File name: Pandora243s1_Downsview_20230907_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T234641.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230907_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230907T114539.9Z 8650.490046 269 1 29.68 2 80.47 90.73 16.84 190.23 0.00 1 0.00 1 0 25 3.225e-01 2.806e-02 1.391e-01 5.932e-03 6.626973e-01 3.174624e-03 7.977802e-03 -6.000000e+00 1.866154e-01 229.80 -2.00 3.57 -2.00 321.07 0.00e+00 -2.591537e-03 1.411693e-03 5.064375e-03 -6.000000e+00 8.924781e-03 285.55 -2.00 20.00 -2.00 320.43 0.00e+00 5.751 0.004 302.00 328.00 3 2.9980e+00 1.0540e-02 7.2474e-02 -6.0000e+00 4.6566e-01 4.0674e-01 1.3663e-02 5.4407e-02 -6.0000e+00 5.0771e-01 -5.9909e-01 1.1606e-02 2.0441e-02 -6.0000e+00 2.9985e-01 2.4906e-01 5.5774e-03 6.6423e-03 -6.0000e+00 1.2620e-01 4.9326e-05 -1.6297e-04 1.6627e-04 6.4185e-05 -6.0000e+00 8.8902e-03 3.2656e-03 0.0000e+00 12 9 8 11 40 0 40.25 28.29 0.68 0.00327 0.00204 30 30 1 5 0 989.310 36.50 20.00 28.29 29.12 3.4 979.13 -36508 -118218 900000 900000 64377 900000 -130196 2176 -27188 -160361 -143692 -49834 -45284 -1290 29361 -9215 -47360 -32790 54766 -24826 -22707 -23296 50359 62078 -36102 900000 -62951 1442 -33840 -70146 -33320 900000 37328 21236 900000 -19228 -25277 53465 12305 43532 26593 15189 45372 7475 1782 6455 19122 54355 6187 5143 33237 27852 13281 861 14065 13753 9828 20201 10652 14124 -202 15407 -3821 9780 14950 15513 -4724 3406 4711 7245 -3177 10086 4431 16141 -5192 -6770 -5408 4908 1799 139 -9349 -5788 1627 -3220 5340 5050 -6234 -1998 1985 -728 231 -3244 6250 -2059 -2864 -3686 -4436 64 -1808 -2864 -3815 -834 158 2411 -4826 -4138 -1827 -1520 -303 176 593 978 -2220 2326 2126 -1319 2556 902 564 559 584 -74 -536 2130 4008 2048 -770 2643 -234 3272 691 522 296 638 -779 -219 -389 -1210 -420 -446 -1614 450 -220 -499 -3913 900000 900000 372 900000 -4309 22 -400 -9267 -7247 -1126 -1189 -29 577 -298 -2408 -1535 1108 -1133 -997 -1023 1135 1363 -2253 900000 -5093 57 -1838 -5999 -2311 900000 1639 1092 900000 -1411 -2235 2595 1102 3321 2612 1747 3933 937 235 813 2133 4366 837 758 4129 4024 2410 191 2861 2917 2204 3981 2210 2775 -48 3455 -1175 2888 4233 4204 -1567 1094 1693 2905 -1387 4336 1951 5876 -2103 -2500 -1878 1602 698 65 -5068 -3430 967 -2130 3482 3507 -5060 -1583 1492 -533 155 -2134 3658 -1391 -2225 -3348 -4691 67 -2063 -3226 -4014 -835 147 2277 -5302 -4750 -1995 -1783 -389 253 934 1478 -3439 3578 3098 -1929 3676 1390 928 875 971 -120 -840 3132 5568 2797 -1056 3751 -389 5432 1284 1030 616 1308 -1739 -508 -921 -2929 -998 -1007 -3461 959 -461 SS 20230907T115404.4Z 8650.495884 274 1 30.01 2 78.95 92.20 17.17 196.37 0.00 1 0.00 1 0 25 2.909e-01 1.004e-02 3.357e-02 1.698e-03 5.962457e-01 8.700290e-04 6.925305e-03 -6.000000e+00 1.653297e-01 229.80 -2.00 3.57 -2.00 320.24 0.00e+00 1.747927e-03 3.130988e-04 1.005361e-03 -6.000000e+00 7.366650e-03 285.55 -2.00 20.00 -2.00 319.54 0.00e+00 5.030 0.002 302.00 328.00 3 1.7295e+00 2.6275e-03 5.8607e-02 -6.0000e+00 4.1244e-01 8.7080e-02 3.2640e-03 3.2156e-02 -6.0000e+00 4.4782e-01 -1.5192e-01 2.8564e-03 1.6147e-02 -6.0000e+00 2.6671e-01 6.1552e-02 1.4492e-03 4.8014e-03 -6.0000e+00 1.1286e-01 3.7817e-04 -3.8510e-04 4.5450e-05 