File name: Pandora243s1_Downsview_20230911_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T061733.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230911_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230911T130843.6Z 8654.547727 236 1 29.57 2 66.53 107.28 30.69 126.27 0.00 1 0.00 1 0 17 3.242e-02 8.781e-03 8.395e-03 2.304e-03 3.103949e-01 1.154375e-03 3.747006e-03 -6.000000e+00 1.840262e-02 229.43 -2.00 3.57 -2.00 317.64 0.00e+00 6.227122e-05 1.845194e-04 1.553058e-04 -6.000000e+00 8.197526e-04 285.21 -2.00 20.00 -2.00 316.85 0.00e+00 2.491 0.000 302.00 328.00 3 4.6576e+00 3.0775e-03 2.9373e-02 -6.0000e+00 4.5872e-02 4.5598e-02 3.4788e-03 1.6369e-02 -6.0000e+00 4.9822e-02 -1.9032e-02 2.1280e-03 7.9597e-03 -6.0000e+00 2.9676e-02 3.9378e-03 1.0632e-03 2.1879e-03 -6.0000e+00 1.2571e-02 3.0083e-04 -9.4460e-05 6.5107e-05 2.3432e-05 -6.0000e+00 8.6184e-04 9.5805e-03 3.8808e-05 11 9 0 11 32 0 92.53 27.99 0.15 0.00958 0.00887 18 18 1 5 0 1642.470 36.25 20.00 27.99 29.59 3.5 983.47 -16383 -4409 8810 -8673 -6841 -1571 -836 -7287 1442 -12083 -10125 -12276 -4116 476 -2927 3445 -3309 1554 5737 -297 1316 1354 1290 3093 159 9837 -1957 -2955 -1854 -3168 -770 7252 -67 -1245 5507 -4327 -6846 3921 -1787 2708 2537 249 -1929 281 -693 22 261 2426 -1601 26 -856 1786 -22 1022 799 317 -147 854 900 -374 -188 1376 1094 1033 1024 1389 -2601 400 -406 2028 -439 1115 -454 1712 -1653 -1857 -1441 -1281 -1345 -1094 -1818 -1236 -1523 -1582 -246 1011 -250 295 972 612 51 -625 -331 -1215 766 358 -153 861 373 -93 -904 -395 -468 5 -639 -783 -455 156 357 509 -328 432 41 451 727 -85 359 210 -110 -233 161 -53 154 605 663 -241 7 778 537 680 179 418 -325 -145 -51 -451 -38 -390 -392 -458 -540 304 384 -1715 -436 754 -795 -561 -124 -73 -768 153 -1493 -1222 -1649 -591 76 -550 657 -704 331 1219 -63 303 312 284 715 40 2303 -501 -709 -461 -824 -194 1850 -20 -369 1421 -1268 -2332 1432 -763 1264 1270 132 -1076 154 -382 12 139 1246 -850 14 -503 1096 -15 652 524 214 -101 574 591 -249 -131 1030 897 830 797 1067 -1973 296 -335 1721 -411 1056 -429 1505 -1375 -1490 -1058 -924 -1059 -911 -1712 -1189 -1553 -1701 -281 1141 -300 359 1165 698 57 -647 -340 -1262 791 414 -187 1149 489 -125 -1147 -457 -554 6 -815 -1049 -600 214 519 751 -513 674 61 662 980 -117 497 288 -163 -344 238 -82 231 861 896 -333 10 1045 737 1000 278 630 -505 -236 -83 -774 -66 -699 -703 -794 -900 510 634 SS 20230911T133343.7Z 8654.565089 250 1 31.00 2 62.28 112.35 27.39 135.81 0.00 1 0.00 1 0 17 7.225e-02 1.853e-02 1.820e-02 4.899e-03 2.823513e-01 2.452089e-03 3.439012e-03 -6.000000e+00 4.098667e-02 229.42 -2.00 3.57 -2.00 317.58 0.00e+00 -1.862191e-03 3.788292e-04 1.630610e-04 -6.000000e+00 1.826459e-03 285.21 -2.00 20.00 -2.00 316.77 0.00e+00 2.139 0.000 302.00 328.00 3 6.1395e+00 6.5272e-03 2.5797e-02 -6.0000e+00 1.0217e-01 1.0060e-01 7.3751e-03 1.5222e-02 -6.0000e+00 1.1099e-01 -3.2160e-02 4.4760e-03 7.3094e-03 -6.0000e+00 6.6107e-02 6.7997e-03 2.2220e-03 2.5299e-03 -6.0000e+00 2.7990e-02 9.8008e-05 -4.8467e-04 1.4004e-04 2.4892e-05 -6.0000e+00 1.9207e-03 1.1004e-02 -4.6841e-05 12 9 9 12 32 32 55.25 27.97 0.94 0.01100 0.00736 8 8 1 5 0 3874.570 36.25 20.00 27.97 30.95 3.5 993.75 -19420 -7822 