File name: Pandora243s1_Downsview_20230901_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T234757.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230901_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230901T113251.5Z 8644.481151 232 1 30.31 2 81.62 86.55 81.64 257.07 0.00 1 0.00 1 0 25 5.244e-01 4.769e-02 2.150e-01 1.197e-02 7.271594e-01 6.590004e-03 8.286539e-03 -6.000000e+00 3.032750e-01 230.36 -2.00 3.57 -2.00 321.36 0.00e+00 -2.196833e-02 2.975125e-03 8.490688e-03 -6.000000e+00 1.559819e-02 286.06 -2.00 20.00 -2.00 320.70 0.00e+00 6.444 0.005 302.00 328.00 3 3.2194e+00 2.2574e-02 1.0004e-01 -6.0000e+00 7.5752e-01 7.4493e-01 2.8759e-02 1.0875e-01 -6.0000e+00 8.2612e-01 -1.1348e+00 2.0929e-02 2.2055e-02 -6.0000e+00 4.8793e-01 4.8828e-01 9.9855e-03 2.4572e-02 -6.0000e+00 2.0608e-01 1.9633e-05 -6.6623e-04 3.3879e-04 1.8634e-04 -6.0000e+00 1.4597e-02 5.0138e-03 0.0000e+00 12 9 8 11 32 0 -54.69 27.92 2.05 0.00501 0.00001 15 15 1 5 0 2020.090 36.25 20.00 27.92 22.11 3.6 932.04 -27476 -37569 900000 900000 900000 84639 -29631 -8773 -53165 900000 68463 -108126 199945 87063 48253 81450 -408 64727 20177 -4947 52246 -46258 338075 900000 -6746 900000 51660 97726 7306 -79739 34679 900000 82908 5156 900000 -17411 -39174 117461 21945 189921 54416 36577 -10806 51264 -13760 77958 43673 88271 60705 34113 76992 75054 8748 16393 66129 46192 22918 45458 40284 8603 -19477 60193 -7372 17892 25497 53856 -3457 4074 22323 17015 -9442 17459 1281 28253 6409 -10829 16271 6394 -523 26911 -10115 2493 6681 6997 -2348 17809 -12784 -7197 2485 3181 1646 -2091 -3006 -8772 -5473 -4478 -7182 -2036 -2788 -6977 -4321 386 -4705 4780 -4434 -3726 -81 -3909 1688 -3726 -1485 -1108 -3201 7666 2579 -2574 5235 6094 1723 -285 246 2675 528 2356 7843 1771 -3196 5435 -1644 3203 -534 1370 3027 284 -1856 -1693 993 -1376 29 -1097 -5605 2673 1156 -1281 -1911 900000 900000 900000 987 -1162 -335 -3606 900000 1451 -13981 2331 1845 1636 2072 -24 1989 962 -299 1717 -4069 3941 900000 -586 900000 2590 2620 426 -10141 1698 900000 2996 397 900000 -1563 -4978 3834 2328 4428 5329 4349 -2003 4781 -2310 4999 3819 4940 4600 3619 5924 6475 1591 3001 7863 7108 4569 6995 6058 1665 -4995 7508 -2011 4130 5469 8350 -955 1107 5751 5296 -4139 5984 499 7773 1958 -3497 3794 1700 -169 7812 -4941 1224 3419 3801 -1505 9903 -10045 -5420 1669 2006 981 -1228 -1762 -5829 -4013 -3754 -7117 -1979 -2905 -7416 -4564 350 -4202 4051 -4467 -3923 -87 -4292 1947 -5138 -2223 -1743 -5153 10708 3599 -3667 7030 8532 2671 -463 390 3966 776 3284 9983 2312 -4281 7171 -2660 5561 -1054 2829 6492 614 -4401 -4188 2430 -3490 72 -2581 -12862 5768 2468 SS 20230901T114727.4Z 8644.491289 237 1 29.72 2 78.98 89.07 84.09 259.64 0.00 1 0.00 1 0 17 3.276e-01 1.310e-02 1.013e-01 2.745e-03 6.069858e-01 1.414675e-03 7.032741e-03 -6.000000e+00 1.865870e-01 230.36 -2.00 3.57 -2.00 320.35 0.00e+00 -5.456964e-04 5.270685e-04 1.179251e-03 -6.000000e+00 8.315359e-03 286.06 -2.00 20.00 -2.00 319.65 0.00e+00 5.044 0.002 302.00 328.00 3 2.5322e+00 4.3163e-03 5.9301e-02 -6.0000e+00 4.6601e-01 1.4155e-01 5.4003e-03 3.3491e-02 -6.0000e+00 5.0577e-01 -1.9665e-01 4.7198e-03 1.6123e-02 -6.0000e+00 3.0118e-01 8.1467e-02 2.3707e-03 4.4865e-03 -6.0000e+00 