File name: Pandora243s1_Downsview_20231016_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241111T143517.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20231016_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231016 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231016T140638.6Z 8689.587947 133 1 6.03 2 66.18 131.15 85.87 120.63 0.00 1 0.00 1 0 17 5.015e-02 1.319e-02 3.623e-02 9.255e-03 3.009112e-01 4.564834e-03 3.653997e-03 -6.000000e+00 2.804731e-02 225.33 -2.00 3.57 -2.00 317.67 0.00e+00 1.099013e-03 7.344187e-04 9.670244e-05 -6.000000e+00 1.246343e-03 280.98 -2.00 20.00 -2.00 316.95 0.00e+00 2.458 0.000 302.00 328.00 3 5.4287e+00 1.2083e-02 2.8566e-02 -6.0000e+00 6.9345e-02 5.2276e-02 1.3680e-02 1.5654e-02 -6.0000e+00 7.5592e-02 -1.0505e-02 8.5156e-03 7.7032e-03 -6.0000e+00 4.5061e-02 -1.3218e-03 4.3163e-03 2.3910e-03 -6.0000e+00 1.9178e-02 1.4534e-04 3.2947e-04 2.6097e-04 2.4209e-05 -6.0000e+00 1.3312e-03 5.7625e-04 0.0000e+00 12 9 9 12 33 1 999.00 28.11 0.55 0.00058 0.00305 1 10 1 5 0 3014.330 36.50 19.99 28.11 18.98 3.6 908.42 17399 -15674 28467 -9352 -13077 1217 2320 4899 484 -12465 -22017 2368 -594 -8504 -2850 1796 -8066 7964 11064 10842 -543 -5350 -7373 4249 -406 5227 2645 -4195 -5279 -4257 739 3331 -8156 947 6133 -6242 -4424 7236 1501 -622 3743 2541 -1609 -3505 -2354 2943 3030 4526 -890 3639 -2777 535 1305 -1565 -345 -943 -54 2053 733 1955 1390 2853 3535 188 -2543 2069 -3295 2182 -2800 1013 536 343 519 274 -852 -1124 -3244 -626 -1745 618 -2456 -2076 -1169 -1318 -1155 -376 -258 -487 -551 1057 120 -220 1839 -81 1277 249 0 1722 -288 712 -235 -1255 905 1212 -2051 287 -659 109 -158 750 906 854 913 1433 -580 -2050 601 -863 -439 620 -632 -600 758 -659 513 117 932 -668 357 534 -1658 575 587 129 396 -125 198 60 -630 -13 -155 -1017 826 1256 -1683 1953 -844 -1109 90 186 433 49 -1463 -2822 259 -78 -1405 -509 332 -1718 1517 2127 2163 -122 -1251 -1837 1001 -105 1316 666 -1052 -1277 -1053 190 914 -2476 285 1627 -1921 -1372 2375 627 -303 1870 1336 -906 -1848 -1340 1586 1601 2318 -477 1920 -1541 308 789 -1024 -228 -642 -37 1354 480 1269 953 2098 2818 151 -2036 1573 -2503 1574 -2344 854 488 322 477 240 -690 -884 -2394 -442 -1360 536 -2279 -2108 -1243 -1372 -1291 -444 -320 -618 -694 1241 130 -237 1795 -80 1363 277 0 2185 -387 917 -303 -1500 1016 1435 -2719 364 -884 153 -235 1111 1409 1331 1360 2101 -799 -2726 788 -1210 -658 910 -947 -939 1138 -956 699 164 1235 -925 494 791 -2478 863 900 208 677 -212 342 106 -1118 -21 -271 -1719 1348 SS 20231016T142102.4Z 8689.597944 138 1 30.00 2 64.28 134.46 83.77 123.21 0.00 1 0.00 1 0 25 9.511e-03 5.237e-03 3.422e-04 1.687e-04 2.878010e-01 8.388502e-05 3.532267e-03 -6.000000e+00 5.318284e-03 225.33 -2.00 3.57 -2.00 316.30 0.00e+00 3.594777e-04 9.499411e-06 4.499113e-05 -6.000000e+00 2.363445e-04 280.98 -2.00 20.00 -2.00 315.63 0.00e+00 2.290 0.000 302.00 328.00 3 3.2909e-01 2.1687e-04 2.6784e-02 -6.0000e+00 1.3149e-02 1.3893e-02 2.4364e-04 1.4791e-02 -6.0000e+00 1.4334e-02 -1.0330e-02 1.4117e-04 7.3005e-03 -6.0000e+00 8.5448e-03 2.1251e-03 6.6066e-05 2.0753e-03 -6.0000e+00 3.6362e-03 2.9085e-02 -5.6387e-05 4.6657e-06 2.4294e-05 -6.0000e+00 2.5247e-04 1.4980e-03 0.0000e+00 10 0 0 10 0 0 99.99 28.12 0.42 0.00150 0.00107 