File name: Pandora122s1_Downsview_20241011_L2Fit_fout2c2d20240229p1-8.txt File generation date: 20241012T051152.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora122_OF_v2d20240108.txt Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt Level 1 file used: Pandora122s1_Downsview_20241011_L1_smca1c2d20240229p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20241011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241011T141633.0Z 9050.594827 168 1 30.49 2 63.66 132.25 147.67 66.61 0.00 1 0.00 1 0 17 3.765e-02 9.324e-03 1.705e-02 4.245e-03 2.832250e-01 2.128611e-03 3.458432e-03 -6.000000e+00 2.134974e-02 225.79 -2.00 3.57 -2.00 317.75 0.00e+00 2.555968e-04 3.441670e-04 3.370160e-04 -6.000000e+00 9.399171e-04 281.48 -2.00 20.00 -2.00 317.05 0.00e+00 2.241 0.000 302.00 328.00 3 5.9811e+00 5.6395e-03 2.6346e-02 -6.0000e+00 5.2862e-02 5.3931e-03 6.3629e-03 1.4725e-02 -6.0000e+00 5.7342e-02 1.2852e-02 4.0074e-03 7.2902e-03 -6.0000e+00 3.4167e-02 -1.4417e-02 2.0611e-03 2.0866e-03 -6.0000e+00 1.4817e-02 1.0678e-04 2.1086e-04 1.2014e-04 2.1664e-05 -6.0000e+00 9.9301e-04 1.6189e-02 0.0000e+00 11 8 0 10 0 0 29.91 22.17 0.43 0.01619 0.01777 8 8 1 5 0 3810.880 26.94 20.00 22.17 20.22 2.1 983.39 197 -11173 8804 6667 -15512 13317 -13427 6934 -14452 4160 -10057 1162 3925 -6625 -393 -571 -704 -802 -8013 5151 -70 13132 3401 4104 2619 1886 -3738 -7034 -4302 3396 -4103 4760 -4545 -1838 2598 -5843 2643 2480 -3128 285 -1234 -1740 622 2266 2178 -1445 -970 1636 -2489 -1292 820 3064 385 1150 890 1188 897 590 -952 742 1449 2328 1837 621 1630 -1323 -1681 -1249 876 -288 1122 842 902 574 1534 -1628 -35 -1524 -1571 1 -2361 -1418 -1213 -1665 -660 -308 787 194 111 -210 81 -268 -593 -248 -20 -124 388 612 866 -785 -38 -1115 -965 -564 -1144 -1136 -602 47 44 334 782 814 -13 -119 -325 -79 569 1282 -139 248 365 576 187 556 463 73 442 945 395 -444 -287 -642 -106 -59 423 -327 110 -445 426 263 -716 -559 16 -1088 723 518 -1333 862 -1208 583 -1648 415 -1134 124 465 -993 -63 -101 -130 -155 -1722 1018 -15 2428 713 909 620 465 -961 -1746 -989 736 -1022 1188 -1337 -531 673 -1645 764 835 -1307 131 -615 -902 324 1167 1122 -768 -505 822 -1281 -672 446 1736 234 725 576 782 601 392 -631 486 980 1676 1422 507 1293 -1002 -1220 -903 675 -247 1010 777 823 507 1255 -1254 -25 -1080 -1194 1 -2186 -1398 -1243 -1778 -739 -362 950 239 136 -248 90 -278 -585 -245 -21 -141 478 806 1166 -1039 -47 -1319 -1120 -685 -1475 -1516 -828 67 66 515 1236 1281 -19 -172 -448 -105 770 1799 -207 380 561 873 279 799 646 99 581 1276 566 -670 -444 -1012 -169 -98 728 -580 198 -812 770 464 -1241 -947 SS 20241011T142206.6Z 9050.598687 171 1 28.94 2 62.92 133.55 146.78 68.08 0.00 1 0.00 1 0 17 3.353e-02 9.115e-03 1.598e-02 4.284e-03 2.768632e-01 2.147103e-03 3.418595e-03 -6.000000e+00 1.901443e-02 225.79 -2.00 3.57 -2.00 317.68 0.00e+00 3.149502e-04 3.395247e-04 3.848734e-04 -6.000000e+00 8.371504e-04 281.48 -2.00 20.00 -2.00 316.98 0.00e+00 2.185 0.000 302.00 328.00 3 6.0166e+00 5.6806e-03 2.5746e-02 -6.0000e+00 4.7080e-02 -1.0803e-03 6.4029e-03 1.4460e-02 -6.0000e+00 5.1071e-02 2.6154e-03 3.9898e-03 7.1479e-03 -6.0000e+00 3.0430e-02 -7.5089e-03 2.0404e-03 2.0415e-03 -6.0000e+00 1.3195e-02 1.1036e-04 1.4089e-04 1.2128e-04 2.1560e-05 -6.0000e+00 8.8446e-04 1.6541e-02 0.0000e+00 11 8 0 10 0 0 44.45 