File name: Pandora104s1_Downsview_20240508_L2Fit_fout2c18d20230421p1-8.txt File generation date: 20240511T125523.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v18d20230421.txt Level 1 file used: Pandora104s1_Downsview_20240508_L1_smca1c18d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20230421 First and last pixel inside fitting window: 206 348 Nominal wavelengths inside fitting window [nm]: 305.0496 305.1902 305.3308 305.4713 305.6119 305.7524 305.8929 306.0334 306.1739 306.3144 306.4549 306.5954 306.7358 306.8763 307.0167 307.1571 307.2976 307.4380 307.5784 307.7187 307.8591 307.9995 308.1398 308.2801 308.4205 308.5608 308.7011 308.8414 308.9817 309.1219 309.2622 309.4024 309.5427 309.6829 309.8231 309.9633 310.1035 310.2437 310.3838 310.5240 310.6641 310.8043 310.9444 311.0845 311.2246 311.3647 311.5048 311.6448 311.7849 311.9249 312.0650 312.2050 312.3450 312.4850 312.6250 312.7650 312.9049 313.0449 313.1848 313.3248 313.4647 313.6046 313.7445 313.8844 314.0243 314.1641 314.3040 314.4438 314.5836 314.7235 314.8633 315.0031 315.1428 315.2826 315.4224 315.5621 315.7019 315.8416 315.9813 316.1210 316.2607 316.4004 316.5401 316.6797 316.8194 316.9590 317.0986 317.2382 317.3778 317.5174 317.6570 317.7966 317.9361 318.0757 318.2152 318.3547 318.4943 318.6338 318.7732 318.9127 319.0522 319.1916 319.3311 319.4705 319.6099 319.7493 319.8887 320.0281 320.1675 320.3068 320.4462 320.5855 320.7249 320.8642 321.0035 321.1428 321.2820 321.4213 321.5606 321.6998 321.8391 321.9783 322.1175 322.2567 322.3959 322.5351 322.6742 322.8134 322.9525 323.0916 323.2308 323.3699 323.5090 323.6480 323.7871 323.9262 324.0652 324.2043 324.3433 324.4823 324.6213 324.7603 324.8993 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T104804.8Z 8894.450056 61 1 5.10 2 82.72 72.99 83.14 67.72 0.00 1 0.00 1 0 25 5.429e-01 3.598e-02 4.548e-01 3.102e-02 9.980470e-01 2.042328e-02 1.170247e-02 -6.000000e+00 3.454891e-01 230.32 -2.00 3.57 -2.00 322.24 0.00e+00 -7.024483e-03 1.191921e-02 1.483833e-02 -6.000000e+00 2.146793e-02 280.12 -2.00 20.00 -2.00 321.81 0.00e+00 7.289 0.007 302.00 328.00 3 1.7028e+00 8.0520e-02 1.2636e-01 -6.0000e+00 8.7668e-01 1.1144e+00 1.0944e-01 1.3029e-01 -6.0000e+00 9.6193e-01 -1.6255e+00 9.7758e-02 4.8057e-02 -6.0000e+00 5.5237e-01 6.7645e-01 4.5040e-02 1.0563e-02 -6.0000e+00 2.4211e-01 2.7400e-05 -4.5975e-04 9.0410e-04 2.0884e-04 -6.0000e+00 1.7819e-02 7.0726e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.80 0.64 0.00707 0.00362 2 6 1 5 0 1696.790 22.80 15.00 18.53 900000 900000 900000 900000 900000 -196679 900000 900000 900000 900000 900000 -133868 900000 54355 -3729 900000 900000 129505 54760 900000 104898 900000 900000 900000 -99220 900000 -5794 900000 900000 -25004 -41582 900000 900000 -54698 900000 -11257 900000 33204 900000 900000 900000 -11687 88409 89729 900000 7391 193286 900000 900000 31644 228504 17773 900000 17825 11089 62614 -6040 119109 70854 113186 121670 85205 28683 109207 1373 52421 3947 52734 44145 41899 21236 56008 13949 22068 77229 -1886 48426 -20197 14974 3421 24781 2123 16001 1422 7230 -1058 10657 6752 2515 -9187 -13812 -3631 -3090 -10268 1358 -11523 -3803 853 -6301 1329 -3658 -3675 -150 108 -7655 3467 -3315 -2791 4074 -2917 -6702 123 -3275 -136 140 2123 3045 268 1110 3514 2991 662 1778 3680 858 1348 1700 -3394 2598 101 1402 -1660 2987 -1243 235 47 -659 419 -365 -82 -2640 -1371 2717 900000 900000 900000 900000 900000 -10244 900000 900000 900000 900000 900000 -5321 900000 1632 -112 900000 900000 3889 1644 900000 3150 