File name: Pandora104s1_Downsview_20231127_L2Fit_fout2c18d20230421p1-8.txt File generation date: 20231128T061920.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v18d20230421.txt Level 1 file used: Pandora104s1_Downsview_20231127_L1_smca1c18d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20230421 First and last pixel inside fitting window: 206 348 Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231127T134931.6Z 8731.576060 303 1 6.22 2 78.91 134.18 97.86 314.93 0.00 1 0.00 1 0 25 3.333e-01 1.023e-02 3.015e-01 7.346e-03 6.623179e-01 3.976330e-03 7.940969e-03 -6.000000e+00 1.943866e-01 222.41 -2.00 3.57 -2.00 321.03 0.00e+00 5.729013e-03 1.796170e-03 3.316068e-03 -6.000000e+00 8.610262e-03 275.78 -2.00 20.00 -2.00 320.55 0.00e+00 5.016 0.002 302.00 328.00 3 2.1629e+00 1.2769e-02 6.0974e-02 -6.0000e+00 4.7868e-01 7.2659e-02 1.7492e-02 3.8175e-02 -6.0000e+00 5.2150e-01 -6.5702e-02 1.8689e-02 2.4368e-02 -6.0000e+00 3.0869e-01 1.5480e-02 9.0673e-03 1.0399e-02 -6.0000e+00 1.3165e-01 2.2488e-04 -4.3204e-04 2.1015e-04 1.4116e-04 -6.0000e+00 9.2965e-03 5.2177e-03 0.0000e+00 12 9 9 12 1 1 99.97 22.71 0.47 0.00522 0.00197 15 26 1 5 0 388.390 22.71 15.00 18.43 24162 900000 -40448 120848 43740 900000 -153814 900000 -135005 -43733 -161007 -49884 -103622 85270 -76513 -47692 -79824 38809 -63987 -6956 -27572 26037 -47958 591 -15013 30857 48120 -51147 -14662 -44066 2492 -38381 23980 -25262 46036 -12119 13374 -18012 2229 6149 7209 6814 6584 576 4422 11675 -2056 4954 15799 11456 -246 5837 -2249 8502 -3990 3641 -3597 1485 -5292 256 -2792 4132 4619 2223 4634 -1785 7293 2251 5079 2316 1859 -834 3497 -1283 1585 -3877 1189 -3005 -416 -3328 -242 -884 -1739 -3214 -819 39 -245 975 -64 1942 396 -183 -1436 -820 -321 363 -1021 1418 149 -178 -1108 -862 -793 1603 -582 -1912 -1920 -872 -98 816 830 763 -41 -499 -190 676 535 658 643 -61 -94 495 1051 560 -661 691 -583 -189 602 -38 -484 -444 -1077 170 -654 286 -498 583 483 430 -247 258 -556 173 900000 -290 865 313 900000 -1502 900000 -1406 -313 -2515 -357 -1349 611 -1295 -745 -1974 328 -1666 -109 -556 305 -1217 10 -322 442 595 -1698 -344 -1492 63 -1799 702 -1348 1169 -544 505 -1102 136 432 520 537 554 54 404 1031 -215 505 1527 1237 -33 836 -384 1421 -802 706 -777 306 -1140 52 -595 900 1138 635 1405 -573 2097 700 1667 906 805 -360 1561 -571 635 -1478 401 -1061 -157 -1537 -127 -493 -1089 -2167 -573 29 -191 781 -52 1499 293 -128 -969 -557 -240 312 -1025 1465 174 -213 -1277 -894 -800 1551 -615 -2177 -2123 -1021 -123 1142 1288 1189 -66 -781 -301 1017 796 1017 1043 -98 -151 819 1646 862 -990 996 -814 -265 935 -63 -893 -879 -2239 350 -1440 664 -1189 1398 1166 1017 -555 542 -1196 SS 20231127T140754.2Z 8731.588821 318 1 17.75 2 76.61 137.88 100.01 318.33 0.00 1 0.00 1 0 17 1.648e-01 6.557e-03 1.276e-01 3.025e-03 5.604074e-01 1.586274e-03 6.688271e-03 -6.000000e+00 9.496823e-02 