File name: Pandora104s1_Downsview_20240610_L2Fit_fwvt1c18d20230421p1-8.txt File generation date: 20240611T052857.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c18p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v18d20230421.txt Level 1 file used: Pandora104s1_Downsview_20240610_L1_smca1c18d20230421p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 14 for VP 20230421 First and last pixel inside fitting window: 1630 1780 Nominal wavelengths inside fitting window [nm]: 492.0182 492.1387 492.2593 492.3798 492.5004 492.6209 492.7414 492.8618 492.9823 493.1027 493.2231 493.3435 493.4639 493.5843 493.7046 493.8250 493.9453 494.0656 494.1859 494.3061 494.4264 494.5466 494.6668 494.7870 494.9072 495.0274 495.1475 495.2676 495.3877 495.5078 495.6279 495.7480 495.8680 495.9880 496.1080 496.2280 496.3480 496.4680 496.5879 496.7078 496.8277 496.9476 497.0675 497.1873 497.3071 497.4270 497.5468 497.6665 497.7863 497.9060 498.0258 498.1455 498.2652 498.3849 498.5045 498.6242 498.7438 498.8634 498.9830 499.1026 499.2221 499.3416 499.4612 499.5807 499.7002 499.8196 499.9391 500.0585 500.1779 500.2973 500.4167 500.5361 500.6554 500.7747 500.8941 501.0133 501.1326 501.2519 501.3711 501.4903 501.6096 501.7287 501.8479 501.9671 502.0862 502.2053 502.3244 502.4435 502.5626 502.6816 502.8007 502.9197 503.0387 503.1576 503.2766 503.3955 503.5145 503.6334 503.7523 503.8711 503.9900 504.1088 504.2277 504.3465 504.4652 504.5840 504.7028 504.8215 504.9402 505.0589 505.1776 505.2963 505.4149 505.5335 505.6521 505.7707 505.8893 506.0079 506.1264 506.2449 506.3634 506.4819 506.6004 506.7188 506.8373 506.9557 507.0741 507.1924 507.3108 507.4292 507.5475 507.6658 507.7841 507.9023 508.0206 508.1388 508.2571 508.3753 508.4935 508.6116 508.7298 508.8479 508.9660 509.0841 509.2022 509.3202 509.4383 509.5563 509.6743 509.7923 509.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240610T121149.7Z 8927.508214 118 1 49.59 2 64.71 81.52 100.25 46.12 0.00 1 0.00 1 0 15 2.583e-03 2.572e-03 1.013e-03 1.010e-03 2.838439e+03 6.050312e+01 1.968035e+02 -6.000000e+00 1.409801e+02 283.64 -2.00 20.00 -2.00 505.25 0.00e+00 5.501174e-04 2.743322e-05 3.370050e-05 -6.000000e+00 7.194645e-05 283.64 -2.00 20.00 -2.00 500.40 0.00e+00 2.356906e-01 1.982668e-02 2.155856e-02 -6.000000e+00 5.086418e-02 232.63 -2.00 3.57 -2.00 501.99 0.00e+00 2.326 0.000 489.00 513.00 1 7.7239e+00 1.5123e-03 3.8120e-03 -6.0000e+00 3.8935e-03 7.4105e-03 3.9714e-04 5.2441e-04 -6.0000e+00 1.0181e-03 6.0843e-04 2.7945e-04 8.6952e-05 2.3797e-05 -6.0000e+00 2.2839e-04 5.8948e-03 1.2534e-05 10 0 0 10 0 0 99.89 22.71 1.29 0.00589 0.00783 26 5 1 4 0 1907.160 22.71 15.00 18.36 -341 -191 -593 -105 -236 88 397 562 