File name: Pandora104s1_Downsview_20231207_L2Fit_fwvt1c18d20230421p1-8.txt File generation date: 20240426T154953.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v18d20230421.txt Level 1 file used: Pandora104s1_Downsview_20231207_L1_smca1c18d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20230421 First and last pixel inside fitting window: 1630 1780 Nominal wavelengths inside fitting window [nm]: 492.0182 492.1387 492.2593 492.3798 492.5004 492.6209 492.7414 492.8618 492.9823 493.1027 493.2231 493.3435 493.4639 493.5843 493.7046 493.8250 493.9453 494.0656 494.1859 494.3061 494.4264 494.5466 494.6668 494.7870 494.9072 495.0274 495.1475 495.2676 495.3877 495.5078 495.6279 495.7480 495.8680 495.9880 496.1080 496.2280 496.3480 496.4680 496.5879 496.7078 496.8277 496.9476 497.0675 497.1873 497.3071 497.4270 497.5468 497.6665 497.7863 497.9060 498.0258 498.1455 498.2652 498.3849 498.5045 498.6242 498.7438 498.8634 498.9830 499.1026 499.2221 499.3416 499.4612 499.5807 499.7002 499.8196 499.9391 500.0585 500.1779 500.2973 500.4167 500.5361 500.6554 500.7747 500.8941 501.0133 501.1326 501.2519 501.3711 501.4903 501.6096 501.7287 501.8479 501.9671 502.0862 502.2053 502.3244 502.4435 502.5626 502.6816 502.8007 502.9197 503.0387 503.1576 503.2766 503.3955 503.5145 503.6334 503.7523 503.8711 503.9900 504.1088 504.2277 504.3465 504.4652 504.5840 504.7028 504.8215 504.9402 505.0589 505.1776 505.2963 505.4149 505.5335 505.6521 505.7707 505.8893 506.0079 506.1264 506.2449 506.3634 506.4819 506.6004 506.7188 506.8373 506.9557 507.0741 507.1924 507.3108 507.4292 507.5475 507.6658 507.7841 507.9023 508.0206 508.1388 508.2571 508.3753 508.4935 508.6116 508.7298 508.8479 508.9660 509.0841 509.2022 509.3202 509.4383 509.5563 509.6743 509.7923 509.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231207T161946.8Z 8741.680403 339 1 6.09 2 67.37 167.62 66.28 237.52 0.00 1 0.00 1 0 15 2.675e-03 2.677e-03 1.458e-03 1.456e-03 1.369530e+03 7.972659e+01 8.979879e+01 -6.000000e+00 1.407868e+02 274.64 -2.00 20.00 -2.00 505.26 0.00e+00 6.831816e-04 3.883459e-05 3.922449e-05 -6.000000e+00 7.296175e-05 274.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.294694e-02 2.822023e-02 1.476071e-02 -6.000000e+00 5.231956e-02 222.28 -2.00 3.57 -2.00 502.07 0.00e+00 2.578 0.000 489.00 513.00 1 6.6210e+00 2.1544e-03 3.9118e-03 -6.0000e+00 3.9963e-03 6.3277e-03 5.6283e-04 3.5894e-04 -6.0000e+00 1.0459e-03 1.7918e-03 1.3277e-04 1.2512e-04 1.6074e-05 -6.0000e+00 2.3616e-04 2.8180e-03 1.7085e-07 12 1 1 12 1 1 -309.07 22.90 1.27 0.00282 0.00374 3 7 1 4 0 1521.590 22.90 15.00 18.58 -61 -180 -610 -46 -332 270 276 293 417 506 174 472 -309 -211 -110 -113 -281 -22 -145 -25 -45 184 2 313 390 382 156 -77 -158 -524 -220 -69 -152 61 152 -181 -151 43 94 -2 224 100 254 428 104 175 157 46 -2 146 -59 -27 -395 -445 -20 -259 -575 -225 -227 41 299 714 193 167 227 86 194 -34 -30 -237 -395 74 -75 -260 -149 -43 -509 70 -166 -484 41 -200 -200 -367 63 -325 -298 -55 -483 -444 251 257 204 278 -5 -75 39 109 -305 109 -624 96 -373 -277 -211 -448 -281 17 59 -3 166 102 -96 158 386 225 436 466 619 -70 196 506 509 266 -4 305 34 284 243 48 175 70 -228 -125 -80 -152 -216 -223 -179 -70 -45 179 214 322 177 -191 -275 -254 -299 -220 32 -58 -175 -596 -46 -337 277 282 303 433 520 180 483 -314 -210 -109 -111 -281 -23 -149 -26 -46 192 2 326 410 401 163 -80 -163 -535 -217 -68 -151 62 158 -188 -159 44 97 -2 226 101 259 441 109 179 161 48 -2 146 -60 -26 -388 -434 -19 -260 -581 -231 -233 41 303 724 198 172 233 88 193 -35 -30 -234 -385 72 -73 -257 -146 -43 -509 68 -159 -465 39 -193 -195 -360 62 -318 -293 -54 -476 -438 248 255 206 278 -5 -76 39 106 -299 104 -587 90 -357 -268 -208 -448 -279 17 58 -3 163 102 -96 159 391 229 445 479 635 -72 196 497 505 264 -4 299 34 278 237 47 171 69 -222 -120 -76 -144 -208 -221 -175 -70 -45 180 216 326 176 -191 -273 -253 -289 -214 30 SQ 20231207T163017.6Z 8741.687704 343 1 39.40 2 67.01 170.22 67.90 239.69 0.00 1 0.00 1 0 15 2.171e-03 2.172e-03 1.956e-04 1.952e-04 1.171422e+03 1.061853e+01 8.016721e+01 -6.000000e+00 1.142441e+02 274.64 -2.00 20.00 -2.00 505.27 0.00e+00 6.825484e-04 5.199493e-06 3.941628e-05 -6.000000e+00 5.920332e-05 274.64 -2.00 20.00 -2.00 500.48 0.00e+00 9.989236e-02 3.780036e-03 1.246449e-02 -6.000000e+00 4.246795e-02 222.28 -2.00 3.57 -2.00 502.07 0.00e+00 2.541 0.000 489.00 513.00 1 4.6373e+00 2.8842e-04 3.8110e-03 -6.0000e+00 3.2437e-03 2.2060e-03 7.5436e-05 3.1829e-04 -6.0000e+00 8.4919e-04 1.3094e-02 6.5203e-04 1.6891e-05 1.5605e-05 -6.0000e+00 1.9157e-04 6.2292e-03 -3.4053e-05 12 1 1 12 1 1 99.99 22.90 1.28 0.00623 0.01075 318 83 1 4 0 123.470 22.90 14.99 18.57 -103 -177 -291 -94 -16 144 402 356 339 304 199 334 12 -165 -115 -173 -10 -103 13 -46 -46 221 194 242 351 231 122 135 -188 -267 -224 154 -234 -71 -145 -272 -156 -9 72 2 93 59 146 137 221 181 221 171 89 -43 -312 -356 -262 -378 -230 -281 -443 -199 -198 91 187 305 213 145 186 74 167 38 -39 -167 -283 -96 9 -188 -155 -248 -302 -107 -133 -62 -293 -192 -275 -318 -174 -183 -304 -183 -119 -56 115 36 286 66 11 45 70 5 -298 -229 -402 -166 -213 -308 -316 -546 -341 -117 -6 139 162 17 75 163 260 404 480 407 235 177 199 331 302 365 342 161 176 288 201 269 195 -89 -75 38 16 -29 40 -69 -221 -99 -58 47 146 193 77 -31 -175 -309 -210 -121 -45 -96 -168 -284 -95 -16 146 415 372 356 317 203 337 12 -163 -117 -176 -9 -103 14 -49 -48 233 