File name: Pandora122s1_Downsview_20250503_L2Fit_fwvt1c2d20240229p1-8.txt
File generation date: 20250504T052212.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 122
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora122_OF_v3d20240108.txt
Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt
Level 1 file used: Pandora122s1_Downsview_20250503_L1_smca1c2d20240229p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250503
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 1
First and last pixel inside fitting window: 1652 1801
Nominal wavelengths inside fitting window [nm]: 492.0395 492.1607 492.2819 492.4031 492.5242 492.6454 492.7665 492.8876 493.0087 493.1298 493.2508 493.3718 493.4929 493.6139 493.7348 493.8558 493.9768 494.0977 494.2186 494.3395 494.4604 494.5813 494.7021 494.8229 494.9438 495.0646 495.1853 495.3061 495.4268 495.5476 495.6683 495.7890 495.9097 496.0303 496.1510 496.2716 496.3922 496.5128 496.6334 496.7539 496.8745 496.9950 497.1155 497.2360 497.3565 497.4770 497.5974 497.7178 497.8382 497.9586 498.0790 498.1994 498.3197 498.4400 498.5603 498.6806 498.8009 498.9212 499.0414 499.1616 499.2818 499.4020 499.5222 499.6423 499.7625 499.8826 500.0027 500.1228 500.2428 500.3629 500.4829 500.6029 500.7229 500.8429 500.9629 501.0828 501.2028 501.3227 501.4426 501.5625 501.6823 501.8022 501.9220 502.0418 502.1616 502.2814 502.4012 502.5209 502.6406 502.7603 502.8800 502.9997 503.1194 503.2390 503.3586 503.4782 503.5978 503.7174 503.8370 503.9565 504.0760 504.1955 504.3150 504.4345 504.5539 504.6734 504.7928 504.9122 505.0316 505.1510 505.2703 505.3896 505.5090 505.6283 505.7475 505.8668 505.9861 506.1053 506.2245 506.3437 506.4629 506.5820 506.7012 506.8203 506.9394 507.0585 507.1776 507.2966 507.4157 507.5347 507.6537 507.7727 507.8917 508.0106 508.1296 508.2485 508.3674 508.4863 508.6052 508.7240 508.8428 508.9617 509.0805 509.1992 509.3180 509.4368 509.5555 509.6742 509.7929 509.9116
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250503T125632.1Z 9254.539260 224 1 30.74 2 60.84 95.84 106.83 30.47 0.00 1 0.00 1 0 15 3.676e-03 3.672e-03 1.582e-03 1.578e-03 3.157260e+03 9.801366e+01 2.219378e+02 -6.000000e+00 2.050632e+02 279.45 -2.00 20.00 -2.00 505.26 0.00e+00 7.107798e-04 4.334835e-05 3.491860e-05 -6.000000e+00 1.030234e-04 279.45 -2.00 20.00 -2.00 500.34 0.00e+00 8.611406e-02 3.178522e-02 2.486843e-02 -6.000000e+00 7.399750e-02 229.79 -2.00 3.57 -2.00 501.95 0.00e+00 2.043 0.000 489.00 513.00 1 8.1306e+00 2.4342e-03 3.6434e-03 -6.0000e+00 5.6671e-03 2.2657e-03 6.2525e-04 5.9880e-04 -6.0000e+00 1.4701e-03 4.2479e-04 3.6202e-04 1.6339e-04 2.8226e-05 -6.0000e+00 3.9214e-04 -1.1729e-02 7.3715e-06 10 0 0 10 0 0 93.13 22.08 1.71 -0.01173 -0.00922 9 9 1 4 0 3414.910 26.73 20.00 22.08 13.23 2.4 929.29 -725 -384 -490 -450 -61 90 460 253 319 -251 -160 -327 -51 153 -144 -41 151 -18 288 259 231 611 461 395 917 505 233 78 -124 -281 -326 -82 -147 -110 -93 -244 -532 -417 -152 -34 273 85 114 -216 51 272 309 -418 -20 -58 -329 -370 -81 -119 -195 466 206 -365 104 -201 203 541 217 252 241 181 -138 -114 6 -332 30 -138 -150 -19 -265 -351 -454 -170 -75 432 -146 -27 57 -162 -167 -204 -124 113 49 453 415 402 -128 265 228 160 25 132 -88 -123 -438 -162 -335 -473 -534 -974 -446 -338 -714 -321 -277 124 -261 475 681 842 746 703 1130 259 510 776 417 242 466 -74 84 90 -194 -821 129 -754 -420 -585 -415 -158 -262 -866 -256 -57 -20 235 523 2 166 126 -179 41 47 114 -723 -385 -482 -458 -63 96 477 265 334 -262 -165 -332 -54 157 -147 -41 156 -18 298 272 244 644 487 419 970 537 247 82 -128 -281 -334 -84 -147 -112 -98 -261 -568 -440 -158 -35 280 87 119 -229 54 289 328 -440 -21 -58 -324 -370 -80 -118 -190 463 210 -379 108 -209 210 559 226 262 248 184 -139 -113 6 -322 29 -132 -146 -18 -263 -347 -444 -163 -71 405 -138 -26 55 -157 -164 -201 -123 112 48 449 415 390 -127 261 223 154 25 126 -82 -113 -402 -150 -321 -452 -523 -964 -436 -326 -686 -308 -268 121 -261 475 684 848 755 713 1133 258 499 749 401 234 450 -72 82 87 -188 -800 124 -718 -393 -543 -384 -148 -249 -845 -253 -57 -20 235 525 2 168 126 -177 40 45 108
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SQ 20250503T133142.7Z 9254.563689 252 1 29.08 2 54.57 102.57 103.49 37.67 0.00 1 0.00 1 0 15 3.613e-03 3.608e-03 1.591e-03 1.587e-03 2.888403e+03 9.724038e+01 2.064154e+02 -6.000000e+00 2.015406e+02 279.45 -2.00 20.00 -2.00 505.26 0.00e+00 6.637141e-04 4.354702e-05 3.189117e-05 -6.000000e+00 1.012429e-04 279.45 -2.00 20.00 -2.00 500.35 0.00e+00 8.284491e-02 3.191971e-02 2.236404e-02 -6.000000e+00 7.269857e-02 229.79 -2.00 3.57 -2.00 501.96 0.00e+00 1.720 0.000 489.00 513.00 1 8.1461e+00 2.4456e-03 3.1588e-03 -6.0000e+00 5.5681e-03 7.7833e-04 6.3069e-04 5.4018e-04 -6.0000e+00 1.4437e-03 4.3820e-04 -4.9198e-04 1.6365e-04 2.6061e-05 -6.0000e+00 3.8544e-04 -1.1229e-02 3.4867e-05 10 0 0 10 0 0 94.44 22.08 1.76 -0.01123 -0.01464 8 8 1 4 0 3633.920 26.73 20.00 22.08 14.47 2.4 939.02 -590 -441 -227 -131 -163 -98 65 49 249 -362 156 -698 -161 177 -259 79 370 51 -59 101 208 666 683 282 948 519 265 -79 -169 -181 -535 207 200 -86 -133 -599 -333 -48 -122 212 -269 114 -165 -85 54 333 499 -112 -26 103 -487 -492 -428 -329 -12 -7 218 -193 -59 315 414 556 330 110 235 -119 -159 -99 -76 -240 -398 44 262 -13 -79 75 -353 -229 8 58 -301 -174 18 -15 -22 -14 -135 -106 -54 446 167 287 593 268 437 62 36 52 297 -270 -369 -250 -537 -470 -145 -898 -457 -355 -630 -635 -196 -98 -12 320 222 686 852 883 865 361 737 678 709 394 172 -439 166 -3 -363 -233 45 -802 -481 -448 -296 -215 -22 -603 -368 -96 -237 265 285 -8 -50 -194 -6 -82 338 278 -570 -429 -227 -135 -166 -102 69 52 265 -385 162 -723 -163 177 -258 79 371 52 -63 108 223 712 731 304 1018 559 285 -84 -177 -183 -535 205 202 -89 -142 -626 -346 -51 -129 221 -281 119 -175 -88 56 345 514 -114 -28 105 -486 -479 -411 -318 -11 -7 225 -195 -59 317 416 559 334 112 236 -118 -162 -100 -76 -236 -390 43 257 -13 -80 75 -350 -223 7 55 -289 -169 17 -15 -21 -13 -131 -102 -52 430 162 283 589 268 432 61 35 51 281 -253 -344 -236 -504 -456 -144 -901 -453 -347 -613 -620 -193 -98 -12 325 219 676 841 871 848 365 731 664 690 385 169 -435 164 -3 -358 -229 44 -774 -456 -421 -277 -203 -21 -595 -353 -93 -232 259 280 -8 -49 -191 -5 -81 323 265
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