File name: Pandora185s1_EastProvidenceRI_20230720_L2Fit_fout2c4d20210421p1-8.txt File generation date: 20230722T145315.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 185 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora185_OF_v3d20200108.txt Instrument calibration file used: Pandora185s1_CF_v4d20210421.txt Level 1 file used: Pandora185s1_EastProvidenceRI_20230720_L1_smca1c4d20210421p1-8.txt Full location name: FRANCIS SCHOOL East Providence Short location name: EastProvidenceRI Country of location: United States Location latitude [deg]: 41.8410 Location longitude [deg]: -71.3610 Location altitude [m]: 15 Local noon date: 20230720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: 1-8 data preparation fieldcal ref day 20220917 First and last pixel inside fitting window: 193 334 Nominal wavelengths inside fitting window [nm]: 305.1280 305.2694 305.4108 305.5521 305.6935 305.8348 305.9761 306.1174 306.2587 306.4000 306.5413 306.6826 306.8238 306.9651 307.1063 307.2476 307.3888 307.5300 307.6712 307.8123 307.9535 308.0947 308.2358 308.3770 308.5181 308.6592 308.8003 308.9414 309.0825 309.2235 309.3646 309.5056 309.6467 309.7877 309.9287 310.0697 310.2107 310.3517 310.4927 310.6336 310.7746 310.9155 311.0564 311.1973 311.3382 311.4791 311.6200 311.7609 311.9017 312.0426 312.1834 312.3242 312.4651 312.6059 312.7466 312.8874 313.0282 313.1689 313.3097 313.4504 313.5911 313.7319 313.8726 314.0132 314.1539 314.2946 314.4352 314.5759 314.7165 314.8571 314.9977 315.1383 315.2789 315.4195 315.5601 315.7006 315.8412 315.9817 316.1222 316.2627 316.4032 316.5437 316.6842 316.8246 316.9651 317.1055 317.2460 317.3864 317.5268 317.6672 317.8076 317.9479 318.0883 318.2287 318.3690 318.5093 318.6496 318.7899 318.9302 319.0705 319.2108 319.3510 319.4913 319.6315 319.7718 319.9120 320.0522 320.1924 320.3325 320.4727 320.6129 320.7530 320.8931 321.0333 321.1734 321.3135 321.4536 321.5936 321.7337 321.8738 322.0138 322.1538 322.2939 322.4339 322.5739 322.7139 322.8538 322.9938 323.1337 323.2737 323.4136 323.5535 323.6934 323.8333 323.9732 324.1131 324.2530 324.3928 324.5326 324.6725 324.8123 324.9521 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230720T111449.5Z 8601.468629 94 1 48.88 2 72.24 77.86 97.61 60.52 0.00 1 0.00 1 0 17 2.009e-01 8.369e-03 1.190e-01 4.140e-03 4.455317e-01 2.187818e-03 5.148970e-03 -6.000000e+00 1.188386e-01 232.83 -2.00 3.53 -2.00 320.07 0.00e+00 1.903846e-03 7.381647e-04 1.031035e-03 -6.000000e+00 5.298960e-03 289.03 -2.00 20.00 -2.00 319.29 0.00e+00 3.232 0.001 302.00 328.00 3 3.9346e+00 6.5550e-03 4.0358e-02 -6.0000e+00 2.9815e-01 1.3912e-02 7.9823e-03 2.4137e-02 -6.0000e+00 3.2217e-01 -2.5501e-03 6.5732e-03 1.2131e-02 -6.0000e+00 