File name: Pandora122s1_Downsview_20250510_L2Fit_fout2c2d20240229p1-8.txt
File generation date: 20250511T052138.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 122
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora122_OF_v3d20240108.txt
Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt
Level 1 file used: Pandora122s1_Downsview_20250510_L1_smca1c2d20240229p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250510
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on clearance session 1
First and last pixel inside fitting window: 234 375
Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250510T115758.8Z 9261.498597 292 1 31.52 2 70.04 84.17 124.57 286.47 0.00 1 0.00 1 0 17 1.953e-01 1.055e-02 1.309e-01 6.779e-03 4.344580e-01 3.521757e-03 5.179399e-03 -6.000000e+00 1.130940e-01 230.42 -2.00 3.57 -2.00 319.46 0.00e+00 -1.885733e-03 9.273300e-04 7.497985e-04 -6.000000e+00 4.857834e-03 280.24 -2.00 20.00 -2.00 318.84 0.00e+00 2.899 0.000 302.00 328.00 3 5.5373e+00 9.8943e-03 3.7053e-02 -6.0000e+00 2.8326e-01 6.6579e-02 1.1594e-02 2.4050e-02 -6.0000e+00 3.0582e-01 -1.0848e-02 9.2562e-03 1.1601e-02 -6.0000e+00 1.8140e-01 -3.8914e-03 4.8870e-03 3.9416e-03 -6.0000e+00 7.8213e-02 6.8420e-05 -5.0274e-04 1.9259e-04 3.4658e-05 -6.0000e+00 5.1471e-03 -1.5891e-02 0.0000e+00 12 9 8 11 8 0 99.57 22.02 0.30 -0.01589 -0.01967 8 8 1 5 0 3939.080 26.73 19.99 22.02 15.47 2.4 946.72 -58512 20661 -35839 34672 165445 -65137 23482 41375 -6423 -13361 -13152 81004 6347 23470 -21173 26266 5148 -10595 4083 -1121 19509 -4048 8186 10169 -14400 -6314 -19234 15720 -9724 9942 -2149 -4546 -5616 6589 -7528 -11401 4799 -3445 -5077 7839 -4287 5806 -1712 36 4849 1221 12804 -2405 704 -2049 1369 2243 -5810 2283 -541 1865 1120 -746 327 1024 861 2374 2820 3505 714 814 -1566 -2204 -1168 895 1172 1551 648 -1337 -54 -1363 -185 -2068 -1988 -4185 -1578 238 -2340 99 -521 355 1134 430 1021 856 286 -1503 562 -466 -985 578 1445 474 338 465 -940 -893 -263 -1365 -1102 -514 -765 -492 -349 -163 610 9 -123 427 -310 -1305 691 -121 1344 255 516 562 503 1340 -760 17 145 430 760 -493 -576 -558 -355 -367 400 510 38 -13 27 596 -596 -654 -1889 365 -1112 548 1094 -2264 395 678 -185 -445 -446 1230 220 816 -1313 1190 307 -781 278 -84 1237 -321 603 803 -1558 -669 -2336 1300 -968 831 -222 -541 -756 832 -1028 -1590 631 -577 -1053 1701 -1161 1512 -496 10 1329 349 3261 -708 203 -627 439 780 -2334 909 -232 808 502 -340 144 441 382 1123 1463 1958 415 446 -841 -1193 -680 580 826 1131 473 -950 -35 -814 -101 -1129 -1171 -2870 -1191 196 -2097 91 -511 366 1215 475 1120 907 284 -1412 489 -411 -946 608 1675 610 458 618 -1191 -1043 -289 -1568 -1354 -657 -1020 -685 -514 -257 1009 16 -205 671 -462 -1885 990 -181 2102 418 844 899 786 2010 -1118 24 198 600 1146 -806 -989 -988 -643 -692 789 1040 79 -28 56 1211 -1176 -1245
SS 20250510T131855.1Z 9261.554804 344 1 29.14 2 55.47 98.41 137.44 305.17 0.00 1 0.00 1 0 17 1.421e-02 5.877e-03 8.580e-03 2.617e-03 2.755850e-01 1.341453e-03 3.376382e-03 -6.000000e+00 8.227657e-03 230.42 -2.00 3.57 -2.00 317.34 0.00e+00 5.605342e-04 1.898510e-04 9.035387e-05 -6.000000e+00 3.533720e-04 280.25 -2.00 20.00 -2.00 316.67 0.00e+00 1.759 0.000 302.00 328.00 3 5.3779e+00 3.5513e-03 2.2759e-02 -6.0000e+00 2.0607e-02 3.7858e-02 3.9673e-03 1.4607e-02 -6.0000e+00 2.2248e-02 -9.8861e-03 2.4168e-03 7.1711e-03 -6.0000e+00 1.3197e-02 -2.4116e-03 1.2134e-03 2.0448e-03 -6.0000e+00 5.6907e-03 3.0178e-04 -4.8611e-04 7.3378e-05 2.1526e-05 -6.0000e+00 3.7438e-04 -1.6827e-02 0.0000e+00 10 0 0 10 0 0 99.54 22.03 0.26 -0.01683 -0.02048 13 13 1 5 0 2240.870 26.73 19.99 22.03 20.60 2.3 985.56 943 -2420 202 -4842 -3912 -5627 1826 306 -557 -161 -5259 -6762 -2649 -2612 529 -1731 2466 -3145 691 618 167 58 -622 2220 1126 636 -1569 624 -220 724 1343 1400 2581 -794 -1850 -1428 -3357 494 -1040 373 -601 -147 -141 -24 646 -1034 170 -1561 -1248 772 592 563 763 999 1400 951 1498 530 250 -53 877 1422 1088 2130 478 -39 -1033 -464 -65 -208 540 249 337 134 -556 -452 -1081 -779 -641 -842 -1124 -639 -1467 -1410 -1143 -553 -64 252 685 641 103 57 -743 -139 -508 -68 555 510 691 -9 -181 -197 -531 -98 -767 -770 -731 -399 330 323 543 227 108 -336 -263 214 161 486 44 -74 -153 153 447 594 477 364 431 785 -30 346 -170 77 -415 134 -138 43 70 227 10 -341 -577 -395 94 -275 23 -552 -393 -547 174 33 -68 -21 -704 -933 -394 -444 100 -368 528 -737 162 150 42 14 -158 579 312 184 -464 171 -57 183 358 403 797 -261 -575 -431 -1116 182 -457 185 -326 -82 -81 -14 371 -603 97 -885 -694 426 343 347 491 671 963 667 1063 378 176 -37 625 1073 882 1802 408 -31 -790 -347 -51 -182 503 240 323 125 -491 -367 -815 -566 -488 -708 -1036 -632 -1528 -1516 -1292 -655 -79 316 856 777 118 61 -753 -138 -532 -77 672 665 935 -12 -231 -236 -615 -117 -977 -1017 -998 -561 479 490 851 357 166 -491 -363 284 215 670 64 -112 -234 230 660 850 660 489 558 1028 -42 502 -256 117 -642 214 -229 74 121 400 18 -591 -976 -652
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