File name: Pandora243s1_Downsview_20230615_L2Fit_fwvt1c6d20230307p1-8.txt File generation date: 20241101T224619.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v1d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230615_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 1621 1771 Nominal wavelengths inside fitting window [nm]: 492.0598 492.1805 492.3011 492.4217 492.5422 492.6628 492.7833 492.9039 493.0244 493.1449 493.2654 493.3858 493.5063 493.6267 493.7471 493.8675 493.9879 494.1082 494.2286 494.3489 494.4692 494.5895 494.7098 494.8300 494.9503 495.0705 495.1907 495.3109 495.4311 495.5512 495.6714 495.7915 495.9116 496.0317 496.1517 496.2718 496.3918 496.5119 496.6319 496.7518 496.8718 496.9918 497.1117 497.2316 497.3515 497.4714 497.5913 497.7111 497.8310 497.9508 498.0706 498.1904 498.3101 498.4299 498.5496 498.6693 498.7890 498.9087 499.0284 499.1480 499.2676 499.3873 499.5069 499.6264 499.7460 499.8655 499.9851 500.1046 500.2241 500.3436 500.4630 500.5825 500.7019 500.8213 500.9407 501.0601 501.1794 501.2988 501.4181 501.5374 501.6567 501.7759 501.8952 502.0144 502.1337 502.2529 502.3720 502.4912 502.6104 502.7295 502.8486 502.9677 503.0868 503.2059 503.3249 503.4440 503.5630 503.6820 503.8009 503.9199 504.0389 504.1578 504.2767 504.3956 504.5145 504.6333 504.7522 504.8710 504.9898 505.1086 505.2274 505.3461 505.4649 505.5836 505.7023 505.8210 505.9397 506.0583 506.1770 506.2956 506.4142 506.5328 506.6513 506.7699 506.8884 507.0069 507.1254 507.2439 507.3624 507.4808 507.5993 507.7177 507.8361 507.9544 508.0728 508.1912 508.3095 508.4278 508.5461 508.6644 508.7826 508.9009 509.0191 509.1373 509.2555 509.3736 509.4918 509.6099 509.7281 509.8462 509.9642 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230615T100948.6Z 8566.423479 132 1 29.77 2 85.51 61.69 64.77 87.03 0.00 1 0.00 1 0 22 7.169e-03 7.122e-03 4.498e-04 4.486e-04 9.220431e+03 3.021894e+01 5.907773e+02 -6.000000e+00 4.062119e+02 284.05 -2.00 20.00 -2.00 505.40 0.00e+00 2.465426e-03 1.252485e-05 1.445355e-04 -6.000000e+00 2.024011e-04 284.05 -2.00 20.00 -2.00 501.00 0.00e+00 7.530656e-01 8.739043e-03 7.629813e-02 -6.000000e+00 1.433653e-01 232.88 -2.00 3.57 -2.00 502.51 0.00e+00 10.582 0.023 489.00 513.00 1 3.5755e+00 6.6924e-04 1.6796e-02 -6.0000e+00 1.1006e-02 -7.0778e-02 1.6806e-04 1.8987e-03 -6.0000e+00 2.8330e-03 1.1323e-02 6.1139e-04 4.5278e-05 8.2825e-05 -6.0000e+00 7.6466e-04 1.3058e-03 -2.9093e-05 12 8 8 10 0 0 75.95 28.15 9.07 0.00131 0.00555 61 61 1 4 0 487.950 36.50 20.00 28.15 20.26 3.8 921.56 -1461 -1206 -576 174 556 1011 1236 1188 1099 762 525 87 -209 -364 -658 -574 -371 94 274 375 441 649 535 675 742 788 447 286 -239 -642 -1085 -946 -703 -122 202 234 193 64 -152 -346 -184 125 161 563 755 757 710 471 150 -469 -939 -1202 -1408 -1288 -729 -318 122 396 553 700 711 910 851 829 757 383 101 -105 -462 -626 -800 -756 -625 -456 -308 -568 -765 -857 -1049 -1229 -1177 -1037 -933 -717 -667 -650 -528 -462 -441 -312 -139 143 438 585 689 500 157 -352 -750 -1274 -1415 -1246 -829 -410 -154 -358 -294 -401 -513 -470 -148 220 531 969 1264 1463 1564 1635 1248 914 648 367 412 559 683 555 603 693 501 594 375 0 -350 -470 -696 -593 -362 -47 85 432 355 390 525 487 415 175 -85 -546 -972 -1052 -1112 -1305 -1091 -523 163 521 966 1201 1141 1057 729 498 83 -198 -343 -619 -543 -355 90 268 364 431 635 526 666 737 785 446 283 -233 -624 -1043 -910 -675 -120 