1.2733e-01 1.6197e-04 -4.7376e-04 7.3817e-05 4.7394e-05 -6.0000e+00 8.7104e-03 4.9399e-03 0.0000e+00 12 9 8 11 40 0 -6.84 27.92 0.85 0.00494 0.00138 50 50 1 5 0 594.250 36.25 20.00 27.92 23.32 3.6 941.16 -116534 -115180 107785 -113952 -41185 -74114 -101794 -96451 -110222 -130845 -50381 -124054 -17126 -46506 -29899 -32632 -36772 -8674 -10308 -25479 -5411 -37872 24181 46656 -38517 57544 -4607 -3758 -4098 -35892 -20603 18808 3028 1282 36364 -15870 10704 6347 3445 21002 6056 4139 -866 5944 -3139 2859 2578 7560 4663 4647 -3749 6495 2392 2282 3331 4555 3822 3274 3764 -813 -1261 7894 641 4584 4477 1809 -526 2494 1822 1774 -222 2296 -398 1030 953 -4667 -2643 -787 -2340 689 -2984 -1448 -876 -1321 -1761 779 26 -431 755 355 407 86 1191 -1313 -1431 -880 -1048 247 -774 -849 -1633 -631 877 239 -1715 -1019 -733 -900 54 30 292 491 -317 1360 120 -662 552 845 -98 -58 905 10 104 382 1364 235 325 1228 463 743 222 126 453 -92 -252 -254 34 -157 -164 -229 -896 -198 -130 -2127 -2299 289 -2319 -375 -972 -1990 -2066 -3040 -4694 -850 -5115 -303 -1370 -905 -1162 -1496 -290 -373 -1119 -196 -1916 712 1212 -2527 1510 -222 -170 -184 -2460 -1434 1027 219 95 1801 -1372 814 613 422 2536 932 687 -156 1011 -589 513 470 1350 894 963 -860 1489 623 643 977 1376 1189 1007 1116 -250 -411 2613 258 1955 1930 769 -228 1098 915 937 -129 1341 -233 555 464 -2362 -1246 -377 -1195 403 -2097 -1045 -677 -1087 -1566 719 25 -429 736 330 351 70 925 -1100 -1359 -890 -1222 300 -1009 -1079 -1937 -714 917 262 -2077 -1202 -913 -1204 73 46 456 793 -508 2176 182 -981 824 1326 -155 -95 1447 17 166 586 1987 333 477 1780 763 1278 393 236 885 -182 -533 -533 72 -341 -353 -496 -1846 -404 -260 SS 20230901T115244.3Z 8644.494957 240 1 30.16 2 78.03 89.98 84.98 260.56 0.00 1 0.00 1 0 17 2.580e-01 1.058e-02 3.654e-02 2.133e-03 5.660602e-01 1.088793e-03 6.579033e-03 -6.000000e+00 1.469428e-01 230.36 -2.00 3.57 -2.00 319.99 0.00e+00 8.536929e-04 3.630314e-04 8.310808e-04 -6.000000e+00 6.548599e-03 286.06 -2.00 20.00 -2.00 319.27 0.00e+00 4.674 0.002 302.00 328.00 3 2.5151e+00 3.2196e-03 5.4839e-02 -6.0000e+00 3.6700e-01 8.9481e-02 3.9288e-03 3.0453e-02 -6.0000e+00 3.9831e-01 -1.1343e-01 3.3196e-03 1.4917e-02 -6.0000e+00 2.3719e-01 4.4350e-02 1.7014e-03 4.1495e-03 -6.0000e+00 1.0027e-01 2.4248e-04 -2.7431e-04 5.7813e-05 4.6159e-05 -6.0000e+00 6.8597e-03 4.9578e-03 0.0000e+00 12 9 8 11 32 0 19.52 27.93 0.64 0.00496 0.00290 62 62 1 5 0 486.430 36.25 20.00 27.93 23.69 3.6 943.19 -93374 -107343 -27276 -80999 -71531 -84991 -88639 -95858 -71561 -103813 -47361 -93617 -25976 3891 -18554 -19769 -31401 -10029 -8483 -12314 -10182 -24536 8859 23946 -16233 15687 -5346 2796 -12906 -20428 -17579 10016 5220 -1439 16115 -8017 -17877 5366 -1079 10147 3238 887 -1394 3835 -118 1896 2267 5230 5156 3648 -896 4240 2535 797 2645 2826 2010 3318 1775 -437 -771 4516 851 3462 3135 3016 -200 -177 1300 1032 707 1737 -543 953 8 -3175 -2848 -494 -891 373 -2029 -1648 -885 -2060 -1781 543 -1040 -335 518 599 398 27 812 -494 -259 -502 -543 39 -81 -833 -1163 -770 104 -637 -1025 -661 -306 -378 224 177 245 335 94 425 727 -599 325 397 -223 68 614 133 163 577 577 198 255 950 214 766 182 392 480 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