1.9181e-01 -1.0585e-02 3.3623e-03 3.6253e-03 -6.0000e+00 8.0772e-02 2.3878e-04 -4.3292e-05 1.2699e-04 4.2192e-05 -6.0000e+00 5.7164e-03 1.3413e-03 0.0000e+00 11 8 0 10 0 0 98.54 23.26 0.31 0.00134 0.00102 20 4 1 5 0 2443.750 27.05 19.99 23.26 29.45 19.8 1015.23 177240 -39488 5556 -29843 -56159 -83988 -9794 -78157 4569 -32481 1437 6618 14406 -23708 -14170 6319 -14269 -280 -20091 2153 -10856 -18757 -7372 -4017 6277 5489 -3841 -8350 6486 5531 8128 184 6834 -13150 -8077 -7352 -3186 -7428 1242 -3061 -3340 -4109 426 3265 3402 1962 675 -668 1045 2806 113 3957 -977 2168 150 1487 1195 -113 850 1189 3494 2875 4196 1219 2333 -647 -881 -1363 1503 483 273 1011 297 314 106 -852 -1917 552 -2660 112 -1292 -2048 -2285 -945 -893 115 -119 1427 1497 570 1850 312 492 -222 -512 216 928 -428 -285 -750 -1541 -821 -666 -1153 -1679 -1650 -164 92 981 996 417 354 -286 -28 -527 476 115 452 -383 -31 664 164 496 510 -43 35 512 245 -238 -272 90 -73 618 -244 138 12 734 -259 -7 -265 -442 -548 716 -638 58 -412 -945 -1921 -129 -2323 65 -703 23 117 286 -835 -536 218 -655 -12 -1113 100 -578 -1101 -411 -233 348 316 -238 -518 348 327 534 15 559 -1298 -732 -772 -370 -990 201 -588 -694 -904 92 696 733 432 151 -153 243 686 31 1139 -317 722 53 531 431 -41 299 426 1313 1205 1909 597 1094 -297 -402 -663 805 291 174 646 184 181 55 -410 -901 267 -1520 72 -944 -1646 -1951 -850 -861 116 -124 1480 1506 541 1599 256 397 -193 -502 239 1146 -526 -351 -965 -1831 -901 -735 -1371 -2132 -2203 -228 124 1428 1564 683 573 -442 -40 -723 708 163 678 -611 -50 1039 251 726 783 -64 50 740 386 -375 -459 159 -134 1182 -501 296 27 1644 -587 -16 -556 -889 -1078 SS 20230720T112344.5Z 8601.474821 100 1 2.19 2 70.61 79.23 96.22 62.06 0.00 1 0.00 1 0 17 1.097e-01 1.394e-02 8.370e-02 9.379e-03 4.210051e-01 4.880021e-03 4.890434e-03 -6.000000e+00 6.486217e-02 232.83 -2.00 3.53 -2.00 318.89 0.00e+00 2.255282e-03 1.137480e-03 4.514665e-04 -6.000000e+00 2.891974e-03 289.03 -2.00 20.00 -2.00 318.07 0.00e+00 2.977 0.000 302.00 328.00 3 3.0607e+00 1.3555e-02 3.7358e-02 -6.0000e+00 1.6273e-01 4.5486e-02 1.5611e-02 2.2265e-02 -6.0000e+00 1.7584e-01 -5.3956e-02 1.0803e-02 1.0946e-02 -6.0000e+00 1.0469e-01 1.8225e-02 5.6143e-03 3.5968e-03 -6.0000e+00 4.4088e-02 7.4735e-04 3.3923e-04 2.7581e-04 3.8001e-05 -6.0000e+00 3.1197e-03 8.5567e-04 0.0000e+00 12 9 9 12 1 1 999.00 23.25 0.53 0.00086 0.00340 1 11 1 5 0 1004.580 27.05 20.00 23.25 29.76 19.7 1016.79 -20385 -1510 -23566 -17654 -27467 -59063 35322 -57063 4614 -25742 19262 -39808 11072 -34234 12679 -11212 -4208 -1309 -7371 -14538 -2597 15483 172 11340 -8225 6496 -19227 12077 -13050 7342 -1973 963 -3530 5666 754 6845 -1481 -3082 -480 -921 7193 -1274 3340 -1789 3311 -202 2388 -1340 1462 4935 4023 -662 371 