900000 900000 900000 -6198 900000 -174 900000 900000 -751 -1492 900000 900000 -3148 900000 -379 900000 997 900000 900000 900000 -779 2655 2695 900000 382 5804 900000 900000 1510 6862 1208 900000 1434 1010 3652 -697 4125 3660 3663 3654 3757 2432 4898 187 4453 534 4778 4788 5351 3588 7096 2580 3533 6633 -305 4588 -3788 2274 695 4874 599 4473 486 2479 -413 3899 2632 1011 -3992 -5932 -1363 -1147 -4319 590 -6652 -2385 589 -5196 1058 -2934 -2676 -95 67 -5362 2329 -2481 -2245 3407 -2994 -8078 154 -4406 -181 182 2656 3781 355 1520 4896 4103 886 2236 4492 1047 1616 1977 -4260 3537 162 2493 -3283 6032 -2786 551 116 -1665 1057 -923 -203 -6208 -2976 5390 SS 20240508T121941.9Z 8894.513680 103 1 3.42 2 66.45 88.19 67.56 81.65 0.00 1 0.00 1 0 17 3.917e-02 8.259e-03 2.644e-02 3.439e-03 4.104109e-01 1.803085e-03 4.894908e-03 -6.000000e+00 2.323333e-02 230.33 -2.00 3.57 -2.00 318.49 0.00e+00 1.708460e-03 3.636489e-04 5.154565e-04 -6.000000e+00 1.006600e-03 280.13 -2.00 20.00 -2.00 317.82 0.00e+00 2.484 0.000 302.00 328.00 3 3.1136e+00 4.8935e-03 3.2835e-02 -6.0000e+00 5.8140e-02 3.5913e-02 5.5577e-03 2.1647e-02 -6.0000e+00 6.2891e-02 -1.2528e-02 3.8040e-03 1.0800e-02 -6.0000e+00 3.7332e-02 -2.7407e-03 1.9842e-03 3.3581e-03 -6.0000e+00 1.5719e-02 1.1857e-03 -6.1667e-05 9.8813e-05 3.3890e-05 -6.0000e+00 1.0757e-03 8.6637e-03 0.0000e+00 12 9 1 12 1 1 99.25 22.80 0.29 0.00866 0.00820 7 24 1 5 0 426.290 22.80 15.00 18.50 13056 -22121 9836 -11517 4638 -10753 -1135 -9147 -8883 265 -8075 -3705 -7522 11176 -11806 8400 -2358 3780 -7817 4237 -4003 5084 -4051 2990 -2732 -529 -5222 -3060 -3085 -1892 412 407 1621 -1626 -2717 -7387 1139 -3373 -446 -3220 460 -2573 657 -1380 3605 905 155 327 82 1481 1243 1389 588 2701 635 2261 -23 738 -949 1118 221 3178 637 1702 1 939 -597 741 1066 1660 364 561 269 -172 289 -902 81 -2003 -1447 -1552 -2017 -2598 -1126 -2695 -208 -846 350 275 1157 622 542 164 -85 -70 411 -101 -484 696 39 -375 -1133 -657 -770 269 -538 -1408 -835 7 -242 1320 344 889 95 497 -183 698 838 662 294 -145 -347 0 272 386 289 406 -308 86 716 -244 -342 -699 -802 176 -212 897 -296 534 -85 -65 -309 68 -517 407 -1060 371 -512 163 -422 -43 -424 -458 13 -448 -209 -514 764 -1174 787 -261 422 -1027 522 -552 642 -566 418 -429 -85 -880 -490 -481 -295 68 76 327 -359 -578 -1616 248 -880 -134 -1130 171 -1028 266 -577 1452 378 65 138 35 636 564 677 305 1448 357 1285 -13 436 -558 646 130 1947 426 1201 1 663 -410 500 751 1283 302 480 231 -144 232 -681 57 -1396 -1041 -1226 -1750 -2439 -1111 -2768 -220 -935 399 321 1342 713 596 173 -86 -69 423 -112 -578 881 52 -506 -1489 -816 -911 318 -671 -1833 -1110 10 -343 1949 533 1407 149 761 -269 990 1177 951 436 -224 -544 -1 413 577 419 578 -427 118 1026 -371 -543 -1142 -1331 299 -372 1623 -546 994 -159 -120 -562 121 -898 SS 20240508T122527.2Z 8894.517676 107 1 50.07 2 65.41 89.17 66.55 82.53 0.00 1 0.00 1 0 17 1.234e-01 1.692e-02 1.572e-01 1.540e-02 4.071716e-01 8.148840e-03 5.194257e-03 -6.000000e+00 7.321950e-02 230.33 -2.00 3.57 -2.00 319.44 0.00e+00 3.987898e-03 2.102147e-03 2.228216e-03 -6.000000e+00 3.172232e-03 280.13 -2.00 20.00 -2.00 318.79 0.00e+00 2.387 0.000 302.00 328.00 3 6.7700e+00 2.2873e-02 3.2711e-02 -6.0000e+00 1.8323e-01 1.7105e-01 2.6543e-02 2.2878e-02 -6.0000e+00 1.9820e-01 -6.1441e-02 1.9395e-02 1.2593e-02 -6.0000e+00 1.1765e-01 1.5097e-02 1.0034e-02 4.6366e-03 -6.0000e+00 4.9539e-02 3.1405e-05 4.9017e-04 4.5923e-04 5.9546e-05 -6.0000e+00 3.3899e-03 8.5589e-03 0.0000e+00 12 9 8 11 8 0 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