1969 1969 1 5 0 15.230 36.25 20.00 28.12 19.76 3.6 915.62 -1909 -1550 -1900 -3223 -4057 -3795 -2209 -745 -842 -1590 -2231 -2139 -1018 -67 391 444 560 882 1131 1289 1064 1005 834 915 707 490 314 -143 -143 238 889 1394 829 -688 -1912 -2216 -1483 -622 -181 -245 -346 -331 -351 -119 -20 7 -179 -252 -316 338 639 916 921 858 731 799 531 487 397 533 670 1068 1469 966 257 -410 -667 -282 258 311 201 97 122 -103 -312 -391 -603 -599 -518 -560 -821 -1365 -1702 -1691 -1109 -461 -105 104 302 369 363 205 94 290 208 205 499 511 197 -262 -550 -653 -365 -274 -477 -539 -479 -362 42 304 388 338 289 56 52 58 162 198 116 -47 -34 50 149 435 518 332 554 672 571 485 131 27 -52 -68 -8 -93 55 -27 -146 -186 -360 -398 -519 -367 -317 -386 -598 -743 -698 -406 -153 -190 -368 -515 -494 -268 -19 125 144 188 310 412 456 378 378 310 361 294 199 132 -56 -53 90 363 583 378 -314 -821 -977 -693 -326 -103 -153 -222 -221 -240 -81 -14 5 -119 -165 -205 224 435 666 681 669 563 629 425 385 307 413 544 905 1304 879 229 -348 -555 -234 227 290 195 97 120 -100 -288 -333 -489 -493 -446 -513 -793 -1414 -1815 -1843 -1258 -539 -125 126 364 433 414 220 96 296 224 231 594 656 258 -333 -684 -766 -421 -325 -599 -692 -629 -486 58 439 574 502 419 78 69 75 213 268 161 -68 -49 71 210 597 693 435 710 859 771 668 186 39 -76 -101 -12 -148 89 -43 -238 -299 -571 -621 -798 SS 20231016T143014.7Z 8689.604337 144 1 29.85 2 63.11 136.64 82.46 124.90 0.00 1 0.00 1 0 17 3.659e-02 1.018e-02 8.938e-03 2.779e-03 2.801794e-01 1.377409e-03 3.399393e-03 -6.000000e+00 2.045323e-02 225.33 -2.00 3.57 -2.00 317.30 0.00e+00 5.824645e-05 1.992313e-04 6.611724e-05 -6.000000e+00 9.090181e-04 280.98 -2.00 20.00 -2.00 316.60 0.00e+00 2.199 0.000 302.00 328.00 3 5.5806e+00 3.6205e-03 2.5852e-02 -6.0000e+00 5.0569e-02 6.6099e-02 4.0832e-03 1.4433e-02 -6.0000e+00 5.5131e-02 -9.7443e-03 2.4709e-03 7.1313e-03 -6.0000e+00 3.2864e-02 -1.3896e-03 1.2289e-03 2.0162e-03 -6.0000e+00 1.3982e-02 1.6384e-04 -3.6569e-04 7.8479e-05 2.2066e-05 -6.0000e+00 9.7122e-04 2.7977e-03 0.0000e+00 12 9 8 11 32 0 99.99 28.15 0.80 0.00280 0.00005 29 29 1 5 0 1029.220 36.25 20.00 28.15 20.07 3.6 916.75 -16721 -7646 18979 10102 15306 -2222 -5602 490 1749 -1593 -9916 -2271 7295 -4193 3589 2026 477 698 2888 6096 -2513 2089 -585 2845 -3791 8734 -7515 -289 -4368 -9409 -4261 5297 -3022 -232 642 -6492 -2306 4296 196 -46 1870 -163 -1227 -1744 -669 570 1159 1735 -1805 3511 -2576 1541 819 532 3659 -401 273 1518 242 77 1392 141 325 1888 -644 -857 -1647 -173 -598 1125 -117 1180 -424 1107 -225 -631 -1446 396 -1056 541 -1985 -1840 -1472 -2215 -270 425 -333 -366 377 208 326 619 1909 -1436 446 745 -201 1048 37 486 -394 -1904 920 -40 -105 -288 119 -869 342 455 -230 827 266 745 -462 -1252 637 -360 459 640 143 -628 -249 346 752 -433 -945 322 661 22 28 359 375 -276 -126 -621 233 -369 133 491 -447 -14 -159 -2184 -970 1826 955 1240 -216 -618 58 223 -214 -1429 -326 1091 -811 729 451 112 170 715 1511 -680 537 -161 807 -1098 2525 -2260 -82 -1224 -2830 -1317 1618 -986 -73 203 -2047 -786 1628 93 -25 1067 -90 -703 -1004 -380 318 685 998 -1061 2007 -1538 944 534 365 2496 -291 199 1079 170 54 1015 113 261 1570 -532 -702 -1283 -132 -506 978 -111 1134 -408 997 -188 -513 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