.73 -2.00 20.00 -2.00 500.41 0.00e+00 1.494759e-01 4.213618e-03 1.418586e-02 -6.000000e+00 4.018180e-02 226.03 -2.00 3.57 -2.00 502.00 0.00e+00 2.338 0.000 489.00 513.00 1 3.6551e+00 3.2190e-04 3.5846e-03 -6.0000e+00 3.0753e-03 5.4983e-03 8.4514e-05 3.4417e-04 -6.0000e+00 8.0457e-04 3.5814e-02 1.3172e-04 1.8657e-05 1.6047e-05 -6.0000e+00 1.8101e-04 -4.0194e-03 4.4311e-06 10 0 0 10 0 0 99.10 22.80 1.30 -0.00402 -0.00311 565 116 1 4 0 25.260 22.80 15.00 18.48 -8 -49 -245 -95 -11 98 383 362 256 301 209 340 34 -145 -57 -127 -18 -82 3 -94 -95 157 178 244 329 241 112 100 -156 -222 -173 171 -135 -115 -185 -272 -221 -19 88 2 108 79 118 91 171 177 166 107 55 -45 -306 -288 -261 -290 -230 -290 -443 -212 -173 76 152 297 214 65 159 50 154 18 2 -153 -262 -18 -6 -172 -162 -263 -300 -109 -107 -35 -300 -186 -244 -248 -188 -193 -267 -188 -174 -42 128 38 194 -21 -28 -31 81 19 -325 -182 -380 -149 -109 -292 -273 -557 -321 -117 18 142 179 6 12 105 208 354 409 435 229 162 152 372 335 455 364 137 155 294 208 215 240 -42 -73 63 52 -1 49 -72 -235 -99 -56 -19 176 146 92 -35 -159 -296 -215 -69 -2 -7 -47 -242 -97 -11 99 397 380 271 315 215 344 34 -144 -56 -124 -18 -82 4 -100 -100 166 188 258 351 258 119 106 -163 -224 -168 165 -132 -116 -196 -293 -236 -20 92 2 110 81 122 95 181 189 177 113 57 -46 -304 -277 -247 -272 -219 -287 -453 -220 -179 79 156 306 223 68 165 52 156 18 2 -149 -252 -17 -6 -168 -161 -263 -296 -105 -102 -33 -283 -176 -235 -239 -183 -190 -265 -187 -173 -41 128 38 198 -22 -28 -32 81 18 -313 -172 -352 -137 -103 -285 -279 -550 -314 -118 18 140 178 6 12 105 208 355 411 440 232 163 150 360 337 455 350 133 150 284 200 206 231 -40 -72 61 49 -1 48 -69 -227 -97 -55 -19 174 146 93 -35 -159 -290 -205 -65 -2 SQ 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