File name: Pandora243s1_Downsview_20230705_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T224408.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230705_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230705T103442.8Z 8586.440774 217 1 30.29 2 82.52 65.47 80.29 224.22 0.00 1 0.00 1 0 17 7.782e-01 4.892e-02 2.720e-01 1.267e-02 8.766465e-01 7.274470e-03 9.985522e-03 -6.000000e+00 4.636440e-01 233.00 -2.00 3.57 -2.00 321.81 0.00e+00 -1.130477e-02 3.210228e-03 1.506965e-03 -6.000000e+00 2.367644e-02 285.88 -2.00 20.00 -2.00 321.22 0.00e+00 7.110 0.007 302.00 328.00 3 2.3608e+00 2.4699e-02 8.6285e-02 -6.0000e+00 1.1663e+00 1.3717e+00 3.0732e-02 5.5473e-02 -6.0000e+00 1.2731e+00 -1.8281e+00 2.1170e-02 2.3451e-02 -6.0000e+00 7.4700e-01 7.3669e-01 1.0504e-02 1.1680e-02 -6.0000e+00 3.1107e-01 1.7545e-05 -2.3345e-03 3.4053e-04 1.3463e-04 -6.0000e+00 2.2780e-02 3.2587e-03 0.0000e+00 12 9 8 11 32 0 97.36 28.52 1.92 0.00326 -0.01428 18 18 1 5 0 1682.450 36.75 19.99 28.52 31.97 3.5 1002.04 96079 445949 900000 900000 18110 79463 18002 88562 900000 97274 -59853 -67713 149713 55334 70031 128840 268251 -10290 -33212 -18919 125790 54869 34568 900000 27403 900000 900000 218767 -35685 -34603 210794 58388 189053 900000 900000 76103 -28674 900000 242578 900000 900000 900000 180588 86507 51362 5468 28435 900000 21778 83020 97349 83035 64408 -11224 122393 70017 83617 30244 168324 47630 -14108 75969 -1612 8613 12540 85646 -19449 53154 46386 76373 -414 -5233 23650 49738 1138 -22597 4886 -13333 26595 45789 -14950 -13157 12190 -9133 4564 16720 -2721 -3916 17997 8341 4881 3719 12166 -14677 6589 2537 -6542 -2550 -9957 -779 -2566 -8053 4449 -5018 -8401 -907 5237 -4357 -1914 -2288 -1507 2757 -1351 5074 -1771 -5087 3777 2420 2497 2077 1756 -4018 1067 1535 4887 7634 -4718 3750 136 1572 -3192 830 2436 -776 2814 -1291 1125 -2884 910 1993 -4268 860 -844 3661 5498 900000 900000 873 1959 868 2283 900000 2398 -6909 -8955 2517 2667 3218 3466 3307 -1119 -4392 -2057 2961 2460 1976 900000 1904 900000 900000 2697 -3200 -3180 2599 2951 2797 900000 900000 2908 -3394 900000 2991 900000 900000 900000 4453 5119 4052 654 2629 900000 2228 4913 5521 5937 5955 -2366 7092 7078 7422 4362 5603 4932 -2696 6369 -330 1763 2520 8024 -5251 7339 7720 10734 -135 -1813 5860 8646 283 -6296 982 -3370 5213 8863 -6230 -6180 4854 -4763 2211 7565 -1549 -2284 8276 4000 2251 1650 4949 -8450 3558 1679 -5548 -2399 -9920 -771 -2398 -7079 3149 -3984 -7447 -786 4538 -4528 -1986 -2748 -2036 3841 -1998 6909 -2478 -7166 4969 3396 3703 3168 2608 -6007 1463 2028 6041 9797 -6102 4813 210 2763 -6562 1774 5460 -1770 6664 -3334 2877 -7756 2322 4735 -9962 1927 -1849 SS 20230705T104423.5Z 8586.447495 220 1 30.05 2 80.92 67.05 81.45 226.05 0.00 1 0.00 1 0 17 6.097e-01 2.542e-02 1.547e-01 4.289e-03 7.477720e-01 2.333670e-03 8.960276e-03 -6.000000e+00 3.514436e-01 233.00 -2.00 3.57 -2.00 321.36 0.00e+00 5.876650e-03 1.142551e-03 4.782298e-03 -6.000000e+00 1.633164e-02 285.88 -2.00 20.00 -2.00 320.77 0.00e+00 6.006 0.004 302.00 328.00 3 2.0720e+00 8.0839e-03 7.4308e-02 -6.0000e+00 8.8542e-01 5.2379e-01 1.0635e-02 4.7561e-02 -6.0000e+00 9.5965e-01 -7.7380e-01 9.3034e-03 2.4445e-02 -6.0000e+00 5.6857e-01 3.2151e-01 