200 234 193 63 -150 -341 -181 124 162 560 758 765 716 472 148 -467 -915 -1173 -1364 -1255 -709 -318 122 400 561 711 724 911 858 837 761 383 102 -104 -458 -615 -781 -739 -616 -454 -309 -571 -762 -842 -1021 -1192 -1143 -1013 -919 -712 -657 -646 -527 -460 -439 -311 -140 144 438 586 696 495 152 -340 -711 -1218 -1350 -1179 -807 -405 -154 -367 -301 -409 -521 -479 -150 225 548 1006 1318 1507 1625 1713 1315 959 672 376 426 578 709 570 621 716 519 613 387 0 -355 -483 -704 -606 -376 -49 90 462 377 419 567 529 452 191 -91 -582 -1023 -1101 -1171 SQ 20230615T101905.0Z 8566.429919 135 1 29.94 2 84.02 63.22 63.13 88.52 0.00 1 0.00 1 0 22 4.696e-03 4.669e-03 5.274e-04 5.266e-04 7.893524e+03 3.510120e+01 5.183350e+02 -6.000000e+00 2.661150e+02 284.05 -2.00 20.00 -2.00 505.37 0.00e+00 1.989478e-03 1.468792e-05 1.177600e-04 -6.000000e+00 1.325968e-04 284.05 -2.00 20.00 -2.00 500.86 0.00e+00 7.713202e-01 1.033520e-02 6.265334e-02 -6.000000e+00 9.392973e-02 232.88 -2.00 3.57 -2.00 502.39 0.00e+00 8.557 0.012 489.00 513.00 1 4.1913e+00 7.9226e-04 1.3480e-02 -6.0000e+00 7.2107e-03 -5.5438e-02 1.9934e-04 1.5704e-03 -6.0000e+00 1.8563e-03 8.1620e-03 2.5486e-04 5.3547e-05 7.0644e-05 -6.0000e+00 5.0096e-04 8.4950e-03 -8.0819e-05 12 8 8 10 0 0 71.70 28.14 5.02 0.00850 0.01026 51 51 1 4 0 587.020 36.50 20.01 28.14 20.42 3.8 922.70 -859 -717 -330 136 313 716 923 829 686 614 400 90 -132 -312 -366 -370 -153 68 155 191 270 402 391 391 552 383 298 84 -183 -453 -670 -675 -423 -86 135 -40 36 88 -87 -174 -109 73 137 343 359 435 448 329 11 -308 -497 -825 -919 -791 -543 -242 117 108 327 430 460 620 499 504 390 340 162 -87 -327 -496 -499 -433 -461 -330 -175 -305 -544 -695 -593 -798 -821 -655 -686 -519 -349 -469 -321 -372 -204 -162 -87 169 303 362 375 351 150 -197 -525 -692 -1004 -814 -712 -330 -217 -274 -290 -309 -182 -196 -191 92 292 658 830 1021 1094 1120 818 578 337 451 335 377 432 275 258 441 313 454 183 87 -191 -326 -398 -417 -85 -45 56 348 206 227 344 411 169 149 -70 -271 -671 -682 -642 -791 -655 -310 129 304 695 911 827 671 608 392 87 -127 -296 -346 -353 -147 67 153 191 272 406 388 390 552 385 299 84 -183 -440 -656 -648 -413 -85 137 -41 36 89 -87 -174 -109 74 140 346 366 446 458 333 11 -309 -486 -808 -891 -771 -529 -242 117 110 334 438 469 623 504 510 393 346 163 -86 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6.0207e-05 -6.0000e+00 3.5266e-04 5.0258e-03 -8.2624e-05 10 0 0 10 0 0 45.25 28.13 3.25 0.00503 0.00963 308 308 1 4 0 97.420 36.50 20.00 28.13 20.64 3.8 924.06 -489 -416 -195 88 250 503 657 571 570 473 289 123 -116 -170 -204 -230 -92 43 133 113 137 275 286 357 410 332 190 69 -110 -322 -380 -348 -316 -41 15 -72 -22 22 -75 -192 -97 -27 14 179 313 314 296 155 -42 -256 -456 -574 -642 -609 -404 -224 -65 48 194 289 363 394 349 340 294 224 64 -143 -205 -293 -333 -319 -282 -247 -139 -240 -372 -386 -418 -458 -566 -504 -503 -410 -274 -304 -284 -289 -208 -133 -1 113 219 242 247 241 55 -160 -317 -550 -669 -581 -465 -317 -261 -315 -227 -160 -209 -106 -23 36 212 428 600 673 797 752 570 402 346 311 226 329 296 145 242 359 237 258 272 32 -115 -99 -229 -189 3 31 39 196 226 207 273 296 205 76 -60 -283 -467 -529 -496 -454 -392 -186 86 247 501 657 570 569 474 286 122 -114 -165 -197 -223 -90 43 134 114 138 279 290 364 415 337 192 70 -110 -316 -371 -341 -311 -41 16 -74 -22 22 -76 -192 -97 -27 15 182 322 321 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