File name: Pandora104s1_Downsview_20231204_L2Fit_fout2c23d20230421p1-8.txt
File generation date: 20241127T202013.1Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c23p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt
Level 1 file used: Pandora104s1_Downsview_20231204_L1_smca1c23d20230421p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20231204
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421"
First and last pixel inside fitting window: 206 348
Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20231204T172251.6Z 8738.724208 421 1 23.35 2 66.14 183.74 85.55 282.23 0.00 1 0.00 1 0 17 5.639e-02 8.744e-03 4.219e-02 5.038e-03 3.753661e-01 2.570608e-03 4.491556e-03 -6.000000e+00 3.249003e-02 222.32 -2.00 3.57 -2.00 318.89 0.00e+00 2.005686e-03 5.814478e-04 3.112706e-04 -6.000000e+00 1.417755e-03 274.97 -2.00 20.00 -2.00 318.33 0.00e+00 2.454 0.000 302.00 328.00 3 5.2871e+00 6.9619e-03 3.0615e-02 -6.0000e+00 7.9968e-02 7.2086e-02 8.0086e-03 1.9127e-02 -6.0000e+00 8.7032e-02 -5.0367e-03 5.8292e-03 9.8890e-03 -6.0000e+00 5.1831e-02 -8.5058e-03 3.0795e-03 3.5763e-03 -6.0000e+00 2.2116e-02 1.4580e-04 2.2893e-04 1.4879e-04 3.6133e-05 -6.0000e+00 1.5509e-03 1.4787e-03 0.0000e+00 12 9 1 12 1 1 99.97 22.80 0.27 0.00148 0.00320 6 3 1 5 0 3334.190 22.80 15.00 18.53 10736 -15008 -26456 -17712 -11832 -11259 -3175 -20447 -21030 16428 -19223 7960 -1433 14711 -12833 9239 -6526 3930 -3127 12314 -1321 1952 -86 -3365 -2941 1299 -8159 -8804 925 2565 6884 6518 407 -3092 -2086 -549 -3001 585 1055 -2273 -536 -2578 -980 999 1703 420 -342 2050 -2207 -1450 -54 5251 965 1934 208 1034 772 1284 -173 1305 -579 2608 781 2677 828 -746 828 163 12 1662 381 -1527 732 279 1147 -1889 1193 -1466 -1791 -1947 -1893 -2874 -1624 -2544 -950 -715 741 1438 1167 1217 -376 962 -677 -600 226 650 -676 1487 348 -244 -427 -1025 -422 -335 -263 -883 -1422 -188 -304 868 109 672 -160 311 -264 155 252 681 46 494 -149 361 438 408 -203 374 -477 824 298 -48 -551 -772 -418 307 -281 320 -228 683 252 395 -571 170 -903 311 -616 -1274 -759 -437 -397 -109 -931 -1074 626 -1039 348 -80 836 -1120 740 -652 377 -340 1203 -153 217 -10 -424 -394 174 -1204 -1262 117 320 890 949 69 -581 -369 -93 -561 123 263 -681 -174 -901 -352 359 609 154 -127 739 -831 -552 -21 2159 438 921 104 527 405 672 -90 666 -306 1433 474 1717 558 -489 506 99 7 1173 294 -1246 587 218 843 -1308 741 -899 -1142 -1390 -1508 -2537 -1526 -2501 -971 -771 828 1644 1338 1368 -406 965 -645 -556 219 685 -787 1848 467 -332 -558 -1255 -483 -385 -320 -1139 -1898 -260 -436 1316 175 1107 -263 490 -394 221 353 977 69 777 -239 574 676 618 -298 531 -654 1106 424 -73 -893 -1293 -709 537 -513 608 -443 1336 499 774 -1093 314 -1631
SS 20231204T173656.0Z 8738.733982 427 1 49.88 2 66.38 187.29 87.99 284.52 0.00 1 0.00 1 0 25 2.578e-02 6.203e-03 3.068e-03 3.357e-04 3.830649e-01 1.717704e-04 4.652812e-03 -6.000000e+00 1.484926e-02 222.32 -2.00 3.57 -2.00 318.95 0.00e+00 2.093915e-03 3.964168e-05 5.104401e-04 -6.000000e+00 6.482654e-04 274.97 -2.00 20.00 -2.00 318.39 0.00e+00 2.478 0.000 302.00 328.00 3 9.4162e-01 4.6644e-04 3.1141e-02 -6.0000e+00 3.6547e-02 3.2421e-02 5.3709e-04 1.9665e-02 -6.0000e+00 3.9782e-02 -1.1070e-02 3.9823e-04 1.0277e-02 -6.0000e+00 2.3691e-02 -6.1043e-03 2.1137e-04 3.6302e-03 -6.0000e+00 1.0104e-02 1.1154e-02 -1.5040e-04 9.9409e-06 3.7606e-05 -6.0000e+00 7.0810e-04 3.7436e-03 0.0000e+00 10 0 0 10 0 0 99.95 22.90 0.24 0.00374 0.00261 1147 235 1 5 0 43.400 22.90 15.00 18.55 -5630 -3856 -4820 -4696 -9956 -6763 -10200 -5330 -8643 -7099 -11418 -8380 -5946 -3055 -1178 -182 -543 434 1084 1318 2030 310 1186 239 -452 -2505 -2213 -4000 -2340 -2306 208 -151 347 -961 -4449 -3447 -2960 -1916 -1137 -1080 -1633 -1678 -689 -370 -253 688 -35 501 -81 770 1008 1756 1126 1590 769 755 773 79 -160 576 1181 1998 1877 1930 942 -223 521 445 1313 1658 289 179 -331 39 -133 -728 -664 -1281 -923 -965 -1732 -1676 -1868 -1958 -887 -569 145 293 494 669 316 650 -47 306 698 286 15 270 117 -732 -615 -707 -470 364 -257 -1246 -1129 -390 -72 783 410 510 -21 382 46 814 883 782 48 222 -424 5 -21 525 -34 490 -297 415 506 -193 -469 -678 -624 113 -132 290 -289 447 140 118 -161 12 -358 -173 -130 -173 -163 -328 -207 -338 -190 -358 -308 -523 -391 -318 -190 -85 -15 -48 40 106 134 214 33 126 27 -56 -328 -290 -514 -285 -281 27 -22 56 -168 -762 -570 -524 -392 -278 -310 -521 -569 -241 -132 -90 247 -12 179 -29 281 389 736 507 758 384 387 407 42 -83 295 614 1106 1143 1274 600 -150 325 273 841 1109 214 139 -259 29 -94 -511 -424 -788 -589 -702 -1321 -1426 -1734 -1906 -908 -622 167 321 584 771 342 650 -43 274 663 303 18 327 155 -988 -786 -894 -549 422 -324 -1554 -1464 -530 -102 1200 627 811 -33 616 70 1141 1212 1113 72 356 -699 9 -33 796 -50 684 -396 586 707 -299 -778 -1178 -1105 193 -238 554 -569 891 282 236 -309 22 -633
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