1653 752 1423 2022 3115 -3701 5535 2503 4602 3082 1551 -1135 3812 -1952 585 -55 169 689 1040 687 -825 1538 -2532 -3238 -675 -3513 -2718 -735 -2504 -1863 -2191 -1209 464 -935 153 1241 2155 -475 614 -983 700 -589 998 -270 -550 579 -1825 -864 -889 1120 -2433 -348 -1385 1120 -1100 853 -59 797 785 -522 -1125 548 1100 186 493 38 555 -269 922 -815 914 -64 2291 833 874 -748 1200 323 -720 548 598 150 -162 485 -677 -303 -117 -1130 -971 -678 -50 -882 -630 -1005 -3025 775 -3548 169 -1318 652 -2767 557 -3256 881 -1097 -412 -133 -836 -1835 -292 1472 20 1265 -1173 820 -3059 1336 -1850 920 -307 163 -675 969 130 1177 -318 -809 -133 -291 2248 -453 1166 -663 1178 -75 859 -503 547 1900 1706 -317 188 800 379 730 1035 1550 -1946 2958 1356 2697 2008 1066 -772 2336 -1251 387 -41 130 557 843 539 -611 1089 -1700 -2107 -451 -2749 -2233 -665 -2332 -1824 -2297 -1345 500 -1059 173 1341 2307 -481 574 -917 685 -654 1153 -333 -732 763 -2327 -1067 -1024 1276 -3085 -459 -1818 1517 -1626 1262 -95 1237 1269 -809 -1634 788 1568 279 739 60 888 -425 1400 -1210 1350 -91 3070 1154 1313 -1172 1973 528 -1231 969 1064 281 -313 951 -1275 -580 -214 -1996 -1769 SS 20230720T112801.4Z 8601.477793 103 1 48.90 2 69.83 79.90 95.54 62.79 0.00 1 0.00 1 0 17 4.181e-02 6.413e-03 6.143e-03 4.798e-04 4.019449e-01 2.518939e-04 4.751624e-03 -6.000000e+00 2.472745e-02 232.83 -2.00 3.53 -2.00 319.38 0.00e+00 1.392427e-03 6.751544e-05 9.538169e-04 -6.000000e+00 1.102590e-03 289.03 -2.00 20.00 -2.00 318.57 0.00e+00 2.869 0.000 302.00 328.00 3 6.6577e-01 7.1793e-04 3.6121e-02 -6.0000e+00 6.2037e-02 6.0218e-03 8.4148e-04 2.1878e-02 -6.0000e+00 6.7037e-02 -8.1320e-04 6.2824e-04 1.0744e-02 -6.0000e+00 3.9912e-02 -9.9759e-03 3.2727e-04 3.0139e-03 -6.0000e+00 1.6807e-02 9.4387e-03 6.4285e-05 1.4559e-05 3.6380e-05 -6.0000e+00 1.1894e-03 1.3547e-03 0.0000e+00 11 8 0 10 0 0 98.00 23.23 0.27 0.00135 0.00184 605 132 1 5 0 80.670 27.05 20.00 23.23 29.87 19.7 1017.84 -6818 -13694 -11529 -14794 -15717 -14901 -15965 -11311 -14001 -11962 -12843 -8208 -10035 -1859 -4219 -1405 -1905 144 -823 -609 -1318 -1158 -1403 -2266 -1642 -3671 -3842 -4394 -3029 -2367 -193 32 -1287 -4475 -4230 -4515 -3077 -1883 -900 -843 -703 -439 -265 398 141 195 -456 -510 -500 720 655 1023 1065 1111 1217 984 449 27 255 768 1951 2445 2693 1147 563 75 -200 625 1072 841 1006 741 809 204 -608 -1298 -2092 -1405 -1633 -1349 -1551 -1994 -1697 -670 -326 311 583 1033 800 779 386 -424 -178 -369 -405 274 894 -32 -432 -918 -1255 -949 -320 -1232 -1233 -928 -584 203 742 806 533 480 18 -51 0 160 192 291 -33 -126 387 545 434 329 -209 -90 808 149 -4 -275 -304 -350 163 -8 -121 343 430 35 -86 -170 -469 -378 -141 -331 -274 -335 -336 -324 -389 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