File name: Pandora104s1_Downsview_20240507_L2Fit_fout2c23d20230421p1-8.txt File generation date: 20241127T212655.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c23p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v23d20230421.txt Level 1 file used: Pandora104s1_Downsview_20240507_L1_smca1c23d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240507 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 18 for SO2 "based on session 14 for VP 20230421" First and last pixel inside fitting window: 206 348 Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240507T103507.4Z 8893.441058 59 1 50.36 2 85.15 71.01 79.83 78.42 0.00 1 0.00 1 0 25 6.322e-01 6.730e-02 4.722e-01 6.190e-02 1.050574e+00 3.682813e-02 1.172991e-02 -6.000000e+00 3.760782e-01 230.23 -2.00 3.57 -2.00 321.67 0.00e+00 -2.028126e-02 9.550977e-03 8.196204e-03 -6.000000e+00 1.642728e-02 280.01 -2.00 20.00 -2.00 321.01 0.00e+00 10.040 0.020 302.00 328.00 3 1.3620e-01 1.1386e-01 1.3135e-01 -6.0000e+00 9.4187e-01 2.4290e+00 1.3236e-01 1.0963e-01 -6.0000e+00 1.0208e+00 -2.3705e+00 7.1772e-02 2.7973e-02 -6.0000e+00 6.0421e-01 7.8933e-01 3.9643e-02 2.3207e-02 -6.0000e+00 2.5570e-01 6.6410e-06 7.6972e-04 1.5803e-03 2.1699e-04 -6.0000e+00 1.7557e-02 9.7962e-03 0.0000e+00 12 8 8 10 0 0 98.60 22.80 1.54 0.00980 0.01558 23 5 1 5 0 2189.070 22.80 15.00 18.47 12452 -2018 99142 -38979 165046 -11741 57446 18907 15559 98765 -43836 249172 11558 124053 -13820 34128 70972 44880 -18284 216864 62039 30871 900000 -13856 88194 -16004 -25227 23617 14804 -37351 69866 -54953 67388 8735 56710 900000 900000 -3124 163347 13328 139234 -18607 43498 -26850 29237 -5563 -29675 79554 -31287 900000 16806 900000 -18305 188611 45321 358135 -13950 217023 -35029 20667 -38703 36486 -15333 -20527 16943 11731 5234 65722 48218 -1734 -3183 28230 29445 16799 93864 -38862 33877 8843 20242 -24162 32257 -4433 5134 15868 -842 11787 29510 -10625 -8931 -6499 6634 -7294 4526 8030 -11171 5630 6846 15720 -6405 17011 -19851 14712 -16169 -14835 -3159 7700 827 -4872 5066 5299 -1760 7301 8994 -1650 297 -8241 9862 -5179 6989 -454 5962 -1477 3402 887 6291 -5363 -1158 -4317 564 -3417 -3003 1816 -1699 321 -4180 2944 -2376 4588 -448 1215 -2072 3132 -1149 2128 -375 5979 -7640 9953 -1239 3464 1710 1564 5956 -8151 15027 1336 7481 -2361 3773 5837 4285 -3124 13078 4422 2708 900000 -2127 5319 -2720 -4288 2072 1217 -4915 4213 -10545 4064 958 3420 900000 900000 -377 9851 1900 8397 -3979 4769 -5447 3045 -762 -4881 4798 -5317 900000 2027 900000 -3713 11375 5466 21598 -3212 13088 -8642 2867 -8275 4181 -3236 -4614 3065 2193 1042 7531 7270 -492 -979 6469 6393 3748 8491 -11484 4495 1547 3540 -7869 7003 -1604 1889 5550 -366 4692 10144 -5510 -4416 -2979 2481 -2991 1638 3002 -5861 2954 4129 9955 -5640 12105 -19274 8961 -11896 -10467 -2114 4876 588 -3967 4186 5113 -2101 8850 11227 -2319 400 -11778 11776 -7496 9357 -676 8054 -2022 4186 1102 7208 -6792 -1361 -5519 806 -6038 -6030 3843 -4015 813 -11974 8379 -7251 13170 -1345 3451 -5609 7386 -2660 SS 20240507T104746.5Z 8893.449844 62 1 49.79 2 82.97 73.13 77.62 80.40 0.00 1 0.00 1 0 25 6.078e-01 1.865e-02 3.436e-01 8.992e-03 9.285465e-01 5.474105e-03 1.121430e-02 -6.000000e+00 3.620638e-01 230.23 -2.00 3.57 -2.00 322.40 0.00e+00 2.362048e-02 3.319801e-03 1.526440e-03 -6.000000e+00 1.693073e-02 280.01 -2.00 20.00 -2.00 321.99 0.00e+00 7.506 0.008 302.00 328.00 3 4.1686e-01 2.2240e-02 9.5680e-02 -6.0000e+00 9.0369e-01 1.0398e+00 3.0523e-02 7.7411e-02 -6.0000e+00 9.7822e-01 -1.3371e+00 2.9027e-02 2.8789e-02 -6.0000e+00 5.8051e-01 5.3072e-01 1.3322e-02 2.3557e-02 -6.0000e+00 2.4528e-01 8.0285e-05 -1.2355e-03 2.5551e-04 3.6372e-04 -6.0000e+00 1.6888e-02 9.4823e-03 0.0000e+00 12 8 8 10 0 0 63.13 22.80 0.46 0.00948 0.00020 116 24 1 5 0 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2.4689e-01 1.0094e-02 5.5524e-02 -6.0000e+00 1.0761e+00 -3.3186e-01 1.0987e-02 3.5375e-02 -6.0000e+00 6.3896e-01 1.2978e-01 4.9665e-03 1.4412e-02 -6.0000e+00 2.6966e-01 4.1297e-04 -7.7132e-05 8.5670e-05 2.4728e-04 -6.0000e+00 1.8483e-02 9.0652e-03 0.0000e+00 12 8 8 10 0 0 45.83 22.80 0.37 0.00907 0.00849 296 61 1 5 0 168.210 22.80 15.00 18.48 -152379 -204300 -176185 -206831 -235537 -159791 -273310 -177707 -264067 -150521 -252471 900000 -178274 900000 -128953 97115 -80127 39824 -60468 -2959 -57897 -19220 -87532 -70173 -75453 -66486 -35162 -82926 -46254 -74227 18374 -37139 12946 -6042 23595 -34384 36298 -6163 23604 11180 14321 15048 17389 4479 7940 5667 -277 11796 3691 9873 4270 12618 4405 14733 3528 11170 4190 12899 2307 12310 4513 11604 5453 11328 5918 3853 4708 1661 6723 2636 3445 2472 2274 -613 3005 -3060 -89 -3599 1319 -1247 443 -953 845 -1570 279 -358 827 364 -170 80 -832 225 -2939 -1104 -1903 -495 -1219 456 21 -402 -981 -573 -943 338 -501 -1996 -1461 -1045 283 142 425 158 -469 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