239 293 159 343 132 -49 -147 3 34 -316 238 -107 -48 3 306 114 499 118 274 60 -182 -257 -201 186 -165 42 -141 -177 -254 121 -55 21 238 0 76 246 196 140 146 393 139 -81 -303 -580 -206 -261 -199 -446 -365 -225 -105 249 235 74 232 -58 220 175 113 29 42 -171 -307 -26 167 -149 -81 -290 -269 -39 -101 -36 -410 -277 -489 -271 -376 -24 -446 -44 -259 -8 105 152 433 107 216 -85 292 112 -199 -440 -543 -376 -315 -309 -225 -632 -207 -245 -71 166 387 180 123 136 315 231 538 585 99 -13 22 184 279 732 208 187 140 223 185 259 252 -1 -43 243 -19 62 70 -48 -75 -302 -6 -139 157 87 59 -228 -189 -372 -215 -284 91 -329 -186 -598 -103 -238 90 414 593 253 307 164 349 133 -49 -145 3 34 -320 248 -114 -51 3 325 122 533 127 292 64 -191 -259 -196 181 -163 43 -150 -191 -272 127 -58 22 244 0 79 258 208 150 156 414 144 -82 -301 -560 -195 -245 -191 -444 -374 -234 -109 257 242 77 241 -60 228 179 113 29 41 -167 -295 -25 160 -145 -80 -289 -264 -37 -96 -34 -386 -262 -469 -260 -366 -23 -442 -43 -256 -8 104 152 440 110 222 -86 288 109 -188 -408 -495 -343 -294 -300 -228 -651 -210 -246 -70 162 383 181 126 132 308 227 529 581 98 -13 21 186 277 723 209 189 141 212 185 258 252 -1 -42 232 -18 59 68 -47 -71 -290 -6 -136 154 86 59 -225 -186 -358 -201 -261 83 SQ 20240610T121653.7Z 8927.511732 121 1 50.77 2 63.81 82.33 99.62 47.07 0.00 1 0.00 1 0 15 2.508e-03 2.504e-03 1.049e-03 1.047e-03 2.746539e+03 6.261863e+01 1.828337e+02 -6.000000e+00 1.369151e+02 283.64 -2.00 20.00 -2.00 505.26 0.00e+00 5.002503e-04 2.854800e-05 3.196269e-05 -6.000000e+00 6.987299e-05 283.64 -2.00 20.00 -2.00 500.39 0.00e+00 2.056179e-01 2.056930e-02 2.291493e-02 -6.000000e+00 4.939420e-02 232.63 -2.00 3.57 -2.00 502.00 0.00e+00 2.252 0.000 489.00 513.00 1 7.9193e+00 1.5735e-03 3.7585e-03 -6.0000e+00 3.7811e-03 6.4014e-03 4.0960e-04 5.3618e-04 -6.0000e+00 9.8855e-04 5.0719e-04 7.4932e-05 9.0027e-05 2.1360e-05 -6.0000e+00 2.2185e-04 6.3728e-03 1.6742e-05 10 0 0 10 0 0 99.85 22.71 1.27 0.00637 0.00689 14 3 1 4 0 3623.980 22.71 15.00 18.37 -211 -183 -485 11 -226 21 475 221 414 245 204 82 263 -154 -46 -191 -39 -58 -86 134 -65 204 248 252 451 346 223 78 -84 -172 -399 78 -422 -2 -278 -190 -144 -129 -89 144 405 114 115 143 178 189 263 -93 51 44 -375 -473 -345 -332 -44 -349 -173 -268 -56 250 353 421 324 188 42 -35 51 -118 -3 -142 -449 -99 -11 7 -80 -147 -363 -169 -262 -173 139 -112 -322 -528 -254 -172 -289 -127 -24 129 150 -85 317 -134 -42 -80 168 22 -445 -78 -289 -295 -237 -265 -316 -591 -364 -86 -95 227 -11 102 116 365 258 368 583 425 232 38 187 428 459 401 361 -22 117 333 243 333 315 -50 -81 139 -88 -427 72 -298 -87 -125 -192 -6 287 60 173 -131 -59 -367 -57 -203 -81 -201 -176 -477 11 -231 22 499 234 439 259 212 85 269 -156 -46 -192 -40 -60 -91 142 -69 215 263 267 479 368 236 82 -87 -175 -397 77 -424 -2 -293 -202 -153 -135 -93 148 415 118 119 149 187 199 277 -97 53 45 -375 -463 -333 -318 -42 -349 -176 -275 -57 256 360 430 332 193 44 -35 51 -117 -3 -139 -436 -96 -11 7 -80 -146 -357 -163 -251 -165 132 -107 -310 -511 -247 -169 -285 -125 -24 127 148 -84 317 -135 -43 -79 164 22 -423 -73 -267 -273 -222 -255 -313 -592 -363 -84 -93 219 -11 101 116 366 260 371 589 431 236 38 186 421 447 389 353 -22 115 326 237 323 307 -48 -78 131 -82 -402 68 -289 -85 -123 -190 -6 286 60 173 -131 -59 -360 -55 -193 -77 SQ 20240610T122205.5Z 8927.515342 124 1 49.88 2 62.88 83.17 98.96 48.03 0.00 1 0.00 1 0 15 2.447e-03 2.439e-03 8.274e-04 8.256e-04 2.626829e+03 4.915467e+01 1.782409e+02 -6.000000e+00 1.336055e+02 283.64 -2.00 20.00 -2.00 505.26 0.00e+00 5.739669e-04 2.251871e-05 3.470147e-05 -6.000000e+00 6.818212e-05 283.64 -2.00 20.00 -2.00 500.40 0.00e+00 1.861415e-01 1.621624e-02 2.140335e-02 -6.000000e+00 4.820885e-02 232.63 -2.00 3.57 -2.00 502.00 0.00e+00 2.182 0.000 489.00 513.00 1 7.5219e+00 1.2406e-03 3.6306e-03 -6.0000e+00 3.6902e-03 7.8526e-03 3.2303e-04 5.0650e-04 -6.0000e+00 9.6507e-04 7.6268e-04 5.3397e-04 7.1211e-05 2.1509e-05 -6.0000e+00 2.1639e-04 7.9828e-03 -1.0024e-05 10 0 0 10 0 0 99.99 22.71 1.29 0.00798 0.01169 19 4 1 4 0 2624.700 22.71 15.00 18.37 -330 -124 -312 -338 -171 141 292 393 327 133 294 372 8 -172 -60 -178 135 -107 69 17 21 379 244 167 327 163 131 158 -211 -303 -279 33 -369 136 -164 -43 -16 -44 -27 -54 113 143 216 133 79 332 217 161 67 -59 -378 -421 -295 -391 -201 -295 -349 -122 -150 212 168 236 331 166 205 -48 232 106 -82 -133 -430 6 -64 -136 -131 -111 -184 -133 -280 -167 39 -239 -353 -425 -202 -360 -219 -215 -105 -64 193 40 358 26 87 79 34 127 -194 -393 -435 -181 -372 -261 -272 -512 -387 -249 -92 -53 259 55 45 195 90 525 650 599 315 195 392 377 257 466 166 254 121 274 78 191 457 -286 -77 -82 33 -187 93 -178 -174 -138 -58 119 280 -7 16 -24 -34 -184 -253 -242 -210 -316 -120 -307 -341 -175 146 307 415 347 141 305 383 8 -174 -61 -179 136 -109 73 18 23 400 257 176 346 173 138 166 -220 -308 -278 33 -370 139 -173 -45 -17 -47 -28 -56 116 147 223 139 83 349 228 168 69 -60 -378 -413 -285 -377 -196 -295 -355 -126 -154 217 171 241 340 171 210 -49 233 105 -81 -130 -418 6 -62 -133 -129 -110 -181 -129 -269 -160 37 -229 -341 -411 -197 -354 -216 -212 -104 -63 190 40 358 27 88 78 33 123 -185 -369 -403 -168 -349 -251 -269 -513 -385 -245 -89 -52 252 55 45 196 90 528 656 607 320 196 390 371 250 453 162 249 119 268 76 186 445 -278 -73 -77 31 -175 89 -172 -170 -136 -57 118 277 -7 16 -24 -34 -180 -244 -230 -200 SQ 20240610T122638.1Z 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