File name: Pandora243s1_Downsview_20230604_L2Fit_fwvt1c6d20230307p1-8.txt
File generation date: 20241101T223528.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v1d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt
Level 1 file used: Pandora243s1_Downsview_20230604_L1_smca1c6d20230307p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230604
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: AnaFld for Downsview
First and last pixel inside fitting window: 1621 1771
Nominal wavelengths inside fitting window [nm]: 492.0598 492.1805 492.3011 492.4217 492.5422 492.6628 492.7833 492.9039 493.0244 493.1449 493.2654 493.3858 493.5063 493.6267 493.7471 493.8675 493.9879 494.1082 494.2286 494.3489 494.4692 494.5895 494.7098 494.8300 494.9503 495.0705 495.1907 495.3109 495.4311 495.5512 495.6714 495.7915 495.9116 496.0317 496.1517 496.2718 496.3918 496.5119 496.6319 496.7518 496.8718 496.9918 497.1117 497.2316 497.3515 497.4714 497.5913 497.7111 497.8310 497.9508 498.0706 498.1904 498.3101 498.4299 498.5496 498.6693 498.7890 498.9087 499.0284 499.1480 499.2676 499.3873 499.5069 499.6264 499.7460 499.8655 499.9851 500.1046 500.2241 500.3436 500.4630 500.5825 500.7019 500.8213 500.9407 501.0601 501.1794 501.2988 501.4181 501.5374 501.6567 501.7759 501.8952 502.0144 502.1337 502.2529 502.3720 502.4912 502.6104 502.7295 502.8486 502.9677 503.0868 503.2059 503.3249 503.4440 503.5630 503.6820 503.8009 503.9199 504.0389 504.1578 504.2767 504.3956 504.5145 504.6333 504.7522 504.8710 504.9898 505.1086 505.2274 505.3461 505.4649 505.5836 505.7023 505.8210 505.9397 506.0583 506.1770 506.2956 506.4142 506.5328 506.6513 506.7699 506.8884 507.0069 507.1254 507.2439 507.3624 507.4808 507.5993 507.7177 507.8361 507.9544 508.0728 508.1912 508.3095 508.4278 508.5461 508.6644 508.7826 508.9009 509.0191 509.1373 509.2555 509.3736 509.4918 509.6099 509.7281 509.8462 509.9642
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20230604T102052.7Z 8555.431165 217 1 19.98 2 84.01 64.49 97.54 239.32 0.00 1 0.00 1 0 15 3.348e-03 3.334e-03 1.251e-04 1.250e-04 4.003834e+03 7.788405e+00 2.714215e+02 -6.000000e+00 1.888522e+02 282.90 -2.00 20.00 -2.00 505.34 0.00e+00 1.291921e-03 3.465436e-06 7.542858e-05 -6.000000e+00 9.426121e-05 282.90 -2.00 20.00 -2.00 500.78 0.00e+00 8.287332e-01 2.452856e-03 3.453103e-02 -6.000000e+00 6.695863e-02 232.17 -2.00 3.57 -2.00 502.33 0.00e+00 8.542 0.012 489.00 513.00 1 9.9902e-01 1.8794e-04 1.2560e-02 -6.0000e+00 5.1381e-03 -3.7078e-02 4.7741e-05 1.0100e-03 -6.0000e+00 1.3233e-03 2.0148e-01 5.7703e-04 1.2951e-05 4.1874e-05 -6.0000e+00 3.5709e-04 2.2354e-03 -5.7622e-05 10 0 0 10 0 0 68.64 29.12 3.46 0.00224 0.00624 559 559 1 4 0 35.740 37.25 20.00 29.12 20.70 3.8 925.50 -567 -501 -242 26 202 510 662 585 532 470 294 71 -107 -170 -243 -248 -76 45 136 128 158 288 314 347 405 337 195 76 -112 -331 -428 -360 -289 -28 -12 -70 15 56 -55 -170 -77 -39 56 207 308 341 313 175 33 -214 -446 -569 -658 -626 -396 -203 -82 73 180 315 372 395 376 374 329 245 77 -136 -209 -288 -356 -292 -319 -240 -123 -252 -382 -401 -421 -470 -558 -524 -502 -416 -282 -305 -298 -236 -179 -142 23 110 223 258 278 251 66 -165 -317 -539 -679 -597 -474 -288 -247 -285 -220 -136 -170 -129 -25 46 225 440 620 704 734 695 548 385 344 293 237 326 307 162 243 352 281 294 231 5 -121 -139 -243 -208 4 -11 9 199 237 227 301 296 184 66 -91 -313 -479 -549 -526 -525 -470 -231 25 196 501 661 583 531 465 291 70 -105 -164 -234 -241 -74 45 135 129 160 290 316 350 411 343 198 76 -112 -326 -420 -349 -286 -28 -12 -72 16 56 -55 -171 -77 -39 57 209 314 349 320 177 34 -214 -441 -551 -637 -609 -389 -203 -83 74 183 320 377 398 381 379 331 248 77 -136 -206 -284 -349 -287 -313 -238 -122 -249 -378 -390 -410 -456 -542 -507 -490 -410 -277 -303 -297 -233 -177 -141 23 110 225 262 280 249 65 -161 -306 -518 -649 -570 -460 -285 -246 -289 -222 -135 -170 -130 -25 47 230 449 636 727 755 718 566 394 352 299 240 330 312 164 247 357 285 298 233 5 -121 -137 -243 -207 4 -11 9 206 245 236 315 308 192 69 -95 -324 -488 -560 -532
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SQ 20230604T103116.3Z 8555.438383 220 1 10.00 2 82.30 66.19 99.11 240.92 0.00 1 0.00 1 0 15 2.798e-03 2.788e-03 1.228e-04 1.227e-04 3.301422e+03 7.552694e+00 2.270393e+02 -6.000000e+00 1.578379e+02 282.90 -2.00 20.00 -2.00 505.33 0.00e+00 1.061620e-03 3.398384e-06 6.231237e-05 -6.000000e+00 7.878141e-05 282.90 -2.00 20.00 -2.00 500.71 0.00e+00 6.917537e-01 2.414365e-03 2.822691e-02 -6.000000e+00 5.596374e-02 232.17 -2.00 3.57 -2.00 502.27 0.00e+00 6.942 0.006 489.00 513.00 1 5.1181e-01 1.8506e-04 1.0161e-02 -6.0000e+00 4.2944e-03 -2.8412e-02 4.7128e-05 8.2340e-04 -6.0000e+00 1.1061e-03 4.1586e-01 5.2155e-04 1.2731e-05 3.4797e-05 -6.0000e+00 2.9845e-04 3.7955e-03 -6.9090e-05 10 0 0 10 0 0 52.62 29.12 2.75 0.00380 0.00741 525 525 1 4 0 19.030 37.25 20.00 29.12 21.32 3.8 929.68 -444 -328 -177 28 169 410 547 456 443 418 232 65 -96 -116 -170 -164 -59 55 139 60 119 280 293 297 341 281 130 31 -95 -266 -334 -264 -224 -6 -17 -105 -40 61 -57 -157 -83 -42 54 162 246 251 285 139 -14 -231 -396 -475 -568 -521 -355 -205 -126 -9 145 273 324 364 299 277 275 211 51 -97 -175 -253 -287 -231 -237 -205 -129 -219 -339 -316 -300 -383 -440 -416 -420 -353 -249 -253 -264 -199 -137 -104 57 97 183 194 219 226 46 -146 -272 -405 -544 -496 -408 -301 -263 -321 -205 -113 -161 -64 -7 19 150 356 480 570 648 610 447 359 310 259 203 291 247 110 229 335 237 239 209 -5 -73 -96 -194 -159 13 -21 -45 193 232 230 278 275 162 23 -95 -285 -387 -457 -435 -416 -311 -170 28 167 409 549 458 445 421 230 65 -94 -114 -167 -161 -59 55 140 61 121 285 299 304 347 287 133 32 -96 -264 -326 -258 -223 -6 -18 -107 -41 62 -58 -158 -83 -42 55 165 254 256 294 142 -14 -230 -393 -465 -550 -507 -349 -205 -126 -9 148 277 329 368 303 282 277 213 50 -96 -172 -249 -281 -225 -234 -202 -128 -218 -333 -310 -290 -369 -426 -405 -408 -346 -244 -250 -262 -198 -136 -103 56 98 185 197 221 225 45 -142 -262 -387 -518 -476 -394 -297 -262 -324 -206 -112 -160 -64 -7 19 152 361 491 585 663 627 459 369 314 262 204 292 249 111 230 336 238 240 210 -5 -72 -94 -191 -157 13 -22 -46 196 238 238 286 285 168 24 -97 -290 -390 -457 -436
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