File name: Pandora243s1_Downsview_20230807_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T231801.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230807_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230807T150416.1Z 8619.627964 396 1 2.72 2 40.23 121.89 67.12 266.38 0.00 1 0.00 1 0 17 6.637e-03 5.412e-03 1.892e-03 1.419e-03 1.769493e-01 7.327680e-04 2.180201e-03 -6.000000e+00 3.807031e-03 232.20 -2.00 3.57 -2.00 314.55 0.00e+00 3.194979e-04 5.819540e-05 2.412365e-05 -6.000000e+00 1.693649e-04 287.28 -2.00 20.00 -2.00 313.92 0.00e+00 1.309 0.000 302.00 328.00 3 2.7347e+00 1.8872e-03 1.5973e-02 -6.0000e+00 9.5475e-03 1.1690e-02 2.0892e-03 9.4001e-03 -6.0000e+00 1.0343e-02 3.4797e-03 1.1948e-03 4.5515e-03 -6.0000e+00 6.1543e-03 -3.8094e-03 5.1690e-04 1.2610e-03 -6.0000e+00 2.5960e-03 8.0106e-03 6.2953e-05 3.9108e-05 1.6429e-05 -6.0000e+00 1.7649e-04 1.6494e-03 0.0000e+00 12 1 1 12 1 1 99.62 28.87 0.52 0.00165 0.00212 14 263 1 5 0 113.960 36.75 19.99 28.87 28.52 3.6 977.06 -82 -641 -135 -1343 -2020 -1781 -394 948 66 194 -757 -597 -5 626 462 62 68 287 694 700 600 1196 681 512 612 660 -517 185 652 402 759 1202 928 -337 -1007 -1926 -1778 -1136 -333 -588 -722 -714 -781 -858 -596 -141 -290 -744 -989 11 506 806 1006 542 684 902 395 356 558 420 677 1115 1390 1042 185 -457 -546 -163 212 509 22 180 442 302 -125 -107 -673 -409 -355 -648 -590 -1201 -1656 -1377 -874 -353 134 98 432 375 438 -77 153 124 410 181 553 464 309 -191 -509 -965 -238 -118 -384 -684 -437 -436 -72 126 514 147 343 -75 36 -115 65 192 58 -3 -168 18 -145 386 529 176 545 714 611 432 239 91 -91 157 -19 -175 125 80 -112 -220 -285 -457 -505 -34 -263 -54 -508 -729 -637 -151 381 27 81 -309 -253 -2 297 243 33 37 158 393 390 334 655 387 306 364 400 -306 104 356 219 433 693 570 -204 -591 -1113 -1103 -762 -246 -475 -597 -588 -657 -720 -496 -119 -237 -608 -786 9 408 685 864 471 604 807 358 320 491 372 625 1071 1386 1050 179 -426 -486 -147 195 498 22 190 460 310 -122 -99 -585 -351 -314 -607 -595 -1251 -1769 -1499 -994 -417 161 121 527 445 501 -84 157 128 437 202 642 576 388 -237 -608 -1097 -268 -137 -462 -844 -563 -569 -96 172 710 202 465 -96 44 -136 77 236 75 -4 -226 25 -193 497 659 214 645 853 757 552 311 117 -118 209 -27 -247 180 116 -164 -319 -401 -637 -694 SS 20230807T150851.1Z 8619.631147 399 1 31.03 2 39.54 123.22 67.91 267.19 0.00 1 0.00 1 0 17 4.463e-02 2.133e-02 9.367e-03 4.984e-03 1.816618e-01 2.533699e-03 2.165654e-03 -6.000000e+00 2.558843e-02 232.20 -2.00 3.57 -2.00 316.04 0.00e+00 1.243987e-03 2.695491e-04 7.432672e-05 -6.000000e+00 1.138616e-03 287.28 -2.00 20.00 -2.00 315.28 0.00e+00 1.295 0.000 302.00 328.00 3 7.3970e+00 6.6276e-03 1.5987e-02 -6.0000e+00 6.4173e-02 6.0472e-02 7.3940e-03 9.6663e-03 -6.0000e+00 6.9533e-02 -1.4490e-02 4.2277e-03 4.6111e-03 -6.0000e+00 4.1372e-02 5.9802e-03 1.9285e-03 1.5536e-03 -6.0000e+00 1.7443e-02 7.4461e-05 -1.0407e-04 1.4066e-04 1.5335e-05 -6.0000e+00 1.1871e-03 4.9293e-03 0.0000e+00 12 9 9 12 32 32 99.74 28.86 -0.41 0.00493 0.00415 10 10 1 5 0 3102.750 37.00 20.00 28.86 28.90 3.6 982.67 11252 -9747 27085 4887 1688 -1500 -11235 -13987 -7404 13295 5193 -9732 4182 3414 7547 11328 -6859 -6159 -5289 -4942 2906 3445 -940 2243 -6976 