File name: Pandora243s1_Downsview_20230825_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T065022.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230825_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230825T134815.4Z 8637.575178 175 1 29.55 2 56.21 109.35 153.24 59.74 0.00 1 0.00 1 0 17 6.969e-02 2.574e-02 1.854e-02 7.110e-03 2.371299e-01 3.593097e-03 2.891248e-03 -6.000000e+00 3.972808e-02 231.00 -2.00 3.57 -2.00 316.99 0.00e+00 -1.840301e-03 4.701812e-04 4.772712e-04 -6.000000e+00 1.772932e-03 286.64 -2.00 20.00 -2.00 316.14 0.00e+00 1.793 0.000 302.00 328.00 3 6.9611e+00 9.4778e-03 2.1710e-02 -6.0000e+00 9.9355e-02 1.0311e-01 1.0646e-02 1.3208e-02 -6.0000e+00 1.0781e-01 -4.1520e-02 6.2519e-03 6.0480e-03 -6.0000e+00 6.4183e-02 2.0807e-02 2.9798e-03 2.5413e-03 -6.0000e+00 2.7102e-02 6.4752e-05 -1.2027e-03 2.0478e-04 2.4236e-05 -6.0000e+00 1.8537e-03 1.0491e-02 -2.9846e-04 12 9 8 11 32 0 99.70 27.75 -0.56 0.01049 0.00145 9 9 1 5 0 3282.910 36.00 19.99 27.75 30.15 3.5 988.15 13209 5716 46652 6787 12777 -17802 12658 -23308 -18511 -1465 -3851 -10570 5130 7783 2600 -1051 -13204 -1399 296 261 4973 -8490 7867 22260 -6503 3580 -2285 5404 -4725 -13777 1232 7787 8408 10629 7605 -7752 -9551 7339 4147 8809 328 1598 -3829 433 399 4233 4821 315 -1715 4409 -5388 -150 -3154 -1936 1620 -1153 256 2404 1238 -6747 -60 6180 1736 -1771 1273 1716 -6794 901 -1622 3331 -1797 1822 1981 3144 -2840 -6732 -7594 496 1421 894 -5327 -3654 -480 -488 -1862 5922 791 -2546 2242 876 -932 -2387 4954 -3620 159 1352 -2901 818 -245 -789 -810 1033 3116 1438 -1590 678 1222 -1195 1689 -353 1318 2221 -1837 2893 268 -1118 2865 2910 1194 -230 173 -787 -944 -124 961 -1548 -4890 -1370 487 718 -1134 -372 -348 -763 -1874 -574 -661 -1810 229 2816 -367 1963 1080 1850 896 4691 899 1444 -2777 1615 -4832 -3979 -267 -702 -2184 1014 1684 656 -289 -4184 -407 87 79 1428 -2779 2291 5973 -2440 1239 -803 1604 -1448 -4652 380 2408 2752 3294 2252 -2758 -3914 3023 2111 4844 208 1030 -2404 284 259 2610 2855 189 -1026 2531 -3639 -102 -2324 -1339 1214 -825 183 1815 925 -4968 -47 4499 1422 -1562 1039 1265 -5110 688 -1272 2805 -1708 1713 1830 2733 -2399 -5267 -5998 350 1072 765 -4909 -3614 -484 -517 -2153 6752 994 -3379 2807 1051 -1042 -2461 4795 -3439 157 1449 -3595 1072 -335 -1045 -996 1148 3279 1634 -2020 881 1650 -1724 2487 -563 2156 3579 -2925 4047 352 -1413 3514 3753 1687 -349 264 -1195 -1395 -173 1256 -1969 -6119 -1686 630 984 -1651 -547 -521 -1193 -3150 -994 -1171 -3038 411 4764 -618 3110 1695 SS 20230825T135330.4Z 8637.578824 178 1 29.83 2 55.32 110.48 152.46 61.48 0.00 1 0.00 1 0 17 3.359e-02 1.467e-02 1.008e-02 4.215e-03 2.269518e-01 2.130469e-03 2.722264e-03 -6.000000e+00 1.917995e-02 231.00 -2.00 3.57 -2.00 316.74 0.00e+00 -4.949289e-04 2.663177e-04 4.692060e-05 -6.000000e+00 8.545604e-04 286.64 -2.00 20.00 -2.00 315.93 0.00e+00 1.752 0.000 302.00 328.00 3 6.3564e+00 5.6053e-03 2.0955e-02 -6.0000e+00 4.7969e-02 6.4810e-02 6.2823e-03 1.1938e-02 -6.0000e+00 5.2023e-02 -1.4675e-02 3.6526e-03 5.7862e-03 -6.0000e+00 3.0973e-02 5.6538e-03 1.7320e-03 1.6279e-03 -6.0000e+00 1.3096e-02 1.2594e-04 -8.1952e-05 1.1962e-04 1.7994e-05 -6.0000e+00 8.9335e-04 8.3412e-03 