File name: Pandora243s1_Downsview_20230714_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T225226.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230714_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230714T104132.7Z 8595.445517 179 1 30.82 2 82.38 67.18 51.52 89.95 0.00 1 0.00 1 0 33 1.043e+00 9.560e-02 3.897e-01 2.836e-02 9.480666e-01 1.681070e-02 1.192593e-02 -6.000000e+00 6.404139e-01 233.04 -2.00 3.57 -2.00 321.38 0.00e+00 -2.039531e-02 5.133574e-03 3.263134e-03 -6.000000e+00 3.203480e-02 286.70 -2.00 20.00 -2.00 320.63 0.00e+00 6.998 0.007 302.00 328.00 3 3.0666e+00 5.0720e-02 8.5135e-02 -6.0000e+00 1.6020e+00 1.9526e+00 6.1344e-02 5.0066e-02 -6.0000e+00 1.7411e+00 -2.1731e+00 3.8180e-02 2.8936e-02 -6.0000e+00 1.0294e+00 8.2948e-01 1.9732e-02 1.7873e-02 -6.0000e+00 4.3661e-01 6.5804e-06 -1.4598e-03 7.4342e-04 3.1529e-04 -6.0000e+00 3.0346e-02 3.2256e-03 0.0000e+00 12 9 8 11 32 0 -79.61 28.04 4.19 0.00323 -0.00774 10 10 1 5 0 3081.700 36.25 20.00 28.04 24.06 3.7 946.93 181248 187696 900000 900000 900000 900000 -18419 121313 900000 204372 -15109 -2992 228085 900000 50911 900000 114151 -13068 309339 183549 900000 900000 52796 245186 375503 178058 221113 -58580 116130 41214 265037 900000 -25300 251465 900000 -51292 126101 900000 277637 900000 900000 900000 254700 65336 73847 900000 900000 900000 2787 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2.0563e-04 1.1453e-04 -6.0000e+00 1.5496e-02 2.4699e-03 0.0000e+00 12 9 8 11 32 0 -4.76 28.04 1.03 0.00247 -0.00014 23 23 1 5 0 1302.450 36.25 20.00 28.04 24.50 3.7 950.91 -23772 11622 900000 900000 -24164 -59791 -90425 74107 64894 -39051 -148399 -83059 -11986 215061 -23985 87303 34831 -50161 126686 74135 184544 900000 -8832 81244 9656 900000 23203 -68590 18938 19752 -16332 900000 -22554 69461 900000 -47502 48172 900000 92409 369517 91456 91586 -1728 47542 23721 30145 76643 89614 28423 50512 -2659 25956 49139 7372 51278 31757 29200 15296 43807 42035 7866 16167 -2129 4868 17353 12822 1341 19336 11788 19315 -2444 -4118 34 12615 -14648 5361 -6072 -3227 -5654 19190 -1981 -3751 9063 -2364 239 5248 -1060 -1701 7612 1889 2956 -1784 -1355 -9178 -2449 825 -4875 -5677 -5333 -3021 -4461 -6031 2361 490 -6436 -2557 757 -2457 197 -1852 -2006 2479 -1647 3124 3038 -3350 1880 3919 863 -17 1477 1595 82 2955 1178 4942 -1152 1825 1270 1265 -934 229 642 974 457 -602 1232 -2040 490 800 -2727 -673 -1151 -770 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9.085072e-04 3.620415e-03 -6.000000e+00 1.185697e-02 286.70 -2.00 20.00 -2.00 320.23 0.00e+00 5.065 0.002 302.00 328.00 3 2.9487e+00 6.8077e-03 6.3941e-02 -6.0000e+00 6.6368e-01 3.0248e-01 8.8446e-03 4.2049e-02 -6.0000e+00 7.1859e-01 -4.3782e-01 7.8606e-03 2.1325e-02 -6.0000e+00 4.2739e-01 1.8316e-01 3.8106e-03 6.0673e-03 -6.0000e+00 1.8046e-01 9.0842e-05 -4.5117e-05 1.0464e-04 1.0039e-04 -6.0000e+00 1.2271e-02 2.2782e-03 0.0000e+00 12 9 8 11 32 0 -32.86 28.05 1.12 0.00228 0.00194 36 36 1 5 0 840.710 36.25 20.00 28.05 25.43 3.7 957.16 -102763 -136319 900000 134241 -115047 -129131 -165796 -63454 -45248 -103843 -212006 -143070 -65373 136071 -67332 48742 8569 -73107 -74731 61705 53275 96779 -53304 16970 -28809 -11638 -16397 -54364 -9575 -33755 -13148 40975 -28622 21641 74450 -31475 8358 104883 17015 63246 37843 28343 28398 14759 9994 11985 19732 31616 6003 13173 17502 6976 16911 3272 16342 7061 15413 3604 11660 13684 5993 9392 -1096 80 7268 4269 -176 9214 3309 6021 -436 552 -1613 2817 427 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