File name: Pandora243s1_Downsview_20230707_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T082914.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230707_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230707T110214.2Z 8588.459886 234 1 31.17 2 78.12 70.01 61.29 211.52 0.00 1 0.00 1 0 17 6.195e-01 6.349e-02 2.601e-01 1.448e-02 5.807374e-01 7.873753e-03 6.702795e-03 -6.000000e+00 3.666018e-01 233.01 -2.00 3.57 -2.00 320.74 0.00e+00 -9.495544e-03 2.913098e-03 3.952182e-03 -6.000000e+00 1.757254e-02 286.06 -2.00 20.00 -2.00 320.01 0.00e+00 4.705 0.002 302.00 328.00 3 4.8473e+00 2.4176e-02 6.1706e-02 -6.0000e+00 9.2729e-01 5.3388e-01 3.0755e-02 5.2784e-02 -6.0000e+00 1.0120e+00 -9.0492e-01 2.3203e-02 1.6937e-02 -6.0000e+00 5.9215e-01 4.1681e-01 1.1035e-02 9.6565e-03 -6.0000e+00 2.4557e-01 2.1842e-05 -8.6389e-04 4.3022e-04 8.0497e-05 -6.0000e+00 1.7396e-02 6.1778e-03 1.1705e-04 12 9 8 11 32 0 84.27 28.33 1.39 0.00618 -0.00031 9 9 1 5 0 3462.400 36.50 20.00 28.33 27.40 3.6 970.23 106986 3664 900000 900000 96007 102771 -13740 23045 900000 230484 -84965 -83923 148851 52454 68032 201737 120199 102364 216103 68708 127022 900000 726 150035 11052 900000 140756 -49556 -32512 8627 78452 900000 43576 900000 900000 66589 -6061 220702 179597 142053 900000 58066 -19121 114781 50991 -884 14301 121765 5482 37506 -1316 40694 33056 -7139 81356 7774 39800 10574 91747 42467 -4823 31967 -1738 -414 -11611 28973 6390 14881 13384 36243 -3035 -7598 6027 25990 -11558 -16663 -11770 -2854 16042 20075 -12543 -10601 -2384 -1052 -554 13464 -3031 -5770 10921 7015 2717 67 18231 -8644 785 4140 -5857 -6681 -11898 -4302 -3545 -11155 13201 -2566 -7735 7518 7808 1535 -142 -4893 -11120 3670 207 6642 9721 -4154 3565 2505 4322 3432 1762 -4191 1642 3317 -741 8668 -7261 5152 9 4951 -1204 1830 1654 -753 2840 -1839 803 -3813 1570 2160 -6076 -47 686 2467 239 900000 900000 1722 1712 -810 1063 900000 3248 -12518 -12902 2479 2554 3138 2843 3542 3672 3045 3433 3417 900000 72 3652 1147 900000 4165 -7872 -3957 778 3869 900000 3623 900000 900000 3941 -829 3732 5568 7407 900000 7692 -5443 8249 6683 -189 2559 7379 1074 5603 -317 6996 6568 -2264 11121 2301 8693 3010 10990 8019 -1489 7388 -622 -158 -4942 7758 2098 4634 4734 11645 -1561 -4197 2828 9339 -5456 -7373 -4628 -1037 5403 7582 -7548 -7051 -1575 -727 -409 9202 -2555 -5098 8080 5131 1922 46 9943 -6407 593 3460 -6182 -8040 -14587 -5268 -4011 -12340 10734 -2546 -8774 7713 8439 1888 -176 -7084 -18734 5548 320 9207 13507 -5796 5139 3489 6301 5258 2723 -6647 2384 5012 -1117 11433 -10846 7129 14 7744 -2167 3364 3174 -1567 6098 -4327 1872 -9452 3654 4763 -13677 -93 1321 SS 20230707T110740.1Z 8588.463659 237 1 31.06 2 77.20 70.88 61.78 212.89 0.00 1 0.00 1 0 17 5.484e-01 4.847e-02 2.135e-01 1.060e-02 5.717872e-01 5.660338e-03 6.895849e-03 -6.000000e+00 3.183436e-01 233.01 -2.00 3.57 -2.00 320.52 0.00e+00 -4.049064e-03 1.951697e-03 3.582087e-03 -6.000000e+00 1.471730e-02 286.06 -2.00 20.00 -2.00 319.81 0.00e+00 4.390 0.002 302.00 328.00 3 4.7202e+00 1.7074e-02 5.6764e-02 -6.0000e+00 8.0358e-01 4.7084e-01 2.0781e-02 4.3184e-02 -6.0000e+00 8.7245e-01 -7.6406e-01 1.4965e-02 1.6123e-02 -6.0000e+00 5.1499e-01 