File name: Pandora122s1_Downsview_20250107_L2Fit_fout2c2d20240229p1-8.txt
File generation date: 20250108T053046.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 122
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora122_OF_v2d20240108.txt
Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt
Level 1 file used: Pandora122s1_Downsview_20250107_L1_smca1c2d20240229p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250107
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 1
First and last pixel inside fitting window: 234 375
Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SU 20250107T160231.7Z 9138.668422 216 1 29.97 2 68.67 159.69 99.70 63.63 0.00 1 0.00 1 0 17 2.936e-02 4.933e-03 2.990e-03 3.103e-04 4.398921e-01 1.547013e-04 5.329437e-03 -6.000000e+00 1.649619e-02 223.08 -2.00 3.57 -2.00 318.81 0.00e+00 6.037611e-04 3.403145e-05 1.992688e-04 -6.000000e+00 7.058164e-04 272.28 -2.00 20.00 -2.00 318.31 0.00e+00 2.725 0.000 302.00 328.00 3 2.6030e-01 4.1785e-04 3.4910e-02 -6.0000e+00 4.0728e-02 3.4138e-02 4.7911e-04 2.2636e-02 -6.0000e+00 4.4310e-02 -1.6087e-02 3.6466e-04 1.1543e-02 -6.0000e+00 2.6311e-02 -1.1558e-03 1.9752e-04 3.4953e-03 -6.0000e+00 1.1406e-02 1.6234e-02 -4.0308e-04 8.4730e-06 3.5284e-05 -6.0000e+00 7.7262e-04 4.2730e-03 0.0000e+00 11 1 0 11 16 0 99.67 22.32 0.21 0.00427 0.00124 1167 1167 1 5 0 25.670 26.94 20.00 22.32 0.44 2.5 828.27 -5963 -7657 -6218 -10477 -12592 -12502 -12245 -6709 -7898 -7028 -9209 -7702 -4799 -4648 -1569 -1872 -1198 -1147 47 -558 -1414 -534 -373 -67 -820 -907 -1258 -2727 -1994 -1269 -11 534 397 -1763 -3740 -3314 -3249 -1879 -713 -412 -418 -410 -22 -285 271 -220 -406 -497 -827 310 851 1160 1101 1192 1248 1121 921 531 330 503 1008 1576 1954 1748 465 36 -462 -239 400 394 549 237 223 53 -339 -309 -1106 -841 -600 -593 -616 -1199 -1460 -1464 -899 -457 -77 395 489 424 316 72 -104 22 70 90 765 704 377 -150 -435 -481 -238 -389 -891 -861 -681 -439 5 13 101 -28 63 -76 85 344 365 385 89 -142 -52 228 394 407 479 281 746 576 363 228 -205 -159 -343 -157 -82 -110 266 119 -46 -215 -287 -361 -172 -233 -195 -325 -391 -380 -404 -239 -296 -279 -379 -339 -245 -288 -113 -154 -106 -109 5 -58 -152 -57 -41 -8 -106 -123 -172 -358 -248 -163 -2 86 72 -339 -687 -605 -609 -414 -190 -129 -144 -138 -8 -101 95 -78 -145 -178 -301 117 347 516 526 609 663 615 483 296 179 270 561 892 1227 1195 323 24 -292 -152 280 296 447 199 184 41 -243 -211 -705 -534 -421 -452 -536 -1099 -1434 -1513 -936 -505 -89 462 566 467 340 71 -98 21 74 102 921 949 509 -196 -555 -587 -274 -472 -1114 -1127 -936 -606 8 20 158 -45 102 -115 125 483 522 579 136 -227 -83 349 613 605 680 401 1023 834 554 362 -347 -265 -592 -286 -153 -212 521 227 -87 -407 -515 -646
SU 20250107T160514.5Z 9138.670306 219 1 29.96 2 68.51 160.34 99.26 64.11 0.00 1 0.00 1 0 17 2.705e-02 4.929e-03 2.714e-03 2.925e-04 4.376322e-01 1.461417e-04 5.307370e-03 -6.000000e+00 1.520087e-02 223.08 -2.00 3.57 -2.00 318.77 0.00e+00 5.780724e-04 3.152548e-05 1.954888e-04 -6.000000e+00 6.503959e-04 272.28 -2.00 20.00 -2.00 318.27 0.00e+00 2.705 0.000 302.00 328.00 3 1.6937e-01 3.9447e-04 3.4684e-02 -6.0000e+00 3.7530e-02 3.4039e-02 4.5186e-04 2.2509e-02 -6.0000e+00 4.0831e-02 -1.6154e-02 3.4161e-04 1.1486e-02 -6.0000e+00 2.4245e-02 -1.0988e-03 1.8479e-04 3.4804e-03 -6.0000e+00 1.0510e-02 1.8165e-02 -4.0515e-04 8.0005e-06 3.4910e-05 -6.0000e+00 7.1196e-04 4.3459e-03 0.0000e+00 11 1 0 11 16 0 99.24 22.32 0.22 0.00435 0.00130 1284 1284 1 5 0 23.330 26.94 20.00 22.32 0.63 2.5 829.21 -5634 -5013 -6605 -8508 -12898 -11560 -10001 -6368 -6080 -7343 -8144 -8465 -4815 -3676 -1614 -1159 -977 -533 -558 -15 -1342 -810 -209 -679 -597 -943 -1072 -2601 -2314 -1158 -71 788 470 -1780 -3854 -3534 -2948 -2034 -686 -587 -284 -271 -133 -269 -28 25 -592 -466 -762 211 978 1150 1198 1187 1300 1121 967 495 410 460 1018 1589 1951 1680 472 -108 -360 -256 441 373 579 243 168 106 -397 -329 -1072 -750 -513 -597 -549 -1211 -1509 -1478 -930 -454 -79 344 504 484 234 77 -86 -7 84 72 736 736 356 -131 -441 -461 -265 -427 -874 -816 -684 -446 -8 35 137 -53 55 -73 107 307 363 366 87 -97 -46 191 418 422 456 295 782 585 285 221 -178 -146 -304 -200 -100 -98 263 140 -44 -244 -287 -349 -166 -165 -213 -288 -410 -355 -329 -231 -249 -325 -368 -382 -251 -229 -118 -96 -88 -51 -57 -2 -146 -87 -23 -83 -78 -130 -148 -345 -293 -150 -10 128 86 -346 -716 -652 -603 -453 -184 -185 -98 -99 -50 -96 -10 9 -213 -181 -279 80 400 514 575 609 694 618 545 277 223 248 569 904 1229 1153 329 -71 -227 -164 310 281 472 205 139 83 -304 -225 -684 -476 -359 -455 -477 -1111 -1483 -1527 -969 -501 -91 403 584 532 252 77 -80 -7 89 81 885 990 479 -171 -562 -560 -305 -518 -1091 -1067 -939 -614 -12 53 225 -85 89 -110 156 430 517 548 133 -155 -73 293 648 625 646 420 1069 845 434 348 -299 -242 -523 -364 -184 -187 513 266 -86 -459 -514 -623
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