4.4037e-03 7.3358e-03 -6.0000e+00 2.4038e-01 8.5503e-05 -6.9610e-04 1.1490e-04 1.3403e-04 -6.0000e+00 1.6672e-02 2.5542e-03 0.0000e+00 12 9 8 11 32 0 48.75 28.47 0.83 0.00255 -0.00268 97 97 1 5 0 309.730 36.50 19.99 28.47 32.45 3.5 1005.64 -122059 -82635 900000 900000 -162641 -152153 -163793 -45311 900000 -78874 -192463 -172373 -48891 -16376 38102 -2143 43777 -41460 -79482 -21753 38777 -10501 -52304 202951 -6097 426961 43484 -41622 -37840 -53671 -4675 28451 40449 90042 120928 61650 -27581 109196 62321 78572 26014 46822 2578 55975 51163 3024 9271 52472 17771 17103 30860 21248 25653 2166 26366 22830 26307 4668 25361 23545 6166 22084 2326 4072 8362 11873 -1571 6982 16475 14110 5188 5424 4788 7821 -506 -8343 -1056 -4361 4927 5166 -3503 -3742 687 -6016 705 -2229 -1828 -2040 2858 780 1828 -1794 -2323 -3585 -1181 -655 -1909 -1782 -3553 -902 -2352 -3695 -178 -2326 -4167 -1181 180 -1233 401 -798 -2686 868 -894 960 1298 -1174 155 370 900 1284 2981 385 532 1915 1911 1986 14 1224 1215 1496 976 356 138 -318 472 -624 378 -227 -99 64 -1438 -458 -1554 -2969 -1476 900000 900000 -5068 -4163 -5291 -482 900000 -1259 -9874 -8581 -910 -308 510 -49 695 -1664 -4851 -755 713 -307 -2405 848 -191 1785 818 -1740 -1534 -2917 -190 975 1386 1882 1719 1598 -1948 2328 2553 3153 1914 2936 260 3323 3208 312 919 3509 1768 1859 3277 2744 3442 395 3924 3617 4058 868 3679 3435 1126 3859 568 1091 2199 2933 -447 1923 4676 4695 1849 1966 1851 2710 -171 -2734 -310 -1398 1685 2116 -1664 -2029 386 -3830 449 -1552 -1324 -1508 1991 527 1138 -1095 -1405 -2356 -875 -568 -1796 -1924 -4188 -1017 -2488 -3537 -166 -2288 -4132 -1198 192 -1446 516 -1092 -4171 1372 -1440 1467 1879 -1696 227 570 1463 2139 4763 604 806 2760 2655 2887 20 1747 1996 2579 1864 730 300 -693 1096 -1529 933 -573 -245 151 -3208 -948 -3392 SS 20230705T105513.8Z 8586.455020 226 1 30.11 2 79.11 68.79 82.80 228.07 0.00 1 0.00 1 0 17 4.406e-01 1.270e-02 1.040e-01 1.903e-03 6.572819e-01 9.968107e-04 7.603459e-03 -6.000000e+00 2.534596e-01 233.00 -2.00 3.57 -2.00 320.50 0.00e+00 3.630942e-03 3.895605e-04 1.651628e-03 -6.000000e+00 1.117691e-02 285.88 -2.00 20.00 -2.00 319.82 0.00e+00 5.096 0.002 302.00 328.00 3 1.7913e+00 3.0901e-03 6.1587e-02 -6.0000e+00 6.3722e-01 1.2670e-01 3.9160e-03 3.6128e-02 -6.0000e+00 6.9005e-01 -2.1536e-01 3.5490e-03 1.8786e-02 -6.0000e+00 4.0996e-01 8.7497e-02 1.7658e-03 6.3087e-03 -6.0000e+00 1.7242e-01 3.0537e-04 -2.7465e-04 4.9801e-05 7.3351e-05 -6.0000e+00 1.1717e-02 1.0626e-03 0.0000e+00 12 9 8 11 32 0 4.21 28.41 0.70 0.00106 -0.00100 114 114 1 5 0 264.120 36.50 20.00 28.41 33.06 3.5 1009.68 -145865 -90578 254615 -54945 -176511 -156140 -157300 -107683 40108 -73513 -157230 -140121 -65623 -52416 -18987 -51589 -9972 -39918 -41834 -41557 2709 -30386 -22043 6839 -16820 20161 -4988 -33026 -37148 -23261 -21992 887 -2611 6813 -561 -28593 -14078 13917 6524 13974 2819 1580 -2233 10723 5921 991 1660 12207 4050 17569 5256 6819 6287 1021 5347 4465 4563 1339 2697 3695 1154 4380 1251 2440 1915 4278 -1179 1371 2616 3643 997 -75 1408 1278 -1252 -3443 -1399 -3057 -562 137 -1909 -2097 -1415 -2543 -797 -570 -248 69 1335 566 729 135 -441 -1281 3 -189 -388 -39 -755 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