5.3923e-05 -6.0000e+00 7.7307e-03 3.5633e-03 0.0000e+00 12 8 8 10 0 0 66.26 28.27 0.61 0.00356 0.00067 167 167 1 5 0 179.700 36.50 19.99 28.27 29.37 3.5 981.41 -102547 -106860 -52472 -58901 -118726 -87484 -107769 -81889 -60197 -102308 -100947 -110809 -53811 -34139 -18322 -27944 -26050 -20530 -220 -4174 -15387 -25466 -9978 -2542 -12628 9195 -15919 -13828 -18509 -22813 -23712 14841 6638 -5042 7601 -9093 -8634 1415 68 7448 3448 -173 -3560 3986 1872 1569 1967 6200 2740 2884 -779 5454 2508 2380 2549 3174 2761 3724 1802 1888 165 4121 1659 3395 2710 2455 -418 954 1644 1924 338 1564 624 1077 -882 -2439 -2252 -1203 -1919 -1151 -2257 -2533 -1332 -1953 -62 207 -434 -90 835 570 743 3 113 -564 -375 -493 -472 419 18 -630 -1114 -1068 -709 -793 -1518 -965 -725 -448 124 408 355 595 143 371 363 -361 207 252 -158 -79 236 294 260 571 858 476 364 864 443 733 348 106 207 -30 -193 -203 102 -216 -196 -176 -504 -177 -405 -1732 -2106 -617 -683 -2320 -1290 -2178 -1465 -967 -2643 -2709 -3872 -1346 -882 -495 -958 -966 -789 -7 -152 -632 -1168 -421 -109 -642 393 -867 -705 -990 -1424 -1779 885 487 -422 530 -776 -839 151 9 1077 570 -31 -698 734 357 306 389 1214 579 598 -188 1367 706 724 812 1046 933 1228 589 615 58 1550 665 1474 1199 1046 -182 429 830 1112 198 932 366 638 -483 -1220 -1069 -586 -1078 -701 -1608 -1898 -1062 -1662 -56 198 -407 -85 783 546 659 2 92 -483 -363 -515 -531 531 23 -785 -1373 -1186 -784 -916 -1792 -1191 -946 -588 178 615 553 958 229 594 546 -528 307 395 -251 -129 381 457 414 872 1254 712 530 1255 729 1267 624 200 390 -61 -397 -437 222 -461 -415 -372 -1009 -351 -788 SS 20230907T115920.9Z 8650.499547 277 1 29.95 2 78.00 93.12 17.46 200.10 0.00 1 0.00 1 0 25 1.995e-01 7.887e-03 1.891e-02 1.138e-03 5.595230e-01 5.803617e-04 6.548675e-03 -6.000000e+00 1.134018e-01 229.80 -2.00 3.57 -2.00 319.79 0.00e+00 1.574634e-03 1.807736e-04 6.717745e-04 -6.000000e+00 5.052798e-03 285.55 -2.00 20.00 -2.00 319.07 0.00e+00 4.663 0.002 302.00 328.00 3 1.3961e+00 1.6836e-03 5.4457e-02 -6.0000e+00 2.8289e-01 5.3748e-02 2.0239e-03 2.9874e-02 -6.0000e+00 3.0716e-01 -1.0033e-01 1.6858e-03 1.4782e-02 -6.0000e+00 1.8294e-01 3.8503e-02 8.7488e-04 4.3956e-03 -6.0000e+00 7.7415e-02 7.7230e-04 -2.4387e-04 3.0659e-05 4.7041e-05 -6.0000e+00 5.3023e-03 3.2971e-03 0.0000e+00 11 8 0 10 0 0 35.05 28.25 0.49 0.00330 0.00146 253 253 1 5 0 118.350 36.50 19.99 28.25 29.67 3.5 984.80 -59669 -75292 -33684 -58703 -78573 -81076 -66312 -55235 -51660 -64619 -69672 -70574 -29947 -19207 -12691 -12684 -12276 -13726 974 -11673 -5566 -16293 -11027 -455 -6256 2602 -11380 -5647 -13155 -11539 -12237 5160 1740 -3127 -478 -7800 -7416 1875 -1241 2083 1987 1429 -1587 2489 658 176 696 3056 1580 1811 -79 2710 2316 2155 1754 2601 1420 1356 706 748 1383 2641 2135 2684 2547 1172 -980 268 930 855 580 932 428 455 -712 -1667 -1257 -1286 -1709 -1039 -1282 -1609 -1467 -1922 -560 89 -272 219 646 630 577 51 220 -244 -16 -390 -111 449 120 -477 -945 -1242 -607 -738 -1164 -729 -834 -418 121 374 209 561 216 225 409 -124 176 208 -125 -37 59 91 202 627 812 484 381 686 394 675 166 274 164 -77 -177 -171 -8 -58 -147 -220 -471 -160 -359 -960 -1579 -478 -990 -1499 -1637 -1295 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