1.5175e-05 12 9 8 11 32 0 99.88 27.75 -0.08 0.00834 0.00773 9 9 1 5 0 3314.410 36.00 20.00 27.75 30.35 3.5 989.19 4698 518 16145 -34 11158 -7977 4047 -13300 -5076 -7568 -7753 -7095 5352 1500 2193 -4418 -6872 1102 -1831 -1976 2657 -3053 2360 8172 2198 1721 -340 526 -2069 -7183 -540 3589 3782 5217 1950 -6958 -6895 4424 1809 3831 13 717 -3099 -58 595 3169 218 1292 -1573 3239 680 -696 -1403 -1002 1989 -1218 -266 2708 1758 -2766 350 2842 1040 -686 1262 1570 -4418 748 -1401 2051 -325 1478 -232 1082 -2546 -2849 -2588 -70 -156 1617 -4290 -2639 -864 397 -298 2739 -806 -542 1240 473 -374 -487 2799 -2749 147 1046 -1181 1008 -4 -365 -658 334 -583 563 -577 597 767 -927 923 -403 -838 727 -589 1861 414 -2622 -563 943 910 -582 706 -479 667 156 289 335 -450 -97 -360 1078 -504 71 2923 -558 -637 -352 -94 -973 398 903 -103 -1242 -154 745 90 2329 -5 1358 -1184 586 -2586 -989 -1524 -1526 -1470 1102 363 588 -1338 -2181 334 -589 -656 841 -1017 775 2680 800 644 -125 176 -666 -2451 -183 1253 1407 1864 666 -2663 -2973 2020 922 2170 8 459 -2101 -38 385 1975 136 770 -942 1881 431 -475 -1015 -753 1482 -955 -209 2034 1306 -2157 277 2364 950 -608 1147 1289 -3599 574 -1207 1767 -308 1415 -223 977 -2388 -2390 -1968 -50 -120 1382 -3972 -2624 -888 424 -345 3279 -1048 -719 1603 584 -427 -505 2806 -2876 147 1143 -1463 1342 -5 -491 -828 383 -651 659 -742 795 1065 -1260 1293 -608 -1322 1123 -875 2485 556 -3439 -731 1267 1319 -840 1021 -689 922 224 392 432 -555 -121 -482 1513 -750 99 4349 -826 -1004 -579 -158 -1684 680 1489 -166 -1948 -234 SS 20230825T140325.6Z 8637.585713 181 1 8.09 2 53.66 112.67 150.96 64.57 0.00 1 0.00 1 0 17 8.387e-03 5.611e-03 4.292e-03 2.561e-03 2.125354e-01 1.303581e-03 2.586927e-03 -6.000000e+00 4.789790e-03 231.00 -2.00 3.57 -2.00 315.60 0.00e+00 1.450953e-04 1.270821e-04 3.281825e-05 -6.000000e+00 2.133862e-04 286.64 -2.00 20.00 -2.00 314.87 0.00e+00 1.683 0.000 302.00 328.00 3 4.3329e+00 3.3829e-03 1.9966e-02 -6.0000e+00 1.1979e-02 2.5586e-02 3.7684e-03 1.1193e-02 -6.0000e+00 1.2991e-02 -1.1684e-03 2.1576e-03 5.4282e-03 -6.0000e+00 7.7345e-03 -1.3829e-03 9.7192e-04 1.4907e-03 -6.0000e+00 3.2706e-03 1.0575e-03 1.7430e-04 7.1248e-05 1.8247e-05 -6.0000e+00 2.2304e-04 8.6763e-03 6.9552e-05 12 1 1 12 33 1 99.97 27.73 0.47 0.00868 0.00999 7 37 1 5 0 803.460 36.00 20.00 27.73 30.77 3.4 991.51 382 -126 -131 -1342 -1882 -2266 -221 303 83 -2329 -1424 -3128 26 2551 223 630 -161 1152 109 911 986 -528 787 1171 465 1034 -130 -414 -600 -727 68 1948 202 -190 -1496 -3296 -2294 389 631 611 -1040 -528 -803 141 -709 -49 -323 277 -417 568 502 3 273 451 349 421 491 933 821 555 358 925 1596 882 3 -124 -1165 -95 -108 516 144 328 338 -3 67 -569 -470 -256 -429 -100 -1106 -1465 -1695 -1505 -746 -97 -410 130 544 472 134 -272 604 178 -298 499 751 949 504 -305 -475 -423 -24 -195 -476 -325 -501 -651 -36 51 523 423 -86 -137 77 -20 290 23 29 -236 -85 -22 83 484 660 55 335 553 462 335 -40 -199 39 199 -140 -10 143 -172 49 28 -595 -247 -247 99 -34 -35 -322 -447 -543 -57 80 24 -691 -408 -965 9 875 87 260 -68 499 49 391 422 -228 348 545 227 514 -63 -185 -271 -332 30 914 103 -95 -699 -1606 -1247 228 412 425 -782 -408 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