File name: Pandora122s1_Downsview_20250430_L2Fit_fout2c2d20240229p1-8.txt
File generation date: 20250501T051843.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 122
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora122_OF_v3d20240108.txt
Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt
Level 1 file used: Pandora122s1_Downsview_20250430_L1_smca1c2d20240229p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250430
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 1
First and last pixel inside fitting window: 234 375
Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250430T134038.1Z 9251.569885 210 1 29.78 2 53.67 105.12 74.25 66.83 0.00 1 0.00 1 0 17 2.111e-02 9.171e-03 1.433e-02 4.865e-03 2.535414e-01 2.480218e-03 3.082615e-03 -6.000000e+00 1.217344e-02 229.52 -2.00 3.57 -2.00 317.14 0.00e+00 9.693251e-04 3.334914e-04 5.581238e-05 -6.000000e+00 5.224006e-04 279.10 -2.00 20.00 -2.00 316.50 0.00e+00 1.684 0.000 302.00 328.00 3 6.3861e+00 6.5307e-03 2.1325e-02 -6.0000e+00 3.0435e-02 1.0133e-01 7.2946e-03 1.3346e-02 -6.0000e+00 3.2895e-02 -8.2929e-03 4.3911e-03 6.5460e-03 -6.0000e+00 1.9513e-02 -1.8567e-03 2.1804e-03 1.9868e-03 -6.0000e+00 8.4151e-03 1.1952e-04 -3.1126e-04 1.3669e-04 2.0411e-05 -6.0000e+00 5.5613e-04 -1.1868e-02 0.0000e+00 11 8 0 10 0 0 99.11 22.16 0.74 -0.01187 -0.01421 8 8 1 5 0 3722.210 26.83 20.00 22.16 9.77 2.4 901.78 1482 137 2036 -8698 -6870 7254 9 1081 -6786 -421 -6704 -5826 47 -3588 6161 -873 3521 -238 23 2769 1473 4883 -690 2461 -1236 305 2544 -1909 -1184 -276 -11 1440 -1280 -2163 -5328 -1569 -5600 -473 -1809 2121 -1125 10 484 -487 454 -1044 -1586 632 117 -1398 -304 1390 823 1883 1896 559 1222 -193 1027 -86 1356 2490 2212 1742 -329 -703 -2316 -333 -124 -1514 919 461 1769 464 777 -594 -2745 -1882 -1150 -1017 -484 -1243 -824 -2407 -487 -91 806 624 753 1158 -947 -608 -1347 -1166 -432 -428 856 1156 1009 716 -177 -359 -706 -1272 -413 -622 -470 -861 -66 457 707 70 185 -138 -259 -648 -874 -82 -261 -161 1060 772 333 1087 622 -231 655 -83 330 640 -8 -263 -593 -28 -55 175 226 681 180 49 -619 -1373 175 18 268 -1191 -818 719 1 134 -1004 -62 -1024 -896 8 -688 1228 -204 824 -60 6 724 396 1256 -190 693 -378 95 775 -570 -328 -75 -3 437 -431 -752 -1775 -493 -1984 -184 -842 1092 -645 6 291 -297 273 -637 -954 365 66 -808 -183 876 546 1293 1335 404 891 -142 731 -62 987 1918 1832 1525 -290 -577 -1804 -250 -99 -1359 869 451 1705 437 683 -482 -2079 -1363 -869 -854 -445 -1243 -861 -2638 -556 -110 1004 798 960 1420 -1104 -654 -1356 -1151 -449 -482 1039 1515 1374 955 -225 -426 -810 -1525 -526 -824 -645 -1225 -97 702 1121 112 285 -200 -353 -848 -1153 -112 -377 -243 1600 1152 488 1528 843 -303 822 -107 446 906 -12 -394 -902 -45 -90 296 389 1185 315 83 -1031 -2235
SS 20250430T134615.3Z 9251.573788 213 1 30.22 2 52.70 106.30 73.35 67.64 0.00 1 0.00 1 0 17 1.075e-02 6.157e-03 7.443e-03 2.816e-03 2.444073e-01 1.437931e-03 3.019052e-03 -6.000000e+00 6.198069e-03 229.52 -2.00 3.57 -2.00 316.87 0.00e+00 4.436802e-04 1.809101e-04 1.111350e-04 -6.000000e+00 2.659844e-04 279.10 -2.00 20.00 -2.00 316.23 0.00e+00 1.646 0.000 302.00 328.00 3 5.6889e+00 3.7737e-03 2.0767e-02 -6.0000e+00 1.5496e-02 5.2098e-02 4.2060e-03 1.2902e-02 -6.0000e+00 1.6748e-02 -7.5911e-03 2.5005e-03 6.3433e-03 -6.0000e+00 9.9352e-03 -1.5720e-03 1.2260e-03 1.7968e-03 -6.0000e+00 4.2844e-03 2.5929e-04 -5.8949e-04 7.8873e-05 1.9668e-05 -6.0000e+00 2.8316e-04 -1.1619e-02 0.0000e+00 11 1 0 11 8 0 19.04 22.16 0.38 -0.01162 -0.01605 11 11 1 5 0 2746.890 26.83 20.00 22.16 9.91 2.4 903.60 -1850 -1382 950 -4600 -1365 -1267 751 -278 -3931 -2053 23 -2124 -3194 1313 321 -1851 661 808 1521 -71 686 -429 2016 202 773 383 881 -2292 333 774 2478 984 -483 -387 -2604 -1990 -1452 -1181 280 -870 -304 -312 -272 -158 -191 -115 -455 -555 -1275 723 165 1277 799 1103 1074 1030 835 913 -340 116 872 1377 1277 2080 487 -521 -1170 -1490 -409 233 282 394 582 499 410 -995 -961 -1176 -1001 -543 -1150 -920 -1103 -996 -619 -739 163 671 753 449 -112 -786 -593 -302 -375 95 527 715 884 86 -496 -813 -840 -643 -884 -1078 -495 -107 74 195 654 286 615 -65 34 -284 -95 112 245 76 245 136 483 617 244 639 546 535 258 300 -364 16 -571 -15 47 -150 323 29 -54 -293 -411 -451 -255 -207 143 -685 -175 -154 95 -40 -644 -347 4 -358 -603 269 75 -483 175 221 428 -21 204 -128 596 64 255 131 300 -757 101 229 757 326 -175 -143 -918 -682 -536 -498 137 -487 -183 -194 -173 -101 -122 -73 -285 -340 -771 431 103 841 551 790 788 767 633 688 -254 86 661 1104 1092 1853 435 -438 -930 -1163 -335 210 272 391 574 478 370 -837 -746 -881 -782 -465 -1081 -928 -1163 -1083 -707 -889 203 850 953 552 -130 -857 -604 -302 -394 107 639 929 1188 114 -627 -971 -972 -771 -1126 -1427 -673 -149 107 294 1013 445 925 -93 45 -369 -125 152 348 113 366 201 702 866 332 839 692 687 349 424 -533 24 -858 -24 75 -249 543 50 -92 -492 -674 -722
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