File name: Pandora122s1_Downsview_20250120_L2Fit_fout2c2d20240229p1-8.txt
File generation date: 20250121T091752.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 122
Spectrometer number: 1
Processing software version used: BlickP v1.8.70
Instrument operation file used: Pandora122_OF_v2d20240108.txt
Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt
Level 1 file used: Pandora122s1_Downsview_20250120_L1_smca1c2d20240229p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250120
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 1
First and last pixel inside fitting window: 234 375
Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250120T153246.7Z 9151.647763 439 1 29.99 2 69.09 150.74 88.40 255.71 0.00 1 0.00 1 0 17 4.194e-02 5.678e-03 2.009e-02 2.049e-03 4.317418e-01 1.025888e-03 5.263306e-03 -6.000000e+00 2.362033e-02 223.60 -2.00 3.57 -2.00 318.80 0.00e+00 -5.358661e-06 2.234002e-04 2.296862e-04 -6.000000e+00 1.006343e-03 271.77 -2.00 20.00 -2.00 318.31 0.00e+00 2.776 0.000 302.00 328.00 3 4.0335e+00 2.7705e-03 3.5087e-02 -6.0000e+00 5.8396e-02 -3.0357e-04 3.1750e-03 2.2362e-02 -6.0000e+00 6.3497e-02 7.6414e-03 2.4168e-03 1.1365e-02 -6.0000e+00 3.7678e-02 -9.5772e-03 1.3077e-03 3.3722e-03 -6.0000e+00 1.6323e-02 3.6550e-04 -5.0476e-04 5.6425e-05 3.4726e-05 -6.0000e+00 1.1033e-03 -1.0309e-03 0.0000e+00 10 0 0 10 0 0 99.86 22.22 0.19 -0.00103 -0.00482 31 31 1 5 0 967.230 26.83 20.00 22.22 -4.81 2.5 784.82 4815 -14615 -13656 -8867 -17468 -872 -20599 9836 -15734 3499 -18157 -2807 -3987 -6024 8738 -3546 -1688 -6771 -4896 -280 -5663 6879 -1469 -49 -682 -2115 -2490 -4726 -3881 2674 -945 1302 -2670 -813 506 -3600 -3616 -211 -1425 -1482 -531 -562 985 1589 1409 -364 -180 2091 -2023 833 -197 2039 630 970 1486 831 1024 229 -168 136 1121 899 1670 2153 292 -349 -185 -534 754 162 439 178 497 526 18 -128 -504 -500 -812 -598 -986 -1299 -1269 -1701 -656 -558 -173 -248 392 417 169 262 113 31 208 248 1172 824 277 -418 -232 -676 -308 -475 -1111 -738 -921 -256 -257 101 350 369 -75 -166 143 501 342 480 -257 36 -429 192 590 437 440 183 764 461 631 277 -249 76 -112 -49 -228 -164 25 -52 -118 -388 -153 -60 120 -487 -472 -281 -545 -23 -705 291 -662 132 -852 -123 -207 -379 568 -293 -148 -665 -500 -29 -622 673 -162 -6 -87 -286 -341 -629 -492 329 -134 202 -479 -149 87 -637 -705 -47 -380 -457 -178 -198 353 572 510 -135 -66 762 -770 321 -83 903 300 486 769 444 557 124 -90 72 608 525 1053 1445 200 -229 -117 -342 516 123 355 148 409 416 13 -88 -328 -323 -566 -465 -847 -1208 -1238 -1723 -692 -616 -197 -287 451 465 179 262 109 30 217 280 1428 1084 379 -563 -296 -814 -357 -569 -1409 -965 -1246 -357 -375 156 561 598 -119 -254 209 712 491 711 -399 57 -683 299 900 650 636 257 1049 653 951 441 -413 128 -193 -87 -422 -312 47 -101 -228 -733 -281 -108
SS 20250120T153958.6Z 9151.652762 443 1 29.79 2 68.47 152.43 89.65 256.92 0.00 1 0.00 1 0 17 8.472e-02 8.697e-03 3.996e-02 3.833e-03 4.144353e-01 1.919313e-03 5.046574e-03 -6.000000e+00 4.771649e-02 223.60 -2.00 3.57 -2.00 319.00 0.00e+00 5.219336e-04 4.407610e-04 1.676683e-04 -6.000000e+00 2.032963e-03 271.77 -2.00 20.00 -2.00 318.52 0.00e+00 2.701 0.000 302.00 328.00 3 5.1854e+00 5.2156e-03 3.3965e-02 -6.0000e+00 1.1797e-01 -7.9430e-03 6.0042e-03 2.1503e-02 -6.0000e+00 1.2827e-01 1.3458e-02 4.6621e-03 1.0961e-02 -6.0000e+00 7.6115e-02 -1.1898e-02 2.5145e-03 3.3165e-03 -6.0000e+00 3.2975e-02 1.2697e-04 -3.3296e-04 1.0712e-04 3.4254e-05 -6.0000e+00 2.2289e-03 -9.6043e-04 0.0000e+00 11 9 0 11 8 0 99.80 22.22 0.26 -0.00096 -0.00346 14 14 1 5 0 2127.450 26.83 20.00 22.22 -4.40 2.5 788.12 7703 -40971 36703 -22951 -26563 -13610 -33073 22669 -28651 -4185 -31289 8111 -18056 9940 12401 -3030 -3587 -9803 -9373 -3732 4130 13916 -3615 5074 5769 3528 -10507 -1199 -7132 8296 4485 6238 -5917 -3673 4871 -5665 -3700 5131 -6054 611 -1098 275 2414 1353 2703 -2022 -1689 1312 -1729 -1891 -535 3362 2348 1552 1134 1956 1326 468 1133 -949 2626 -326 2727 2256 712 172 -945 -1817 -842 -541 717 660 687 380 1284 -1378 -919 -469 -1332 644 -1476 -796 -2378 -2334 -1159 -217 500 -826 469 414 367 797 -266 -721 136 910 738 1246 989 -338 799 -1478 -346 -457 -1052 -1412 -1279 -146 202 712 -86 730 -274 -606 6 154 684 406 -296 -188 -534 324 319 1011 402 245 316 526 1106 -142 172 87 -178 -109 14 -392 -277 93 -194 1 -257 -117 180 -1668 774 -793 -862 -386 -1209 568 -1285 -160 -1556 301 -999 506 729 -233 -298 -922 -928 -367 386 1186 -377 528 638 418 -1428 -142 -858 890 555 852 -1006 -635 734 -936 -663 992 -1559 172 -344 90 798 455 903 -711 -591 449 -612 -695 -209 1377 1032 728 554 974 678 239 565 -478 1330 -183 1629 1449 465 107 -572 -1115 -556 -398 559 529 545 290 907 -912 -567 -287 -887 475 -1229 -717 -2282 -2325 -1208 -236 561 -955 535 457 381 775 -249 -685 138 1006 894 1628 1344 -453 1008 -1769 -395 -542 -1328 -1852 -1737 -204 298 1105 -140 1194 -442 -937 8 219 979 604 -463 -303 -860 509 492 1505 583 344 433 744 1668 -228 288 149 -311 -197 26 -763 -545 185 -385 2 -482 -212
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