3.5837e-01 7.3598e-03 6.4632e-03 -6.0000e+00 2.1674e-01 3.2784e-05 -9.3810e-04 3.0505e-04 4.7371e-05 -6.0000e+00 1.5108e-02 4.5908e-03 8.1282e-05 12 9 8 11 40 0 99.36 28.32 0.64 0.00459 -0.00246 9 9 1 5 0 3450.780 36.50 20.00 28.32 27.44 3.6 970.40 148749 24246 900000 900000 127697 88622 -13289 -14504 900000 88426 -110668 -90215 157248 47291 -11508 101727 60552 -49967 -27237 69342 74924 121111 -14762 222860 7897 179572 158974 -24866 -46566 -16092 1134 158834 49391 124176 900000 90446 -5611 181256 78455 75557 124796 34520 67297 66809 33831 3937 -4816 50472 1590 36363 -13061 24983 26645 25484 58651 9040 31597 14706 56307 30301 -4493 27820 1828 -3744 -395 24575 8536 14407 4124 16356 -4394 -6822 -342 11793 -12750 -15965 -8264 -7700 -1197 8817 -7149 -10768 -5308 -1702 -2662 5334 -4356 -6067 6199 3902 1937 -7369 9304 -6755 3627 2951 -5097 -3400 -3244 -1440 -3820 -8763 5283 -2360 -4918 464 3339 -82 -852 -1315 -6656 1365 20 3769 317 2604 2540 1574 1852 2318 2242 -307 1269 1919 27 5798 2322 2880 1539 1337 212 -209 1009 -405 1626 -1754 720 -2997 541 1291 -4570 -394 131 1676 979 900000 900000 1319 1332 -599 -736 900000 1744 -15798 -11353 1920 1999 -994 3057 2843 -7321 -3223 3438 3406 3378 -1677 2533 808 3339 3449 -3057 -6639 -1762 117 3774 3827 4490 900000 4205 -759 4494 6565 7493 8122 5706 8065 7868 5417 838 -1100 6622 345 5860 -3778 5368 6028 6213 10664 2783 7867 4223 10179 6918 -1495 7300 691 -1625 -166 7591 3025 4956 1755 7029 -2510 -4094 -187 5348 -6678 -7702 -3449 -3237 -529 4126 -4513 -7932 -3987 -1303 -2007 4348 -3719 -5379 5296 3245 1521 -5923 6075 -5367 2908 2728 -5313 -3943 -3997 -1707 -4312 -9398 5065 -2538 -5349 504 3716 -101 -1152 -1982 -11551 2271 34 5755 469 3624 3588 2359 2949 3828 3672 -499 1965 2837 39 7574 3029 3912 2368 2283 396 -411 2043 -806 3385 -3947 1609 -7047 1216 2748 -9698 -825 263 SS 20230707T111802.8Z 8588.470866 240 1 19.17 2 75.42 72.53 62.76 215.46 0.00 1 0.00 1 0 25 2.536e-01 2.206e-02 7.630e-02 6.612e-03 5.018675e-01 3.438208e-03 6.062545e-03 -6.000000e+00 1.462617e-01 233.01 -2.00 3.57 -2.00 319.91 0.00e+00 3.338337e-03 1.079055e-03 1.883362e-03 -6.000000e+00 6.803300e-03 286.06 -2.00 20.00 -2.00 319.17 0.00e+00 3.889 0.001 302.00 328.00 3 4.0690e+00 1.0068e-02 4.7276e-02 -6.0000e+00 3.6847e-01 1.5264e-01 1.2053e-02 2.8288e-02 -6.0000e+00 3.9928e-01 -1.9672e-01 9.4068e-03 1.4359e-02 -6.0000e+00 2.3659e-01 7.9750e-02 4.8075e-03 4.3517e-03 -6.0000e+00 1.0014e-01 1.1023e-04 -7.6285e-04 1.8812e-04 5.5453e-05 -6.0000e+00 6.9384e-03 6.0063e-03 3.5902e-05 12 9 9 12 33 1 89.98 28.30 0.63 0.00601 0.00027 6 14 1 5 0 2124.360 36.50 19.99 28.30 27.69 3.6 971.48 -17780 -109511 900000 900000 -85529 -37825 -58529 -95135 900000 -41551 -108611 -100951 30690 -12296 -23250 -4219 -224 11840 22117 18290 20661 -928 -17619 24304 -18997 120662 17844 -30427 -37739 -13178 2119 32994 -716 12149 22053 -34686 -3186 25816 8408 20964 23493 9943 -8877 13637 6271 -6341 986 20866 1953 7401 -581 6776 8448 7198 9539 -190 3715 792 13032 14657 -2357 6037 1884 -1261 1643 3848 -7127 1652 1276 4529 -302 -789 -320 1815 -3998 -6027 -2332 -2338 951 3348 -4607 -3045 -1315 -1502 -2016 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