File name: Pandora243s1_Downsview_20230821_L2Fit_fout2c6d20230307p1-8.txt
File generation date: 20241101T231912.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v2d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt
Level 1 file used: Pandora243s1_Downsview_20230821_L1_smca1c6d20230307p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230821
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: AnaFld for Downsview
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230821T133449.2Z 8633.565847 161 1 29.90 2 57.74 105.20 111.37 83.49 0.00 1 0.00 1 0 17 2.945e-02 1.060e-02 7.812e-03 3.329e-03 2.307789e-01 1.685962e-03 2.805681e-03 -6.000000e+00 1.682980e-02 231.37 -2.00 3.57 -2.00 316.68 0.00e+00 -1.581970e-04 2.091868e-04 6.326387e-05 -6.000000e+00 7.502185e-04 286.98 -2.00 20.00 -2.00 315.87 0.00e+00 1.867 0.000 302.00 328.00 3 5.9751e+00 4.4402e-03 2.2048e-02 -6.0000e+00 4.2125e-02 3.4827e-02 4.9744e-03 1.2265e-02 -6.0000e+00 4.5677e-02 -3.4887e-03 2.9009e-03 5.9337e-03 -6.0000e+00 2.7192e-02 -1.2121e-03 1.3683e-03 1.6275e-03 -6.0000e+00 1.1480e-02 1.6588e-04 -2.5237e-04 9.4201e-05 1.8430e-05 -6.0000e+00 7.8305e-04 5.5924e-03 0.0000e+00 12 9 9 12 33 1 99.96 28.15 0.31 0.00559 0.00370 7 10 1 5 0 2985.010 36.25 20.00 28.15 28.38 3.5 976.65 3719 -15902 11879 -4265 7899 -8333 3799 -7404 -4210 -130 -4924 -8519 2692 6956 5425 1475 -355 -2603 -506 -3102 1335 998 165 5808 -990 7863 -4286 113 -1235 2055 -1752 6696 287 2314 2521 -5872 -4148 713 1753 635 216 -686 -976 -350 708 -411 1356 1220 -410 2391 -1403 -91 -563 -1509 1063 -911 2 843 1039 -1023 -430 1743 1412 868 939 1544 -2127 406 326 545 -1155 251 434 216 741 -3338 -962 -1104 1431 -122 -2745 -2171 -1936 -87 -1397 1149 606 359 1010 1175 -223 -743 1399 -1474 5 1208 1048 106 -53 -647 -864 -840 777 -163 -523 -248 153 -1057 328 211 -283 994 610 706 168 -362 -73 -403 495 197 650 -519 304 -8 -105 111 -1219 438 148 647 12 -485 1037 -150 -10 207 -920 294 -302 330 -202 -550 201 602 -3298 1832 -691 1020 -1271 564 -1389 -835 -25 -973 -1850 591 1662 1474 403 -101 -787 -155 -1007 415 309 54 1890 -361 2689 -1602 37 -387 691 -593 2239 110 847 852 -2211 -1731 336 980 374 136 -450 -656 -233 465 -270 851 745 -249 1436 -934 -63 -416 -1176 825 -735 1 668 805 -813 -355 1407 1234 796 825 1225 -1774 328 267 505 -1169 258 439 209 654 -2740 -760 -846 1152 -104 -2678 -2301 -2001 -93 -1627 1394 724 440 1220 1438 -254 -832 1406 -1508 5 1327 1279 135 -70 -823 -1098 -983 865 -195 -680 -315 203 -1475 475 305 -429 1477 923 982 215 -475 -96 -525 689 293 973 -773 438 -11 -137 148 -1559 561 204 880 17 -710 1520 -233 -15 334 -1534 495 -512 541 -321 -846 303
SS 20230821T133937.7Z 8633.569187 164 1 30.03 2 56.91 106.18 110.55 84.34 0.00 1 0.00 1 0 17 7.223e-03 5.064e-03 5.994e-04 3.706e-04 2.261547e-01 1.891804e-04 2.765470e-03 -6.000000e+00 4.129432e-03 231.37 -2.00 3.57 -2.00 315.52 0.00e+00 2.582468e-04 1.811027e-05 2.780338e-05 -6.000000e+00 1.840488e-04 286.98 -2.00 20.00 -2.00 314.79 0.00e+00 1.825 0.000 302.00 328.00 3 2.4055e+00 4.9104e-04 2.1547e-02 -6.0000e+00 1.0336e-02 1.1248e-03 5.4681e-04 1.1961e-02 -6.0000e+00 1.1206e-02 -1.2281e-03 3.1212e-04 5.7890e-03 -6.0000e+00 6.6713e-03 -1.6475e-03 1.3932e-04 1.5894e-03 -6.0000e+00 2.8174e-03 6.2580e-03 3.4834e-05 1.0291e-05 1.9601e-05 -6.0000e+00 1.9206e-04 3.6757e-03 0.0000e+00 10 0 0 10 0 0 99.86 28.15 0.45 0.00368 0.00394 331 331 1 5 0 90.720 36.25 20.00 28.15 28.71 3.5 979.22 -782 -1045 -696 -2323 -2529 -2245 -332 394 223 -812 -1376 -1085 -383 319 719 256 398 686 785 1177 938 771 645 755 449 592 269 70 78 126 953 1468 712 -667 -1813 -2214 -1536 -606 -338 -406 -578 -550 -507 -317 -348 -243 -424 -493 -605 218 534 712 855 639 629 650 467 448 463 412 634 1035 1469 933 323 -340 -592 -133 365 340 227 123 259 -5 -258 -463 -508 -516 -387 -462 -762 -1241 -1595 -1472 -986 -286 -21 132 331 417 301 207 173 235 246 298 505 488 150 -289 -517 -652 -325 -275 -523 -519 -505 -461 82 236 329 260 240 64 6 30 87 99 85 -113 -34 17 103 356 491 318 557 741 577 471 124 36 4 -10 39 -67 58 -3 -170 -154 -349 -383 -533 -225 -297 -207 -628 -618 -590 -87 116 67 -249 -414 -345 -128 121 286 109 173 292 346 533 426 349 303 355 221 299 132 34 35 57 458 714 374 -347 -883 -1109 -819 -362 -220 -287 -419 -412 -388 -242 -265 -183 -312 -366 -441 160 401 545 687 519 521 549 400 379 384 344 554 939 1384 891 298 -307 -501 -115 334 329 229 123 265 -5 -241 -414 -429 -438 -341 -428 -763 -1280 -1685 -1634 -1108 -341 -26 164 407 500 341 227 180 240 262 340 603 606 193 -362 -620 -764 -367 -321 -647 -655 -648 -617 111 334 473 371 335 86 8 38 109 127 115 -159 -47 24 140 473 636 403 690 935 739 625 168 50 6 -14 58 -102 89 -5 -265 -234 -524 -569 -782
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