204 255 373 245 129 142 -195 -268 -217 149 -229 -72 -154 -281 -159 -10 75 2 95 60 151 144 225 185 225 180 92 -44 -309 -342 -258 -369 -220 -279 -453 -207 -206 94 192 315 222 145 193 76 168 38 -39 -163 -272 -92 9 -183 -155 -248 -298 -103 -126 -59 -277 -183 -265 -307 -170 -182 -303 -183 -118 -56 115 36 282 66 11 44 70 5 -288 -217 -374 -155 -202 -304 -312 -547 -338 -114 -6 137 156 17 75 165 264 412 491 419 243 181 199 326 293 354 335 158 172 284 197 262 191 -87 -72 37 15 -28 37 -66 -218 -98 -58 47 148 197 79 -32 -178 -309 -204 -115 -43 SQ 20231207T163429.0Z 8741.690614 346 1 2.86 2 66.89 171.26 68.55 240.53 0.00 1 0.00 1 0 8 2.669e-03 2.676e-03 1.837e-03 1.835e-03 1.176331e+03 9.940960e+01 7.591721e+01 -6.000000e+00 1.404416e+02 274.64 -2.00 20.00 -2.00 505.26 0.00e+00 5.410343e-04 4.897453e-05 3.102708e-05 -6.000000e+00 7.278597e-05 274.64 -2.00 20.00 -2.00 500.50 0.00e+00 8.847450e-02 3.548942e-02 1.291311e-02 -6.000000e+00 5.218339e-02 222.28 -2.00 3.57 -2.00 502.08 0.00e+00 2.528 0.000 489.00 513.00 1 6.2381e+00 2.7096e-03 3.7601e-03 -6.0000e+00 3.9860e-03 2.4804e-03 7.0800e-04 3.2596e-04 -6.0000e+00 1.0430e-03 2.6536e-03 4.4701e-04 1.5883e-04 1.3239e-05 -6.0000e+00 2.3567e-04 2.4560e-03 1.0139e-05 12 1 1 12 1 1 999.00 22.90 1.27 0.00246 0.00556 2 11 1 4 0 950.820 22.90 14.99 18.57 -292 -135 -224 -261 23 180 98 183 500 162 -61 404 -237 -490 -75 -125 -79 176 -108 76 140 291 400 -4 508 -67 75 291 -230 -200 -304 288 -362 -228 -230 -147 -55 223 58 -271 160 368 -95 384 112 462 437 453 200 62 -240 -311 30 -101 -236 -225 -271 -517 -311 26 145 480 99 161 75 -12 -106 104 0 -212 -423 -254 330 -19 -208 -231 -260 -40 -221 -265 -485 -195 -336 -147 -29 132 -376 -173 -77 179 27 46 199 -311 194 165 65 185 -673 -256 -154 -140 -442 -452 45 -383 -196 -429 -27 -28 268 -67 -100 251 182 387 457 598 358 378 355 258 523 255 544 341 277 8 45 136 312 -221 10 -215 211 -13 80 -202 -34 105 -304 -134 16 -94 32 26 14 -512 -271 -279 6 -283 -129 -221 -261 23 183 102 188 516 166 -63 409 -239 -499 -75 -125 -80 178 -110 79 145 302 414 -4 530 -70 78 302 -236 -202 -304 286 -358 -232 -240 -152 -58 230 60 -275 161 370 -97 394 117 483 457 467 204 62 -239 -308 29 -97 -233 -224 -272 -529 -317 27 146 486 102 165 77 -12 -105 104 0 -209 -410 -245 319 -18 -209 -227 -257 -38 -216 -258 -474 -187 -326 -143 -29 131 -370 -170 -75 175 27 46 201 -313 194 167 65 180 -659 -244 -147 -134 -424 -439 44 -385 -194 -431 -27 -27 265 -66 -100 254 186 396 469 602 362 385 356 255 519 253 534 336 273 7 44 133 306 -216 10 -207 205 -13 77 -196 -33 104 -307 -133 16 -94 33 26 14 -513 -263 -271 5 SQ 20231207T163926.0Z 8741.694051 349 1 12.81 2 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