22.18 0.25 0.01654 0.01760 8 8 1 5 0 3616.730 26.94 20.00 22.18 20.51 2.1 985.20 -7274 -2880 -2838 13054 -16686 5991 -16324 6447 -9597 -2275 -6506 -886 -2850 274 -1404 1121 -1418 -5524 -3839 3129 -4044 8013 2102 336 3115 3836 -4004 -3449 -5345 7940 -1038 5059 -3896 -1213 2127 -7003 -952 2183 -3410 631 -610 -1549 -343 3935 1050 694 305 2147 -2423 -239 -46 1794 1283 1268 1218 1942 504 -264 -1022 606 1733 887 2003 981 1443 -1666 -207 -520 843 -1153 200 1130 2074 854 2125 -755 232 -532 -1079 -741 -1873 -820 -2196 -1769 -498 -845 -253 127 12 -791 -382 -1417 -765 -616 106 -390 51 239 72 293 -485 -269 -665 -152 -950 -912 -647 333 601 432 909 1151 -117 -441 -861 623 109 1178 667 5 641 -86 704 900 -221 256 -149 184 314 554 -63 -16 185 -246 269 -724 -26 82 -172 -49 -550 -489 -685 -281 -281 1033 -1563 447 -1620 584 -1118 -257 -756 -102 -381 41 -242 205 -277 -1170 -831 659 -919 1621 465 80 763 964 -1069 -859 -1284 1705 -260 1296 -1170 -357 568 -2041 -291 754 -1458 294 -308 -816 -183 2032 556 368 160 1091 -1264 -125 -25 1039 782 806 793 1281 341 -178 -684 401 1179 651 1560 804 1153 -1272 -149 -375 651 -998 182 1044 1882 754 1738 -580 165 -375 -818 -621 -1729 -805 -2268 -1890 -558 -995 -308 157 14 -940 -425 -1487 -755 -611 112 -446 63 316 97 384 -606 -316 -770 -184 -1223 -1214 -890 470 883 664 1434 1804 -178 -640 -1187 829 147 1650 987 8 984 -131 1044 1289 -309 344 -197 249 449 828 -97 -25 295 -407 461 -1282 -46 148 -311 -87 -950 -824 SS 20241011T142739.4Z 9050.602539 174 1 29.39 2 62.21 134.87 145.89 69.50 0.00 1 0.00 1 0 17 2.933e-02 9.237e-03 1.742e-02 4.490e-03 2.739534e-01 2.250104e-03 3.405199e-03 -6.000000e+00 1.663339e-02 225.79 -2.00 3.57 -2.00 317.75 0.00e+00 -6.433819e-05 3.624062e-04 3.059024e-04 -6.000000e+00 7.323388e-04 281.48 -2.00 20.00 -2.00 317.04 0.00e+00 2.134 0.000 302.00 328.00 3 6.1589e+00 5.9589e-03 2.5294e-02 -6.0000e+00 4.1184e-02 -2.1461e-02 6.7229e-03 1.4404e-02 -6.0000e+00 4.4676e-02 1.1728e-02 4.2187e-03 7.1196e-03 -6.0000e+00 2.6620e-02 -1.2891e-02 2.1624e-03 2.0486e-03 -6.0000e+00 1.1543e-02 1.0181e-04 1.7151e-05 1.2756e-04 2.2042e-05 -6.0000e+00 7.7374e-04 1.6712e-02 0.0000e+00 11 8 0 10 0 0 94.39 22.18 0.35 0.01671 0.01684 8 8 1 5 0 3672.510 26.94 20.00 22.18 20.76 2.1 987.45 5591 -10823 2708 5849 1898 -1784 -7099 655 -9912 -2596 -4542 -5745 -7901 -6340 -3417 465 -2258 -973 -3510 -939 -3067 10970 4496 820 3319 4495 -4415 -4527 -7579 8595 1415 3365 -1412 -4160 7637 -6044 1375 4524 -4614 -627 -674 -38 234 2027 1665 -1114 137 550 -1181 -744 -1222 4159 -416 832 1013 2086 540 1289 -1810 1492 1483 355 2649 133 1378 -342 -1185 -502 386 -319 -689 515 1286 930 1559 -1318 1390 -583 -939 670 -1596 -1194 -1532 -1454 -1386 -1144 562 -633 149 -595 -106 -207 719 182 43 -122 238 824 -336 -334 -383 -924 -566 -893 -808 -1056 -644 433 200 471 739 1226 -295 -188 152 -118 594 1604 -150 1 -594 -92 131 1257 231 -110 658 889 687 416 -119 -366 -75 -178 164 -355 -133 224 -336 63 -674 -312 447 -1091 244 475 144 -138 -623 61 -1124 -286 -504 -675 -1074 -970 -580 83 -430 -191 -734 -199 -671 2098 946 190 794 1100 -1160 -1115 -1816 1789 337 853 -404 -1229 1892 -1705 402 1497 -1958 -291 -335 -20 123 1048 863 -591 71 279 -600 -384 -673 2325 -253 524 653 1359 361 850 -1206 969 1000 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