File name: Pandora104s1_Downsview_20240413_L2Fit_fout2c23d20230421p1-8.txt
File generation date: 20241127T212514.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c23p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 104
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora104_OF_v10d20171009.txt
Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt
Level 1 file used: Pandora104s1_Downsview_20240413_L1_smca1c23d20230421p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20240413
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421"
First and last pixel inside fitting window: 206 348
Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20240413T160351.5Z 8869.669346 209 1 50.32 2 38.00 149.26 68.29 71.48 0.00 1 0.00 1 0 17 2.303e-02 9.702e-03 1.927e-02 5.287e-03 2.717178e-01 2.736376e-03 3.346151e-03 -6.000000e+00 1.354767e-02 228.08 -2.00 3.57 -2.00 317.75 0.00e+00 1.433883e-03 4.314515e-04 3.774926e-04 -6.000000e+00 5.849095e-04 277.28 -2.00 20.00 -2.00 317.11 0.00e+00 1.268 0.000 302.00 328.00 3 6.7642e+00 7.2559e-03 1.9108e-02 -6.0000e+00 3.3753e-02 1.0162e-01 8.1644e-03 1.4155e-02 -6.0000e+00 3.6588e-02 -2.6088e-02 5.0109e-03 7.0941e-03 -6.0000e+00 2.1722e-02 2.0363e-03 2.4897e-03 2.2068e-03 -6.0000e+00 9.1655e-03 1.1725e-04 -8.6700e-05 1.5716e-04 2.2990e-05 -6.0000e+00 6.3210e-04 8.1978e-03 0.0000e+00 12 9 8 11 8 0 99.94 22.61 0.55 0.00820 0.00755 15 3 1 5 0 3353.060 22.61 15.00 18.32 -2222 -3559 2977 -711 3047 -1096 -7137 4730 5448 -2163 -7823 -7755 -3809 -8483 -1511 -652 -4250 1573 2883 5560 -1335 241 5249 -914 1163 -499 -854 -1543 4588 885 -1490 720 -3440 -232 -8308 -4691 -4275 -2235 127 -265 -589 577 1276 -1058 56 1576 352 1002 1050 -1585 205 2424 503 1614 1478 142 102 1288 -884 470 1471 1885 1571 1652 1598 -124 36 129 1289 2721 -582 485 622 387 -293 -1859 -2532 -2287 -718 -2451 -2798 -2331 -1391 -2283 -421 430 466 789 1077 1389 -127 54 -1445 -1560 26 -518 184 -605 624 42 -890 -1091 -944 -484 -345 -1831 -1030 334 -493 1410 922 1646 634 1170 -397 -433 -122 48 -586 312 405 581 299 416 -264 637 -527 -491 602 -135 430 -340 -398 -119 -243 308 -413 666 163 75 -148 -464 -622 -212 -372 301 -71 262 -93 -668 442 559 -250 -944 -954 -508 -1362 -260 -122 -861 313 591 1146 -304 53 1107 -215 283 -127 -217 -376 1000 196 -354 182 -974 -67 -2424 -1287 -1250 -741 49 -118 -287 291 661 -567 29 825 184 509 525 -814 108 1340 298 992 934 92 68 848 -583 305 961 1308 1176 1312 1293 -96 26 90 921 2161 -515 443 568 344 -249 -1458 -1818 -1552 -491 -1893 -2411 -2192 -1391 -2386 -458 494 564 982 1338 1682 -146 58 -1438 -1489 25 -555 214 -771 843 57 -1164 -1326 -1077 -557 -425 -2418 -1397 467 -719 2147 1477 2686 1016 1775 -567 -585 -161 65 -838 472 628 897 449 609 -370 860 -681 -623 796 -192 639 -523 -619 -192 -407 541 -746 1215 302 138 -263 -801 -1045
SS 20240413T160954.5Z 8869.673547 212 1 50.00 2 37.46 151.53 67.29 72.35 0.00 1 0.00 1 0 17 3.101e-02 1.028e-02 2.064e-02 5.629e-03 2.661507e-01 2.917380e-03 3.247747e-03 -6.000000e+00 1.824356e-02 228.08 -2.00 3.57 -2.00 317.81 0.00e+00 4.153961e-04 4.645314e-04 4.288495e-04 -6.000000e+00 7.875534e-04 277.28 -2.00 20.00 -2.00 317.16 0.00e+00 1.259 0.000 302.00 328.00 3 6.5791e+00 7.7500e-03 1.8781e-02 -6.0000e+00 4.5453e-02 8.2889e-02 8.7277e-03 1.3852e-02 -6.0000e+00 4.9269e-02 -1.4996e-02 5.3746e-03 6.8592e-03 -6.0000e+00 2.9250e-02 -4.2317e-03 2.6664e-03 1.9430e-03 -6.0000e+00 1.2344e-02 1.4526e-04 6.0905e-05 1.6806e-04 2.1230e-05 -6.0000e+00 8.5118e-04 7.5622e-03 0.0000e+00 12 9 8 11 8 0 99.98 22.61 0.63 0.00756 0.00802 45 9 1 5 0 1110.990 22.61 15.00 18.32 -6020 10508 771 -4410 -6036 -7533 4061 -6768 4550 -5659 9038 -14140 2793 -8993 5382 -3497 5828 -1920 8895 -1128 8235 226 1791 203 1287 -2700 -2187 -1849 -4208 2546 -4285 294 -2056 5454 -6280 1326 -7304 2546 -1104 3269 -1419 1953 -737 -1492 -1917 327 -932 472 -79 -935 303 -1011 2472 694 1799 -460 2850 -509 2015 -55 2654 311 2633 600 515 -1022 465 -733 393 1968 -60 664 -1197 508 -1098 -619 -3151 -175 -2357 -20 -2390 -98 -1850 -379 553 132 203 455 664 314 740 -265 -97 -2063 1372 -1356 1191 107 502 -1012 539 -1789 -252 -1108 -490 -1987 -994 -290 191 1178 373 1130 -190 1148 -792 735 -308 604 -704 646 -692 1127 16 1894 -218 936 -319 445 227 -216 -748 -1046 -404 -425 -35 -44 121 133 494 204 227 -462 -542 -592 952 79 -449 -561 -678 342 -709 475 -684 941 -1864 351 -1443 857 -665 1054 -388 1687 -243 1676 49 385 47 311 -701 -563 -450 -991 549 -1030 73 -564 1460 -1762 337 -2161 794 -424 1393 -690 964 -386 -794 -1017 171 -485 237 -39 -468 156 -567 1413 424 1117 -297 1829 -338 1277 -36 1694 216 1928 476 416 -785 326 -504 279 1553 -52 599 -1102 448 -930 -475 -2248 -115 -1612 -15 -2025 -89 -1839 -386 592 151 245 567 826 383 844 -282 -95 -1960 1318 -1451 1363 135 676 -1385 692 -2173 -283 -1277 -604 -2626 -1349 -408 277 1804 603 1862 -308 1747 -1133 979 -406 814 -1008 977 -1088 1739 24 2742 -306 1260 -412 558 301 -308 -1128 -1623 -630 -688 -59 -79 221 247 922 379 409 -809 -919
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