222.41 -2.00 3.57 -2.00 320.49 0.00e+00 4.802112e-03 6.035620e-04 1.826611e-03 -6.000000e+00 4.158983e-03 275.78 -2.00 20.00 -2.00 319.97 0.00e+00 4.213 0.001 302.00 328.00 3 2.3179e+00 4.7830e-03 5.0418e-02 -6.0000e+00 2.3372e-01 5.5659e-02 6.0832e-03 2.9886e-02 -6.0000e+00 2.5437e-01 -3.4752e-02 5.9513e-03 1.8402e-02 -6.0000e+00 1.5154e-01 1.5101e-03 3.0032e-03 8.3040e-03 -6.0000e+00 6.4656e-02 4.4998e-04 -1.0643e-04 8.7627e-05 9.3828e-05 -6.0000e+00 4.5246e-03 4.7226e-03 0.0000e+00 12 9 1 12 1 1 99.97 22.80 0.35 0.00472 0.00392 45 26 1 5 0 385.670 22.80 15.00 18.47 -51041 45164 -56459 6523 -60260 490 -57435 -68109 -20329 -78601 -55519 -45126 -39458 -29429 -2163 -24984 -21475 7366 15736 12080 -59 1735 14314 16469 -166 -6235 -17223 -11309 -13911 -13321 -4571 -7243 -2260 -5802 -12350 -6495 -3606 -6917 -3256 46 -90 -819 2592 3894 -159 1709 3557 1512 -888 910 1185 2322 386 1989 2205 637 -440 -1430 -531 1015 671 3182 2736 3426 2263 565 1314 1016 1714 1652 276 212 -1050 -1103 -520 -1129 -2230 -1539 -1547 -1336 -1499 -828 -1396 -1503 -716 -219 1026 426 1216 947 251 148 -1231 -1299 -227 -284 198 476 247 -444 -446 -680 -387 294 -426 -1102 -1319 -368 231 885 484 894 -151 244 -144 588 728 553 71 144 -380 182 310 670 -460 55 -499 340 441 -434 -618 -869 -587 229 -402 154 -353 443 458 183 -104 147 -196 -407 160 -600 37 -604 3 -576 -864 -180 -1223 -786 -639 -664 -521 -40 -637 -593 168 359 301 -2 50 372 451 -6 -242 -762 -464 -586 -586 -213 -414 -141 -411 -898 -439 -256 -599 -331 5 -12 -117 377 580 -25 272 567 253 -158 167 237 514 95 519 606 184 -133 -436 -157 292 199 1004 974 1238 884 220 490 384 693 771 143 116 -579 -581 -253 -499 -1005 -682 -739 -684 -889 -554 -1036 -1179 -593 -193 941 408 1151 876 220 122 -965 -1016 -192 -274 200 540 310 -573 -547 -756 -424 317 -459 -1269 -1589 -467 312 1320 736 1440 -247 385 -230 890 1085 857 117 231 -617 308 502 1058 -704 81 -708 479 683 -708 -1104 -1652 -1153 472 -827 335 -789 998 1040 409 -222 316 -405 SS 20231127T141313.3Z 8731.592515 321 1 49.80 2 75.97 138.98 100.61 319.34 0.00 1 0.00 1 0 25 1.567e-01 5.900e-03 4.507e-02 1.322e-03 5.405838e-01 7.016903e-04 6.495540e-03 -6.000000e+00 9.029604e-02 222.41 -2.00 3.57 -2.00 320.67 0.00e+00 5.450294e-03 2.764636e-04 2.011692e-03 -6.000000e+00 3.954077e-03 275.78 -2.00 20.00 -2.00 320.16 0.00e+00 4.034 0.001 302.00 328.00 3 1.4097e+00 2.1391e-03 4.8511e-02 -6.0000e+00 2.2222e-01 4.3891e-02 2.7421e-03 2.9056e-02 -6.0000e+00 2.4185e-01 -2.2782e-02 2.7034e-03 1.8640e-02 -6.0000e+00 1.4408e-01 -4.8689e-03 1.3540e-03 8.8558e-03 -6.0000e+00 6.1478e-02 1.3481e-03 -9.0910e-05 3.9165e-05 1.0303e-04 -6.0000e+00 4.3029e-03 4.3810e-03 0.0000e+00 10 0 0 10 0 0 99.97 22.80 0.23 0.00438 0.00370 462 95 1 5 0 107.770 22.80 15.00 18.48 -51274 -9649 -53579 -21143 -72107 -18673 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