39290 10988 -709 50032 11011 -5725 15855 -17104 105 10192 -8404 3267 -4935 6521 -9413 6415 8744 -7009 1938 6528 -520 6065 -317 4999 -7378 -4111 -6716 -3142 4803 14842 2341 355 1159 -8562 -13470 8710 -689 4839 -2900 197 2875 -1207 -3742 265 -2027 7009 -5065 -224 3116 3364 -2171 616 1892 -1984 -2064 3728 3921 346 665 509 -54 1666 -278 4957 -5984 2289 -2981 3313 -341 3090 -1202 3361 23 -2971 -1901 -3961 -3475 -1639 -4153 -2916 -1048 -602 1202 271 1827 1072 1338 1526 -1686 -1305 -92 -2864 2631 529 -1738 2966 53 470 -1323 -64 -1031 1055 -492 -1497 -699 456 97 21 208 320 -1183 1180 106 -855 2105 339 -478 86 -92 -1079 -125 624 1861 9 -1803 1249 373 2051 -170 1411 -822 858 -446 -1270 -725 -1128 -229 1779 -2168 398 1223 -2468 -931 2853 945 -62 2701 978 -686 1682 -2566 13 1232 -1389 548 -1009 1268 -2213 1339 1847 -1788 452 1453 -131 1533 -90 1383 -2228 -1102 -1736 -797 1212 3666 704 107 321 -2688 -5033 3113 -325 2243 -1549 105 1526 -663 -2095 141 -1073 3640 -2660 -127 1662 1911 -1378 399 1241 -1387 -1462 2453 2514 230 459 381 -44 1401 -229 3546 -4507 1590 -2410 2845 -327 2932 -1170 2970 19 -2281 -1320 -2742 -2596 -1364 -3965 -3015 -1028 -618 1305 316 2199 1328 1636 1763 -1844 -1413 -91 -2905 2729 570 -2132 3824 73 621 -1653 -72 -1133 1202 -617 -1986 -962 650 146 32 324 499 -1783 1742 146 -1123 2713 468 -715 135 -146 -1696 -190 892 2495 12 -2275 1565 508 2935 -261 2183 -1327 1422 -735 -2207 -1281 -2044 -410 3023 -3686 634 2059 SS 20230911T134305.3Z 8654.571589 256 1 30.02 2 60.73 114.33 26.30 139.85 0.00 1 0.00 1 0 17 8.263e-03 5.163e-03 5.273e-04 2.911e-04 2.555906e-01 1.471954e-04 3.127382e-03 -6.000000e+00 4.690225e-03 229.42 -2.00 3.57 -2.00 315.93 0.00e+00 3.946136e-04 1.542308e-05 3.671630e-05 -6.000000e+00 2.089226e-04 285.21 -2.00 20.00 -2.00 315.21 0.00e+00 2.036 0.000 302.00 328.00 3 1.3620e+00 3.8181e-04 2.4036e-02 -6.0000e+00 1.1691e-02 3.1332e-03 4.2659e-04 1.3406e-02 -6.0000e+00 1.2698e-02 -1.7675e-03 2.4483e-04 6.5262e-03 -6.0000e+00 7.5634e-03 -1.0401e-03 1.1189e-04 1.8207e-03 -6.0000e+00 3.2041e-03 1.3823e-02 6.8116e-05 8.0576e-06 2.1742e-05 -6.0000e+00 2.1964e-04 9.4845e-03 4.7723e-05 10 0 0 10 0 0 96.26 27.97 0.43 0.00948 0.01000 643 643 1 5 0 46.670 36.25 20.00 27.97 31.61 3.4 997.92 -1129 -860 -1769 -3074 -3653 -2688 -739 476 55 -1244 -1563 -1205 -438 498 678 322 307 699 1183 1120 782 860 843 905 624 458 4 -370 -319 458 962 1627 694 -1018 -1940 -2080 -1372 -348 -145 -253 -507 -521 -531 -344 -186 -232 -386 -495 -431 248 653 875 873 822 708 690 425 423 348 487 651 1067 1489 972 166 -349 -678 -146 463 363 286 194 200 -42 -389 -341 -490 -549 -420 -520 -719 -1339 -1624 -1587 -1029 -389 -62 115 349 359 351 179 131 216 298 250 488 527 186 -264 -510 -664 -350 -304 -520 -551 -505 -404 9 289 331 323 299 126 111 42 102 80 38 -172 -52 18 137 475 548 390 609 698 510 481 139 18 -17 -74 -34 -124 24 -43 -145 -109 -314 -365 -503 -270 -201 -442 -696 -755 -556 -165 119 14 -323 -401 -331 -128 165 237 121 119 265 463 453 318 348 356 382 277 209 2 -161 -132 191 431 740 343 -500 -894 -987 -692 -197 -89 -169 -347 -370 -386 -249 -134 -167 -271 -339 -303 170 478 654 663 655 577 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