4997 -2655 -3583 -1811 -3058 2520 4930 -4288 -75 6757 915 -4727 3978 3213 2358 2410 148 93 2341 -2010 1981 1138 764 -1961 3909 426 2545 -444 -1551 6788 -1080 -688 739 3610 -69 -3070 635 -1352 45 -382 7 -1110 -1162 -3632 2034 -2107 1682 791 2791 -86 -5866 -6506 425 -561 -246 -1832 -3752 -811 2525 -2611 4117 172 -461 728 1361 421 -1821 -1250 -3350 -2296 2230 -1432 2299 1049 -278 611 -1816 2047 2183 -1755 181 2529 -1727 64 434 403 2412 710 1702 -72 -4481 -591 -239 948 973 1128 -1536 367 1465 605 589 -2586 -428 639 -336 -1249 -1303 2658 1249 -477 -1725 150 -2036 -41 427 -75 -236 1946 2461 -2743 5134 1026 327 -297 -2648 -3780 -2019 2947 1204 -2744 1149 1064 2502 3805 -2804 -2568 -2247 -2150 1164 1353 -396 955 -3370 2179 -1205 -1508 -700 -1196 982 1991 -2015 -33 2542 372 -2277 2067 1816 1515 1636 106 68 1663 -1485 1390 778 504 -1288 2687 291 1799 -338 -1240 5060 -883 -564 589 2747 -55 -2632 565 -1317 45 -363 6 -887 -915 -3205 1911 -2214 1748 818 2705 -79 -5077 -5128 330 -427 -210 -1761 -3996 -879 2777 -2984 4698 213 -590 915 1610 501 -2005 -1247 -3347 -2422 2470 -1818 2823 1346 -347 769 -2163 2273 2576 -2338 227 3235 -2398 92 650 627 3630 1026 2232 -96 -5892 -755 -320 1244 1360 1602 -2207 504 2059 812 749 -3226 -530 832 -467 -1666 -1764 3818 1735 -716 -2739 239 -3398 -68 677 -116 -352 2799 SS 20230807T153532.6Z 8619.649683 414 1 10.79 2 35.71 131.65 72.53 271.75 0.00 1 0.00 1 0 17 8.520e-03 5.808e-03 3.000e-03 2.115e-03 1.698538e-01 1.088641e-03 2.088891e-03 -6.000000e+00 4.887445e-03 232.20 -2.00 3.57 -2.00 314.83 0.00e+00 4.423568e-04 9.080104e-05 3.376991e-05 -6.000000e+00 2.174235e-04 287.28 -2.00 20.00 -2.00 314.17 0.00e+00 1.231 0.000 302.00 328.00 3 5.2134e+00 2.8126e-03 1.5142e-02 -6.0000e+00 1.2257e-02 3.4772e-02 3.1216e-03 9.0375e-03 -6.0000e+00 1.3278e-02 -5.4466e-04 1.7816e-03 4.3738e-03 -6.0000e+00 7.9007e-03 -3.1932e-03 7.7632e-04 1.2372e-03 -6.0000e+00 3.3330e-03 7.2871e-04 1.6511e-04 5.8510e-05 1.5641e-05 -6.0000e+00 2.2656e-04 1.1822e-03 0.0000e+00 12 1 1 12 33 1 99.98 28.82 0.71 0.00118 0.00242 16 53 1 5 0 565.100 36.75 20.01 28.82 30.96 3.5 992.95 277 -2014 249 -1837 -4133 -1977 -1167 1751 110 1301 -959 -213 -30 767 1988 1192 -590 158 945 713 979 1109 -79 533 -661 559 84 154 -488 1164 -133 2256 -149 -725 -1216 -2390 -2672 -290 -101 -448 -443 -856 -702 -49 -965 -396 -508 -72 -602 536 270 1674 926 753 862 299 384 776 343 355 88 996 1175 794 -102 297 -392 -119 349 428 37 26 51 284 -459 -159 -924 -511 -592 -173 -379 -1359 -1510 -1571 -931 -179 -133 169 488 228 585 179 106 -12 221 629 263 1006 136 -349 -565 -853 8 -63 -402 -369 -295 -682 -120 459 260 226 -41 -69 609 -435 -14 -20 214 -63 212 -168 97 520 756 94 171 320 662 236 -113 123 257 -4 232 -304 -114 -105 -139 94 -597 -94 -372 101 -784 92 -617 -1268 -589 -375 611 42 495 -360 -82 -12 339 958 608 -288 79 479 373 509 569 -42 296 -386 329 48 80 -257 599 -73 1183 -85 -403 -674 -1268 -1593 -185 -72 -362 -356 -711 -593 -41 -809 -326 -403 -58 -472 418 223 1356 790 668 775 274 355 706 308 321 78 948 1134 796 -98 270 -352 -105 315 435 39 28 54 286 -453 -148 -781 -437 -508 -166 -381 -1420 -1657 -1720 -1091 -211 -165 214 612 272 668 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